Ultrasonik Işıma Altında Sentezlenen Grafen Oksitin CO2 Yakalama Performansı

Yıl 2024, Cilt: 27 Sayı: 2, 681 - 687, 27.03.2024

Deniz Sezgin , Müge Sarı Yılmaz

https://doi.org/10.2339/politeknik.1179735

Öz

Günümüzde CO2 yakalama, kontrolsüz salınan CO2 emisyonlarını önemli ölçüde azaltmak için önemli bir teknoloji olarak görülmektedir. CO2 yakalamada grafenin bir türevi olan grafen oksitin kullanılması, grafen oksitin benzersiz morfolojisi nedeniyle büyük ilgi görmektedir. Bu çalışmada, modifiye Hummers yöntemine göre ultrason ışıması altında grafen oksit (GrO) sentezlenmiş ve CO2 yakalama performansı incelenmiştir. Numunenin yapısal özelliklerinin belirlenmesi için X-ışını toz kırınımı (XRD) ve Fourier dönüşümü kızılötesi (FTIR) analizleri uygulanmıştır. GrO'nun CO2 tutma performansı farklı sıcaklıklar altında TG analiziyle incelenmiştir. GrO'nun CO2 adsorpsiyon kapasitesi 25°C'de 1,04 mmol g-1'e ulaştı. Kinetik çalışmadan elde edilen deneysel veriler, Avrami modelinin CO2 adsorpsiyonunu daha iyi tanımladığını ortaya koydu.

Anahtar Kelimeler

Grafen oksit, ultrasonik, CO2 yakalama, kinetic, Graphene oxide, ultrasound, CO2 capture, kinetics

CO2 Capture Performance of Graphene Oxide Synthesized Under Ultrasound Irradiation

Öz

Nowadays, CO2 capture is a vital technology to notably reduce the uncontrolled released CO2 emissions. CO2 capture using graphene oxide, a derivative of graphene, has become of tremendous interest due to its unique morphology. In this present work, graphene oxide (GrO) was synthesized under ultrasound irradiation according to the modified Hummers’ method and its CO2 capture performance was examined. The X-ray powder diffraction (XRD) and Fourier transform infrared (FTIR) analyses were applied to explore the structure of the sample. CO2 capture performance of GrO was examined by performing TG analysis under different temperatures. The CO2 adsorption capacity of GrO was reached up to 1.04 mmol g-1 at 25°C. The experimental data getting from the kinetic study revealed that the Avrami model better described the CO2 adsorption.

Anahtar Kelimeler

Graphene oxide, ultrasound, CO2 capture, kinetics

Kaynakça

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