Research Article
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Year 2023, , 189 - 203, 28.02.2023
https://doi.org/10.16984/saufenbilder.1081514

Abstract

References

  • [1] D. Dai, Z. Li, J. Yang, C. Wang, J. R. Wu, Y. Wang, Y. W. Yang, “Supramolecular assembly-induced emission enhancement for efficient mercury (II) detection and removal,” Journal of the American Chemical Society, vol. 141(11), pp. 4756-4763, 2019.
  • [2] P. Hadi, M. H. To, C. W. Hui, C. S. K. Lin, G. McKay, “Aqueous mercury adsorption by activated carbons, Water” Research, vol. 73, pp.37-55, 2015. [3] M. A. Rahman, M. S. Rahman, M. J. Uddin, A. N. M. Mamum-Or-Rashid, M. G. Pang, H. Rhim, “Emerging risk of environmental factors: insight mechanisms of Alzheimer’s diseases,” Environmental Science and Pollution Research, pp.1-14, 2020.
  • [4] A. Benhamou, M. Baudu, Z. Derriche, J. P. Basly, “Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48,” Journal of Hazardous Materials, vol. 171(1-3), pp. 1001-1008, 2009.
  • [5] V. K. Gupta, S. Agarwal, I. Tyagi, D. Pathania, B. S. Rathore, G. Sharma, “Synthesis, characterization and analytical application of cellulose acetate-tin (IV) molybdate nanocomposite ion exchanger: binary separation of heavy metal ions and antimicrobial activity,” Ionics, vol. 21(7), pp. 2069-2078, 2015.
  • [6] Y. Altunkaynak, “Effectively removing Cu(II) and Ni(II) ions from aqueous solutions using chemically non-processed Midyat stone: equivalent, kinetic and thermodynamic studies,” Journal of the Iranian Chemical Society, 2022.
  • [7] S. Bhuvaneshwari, H. Hettiarachchi, J. N. Meegoda, “Crop residue burning in India: policy challenges and potential solutions,” International Journal of Environmental Research and Public Health, vol. 16(5), pp.832- 851, 2019.
  • [8] Q, Cui, W. Zhang, S. Chai, Q. Zuo, K. H. Kim, “The potential of green biochar generated from biogas residue as a heterogeneous persulfate activator and its non-radical degradation pathways: Adsorption and degradation of tetracycline,” Environmental Research, vol. 204, pp. 112335, 2022.
  • [9] X. Sheng, J. Wang, Q. Cui, W. Zhang, X. Zhu, “A feasible biochar derived from biogas residue and its application in the efficient adsorption of tetracycline from an aqueous solution,” Environmental Research, vol. 207, pp. 112175, 2022.
  • [10] A. Bhatnagar, M. Sillanpää, A. Witek-Krowiak, “Agricultural waste peels as versatile biomass for water purification–A review,” Chemical Engineering Journal, vol. 270, pp. 244-271, 2015.
  • [11] M. Rafatullah, O. Sulaiman, R. Hashim, A. Ahmad, “Adsorption of methylene blue on low-cost adsorbents: a review,” Journal of hazardous materials, vol. 177 (1-3), pp. 70-80, 2010.
  • [12] N. Feng, X. Guo, S. Liang, “Adsorption study of copper (II) by chemically modified orange peel,” Journal of Hazardous Materials, vol. 164(2-3), pp. 1286-1292, 2009.
  • [13] Y. Altunkaynak, M. Canpolat, Ö. Yavuz, “Adsorption of cobalt (II) ions from aqueous solution using orange peel waste: equilibrium, kinetic and thermodynamic studies,” Journal of the Iranian Chemical Society, pp.1-12, 2021.
  • [14] S. Ilhan, A. Cabuk, C. Filik, F. Caliskan, “Effect of pretreatment on biosorption of heavy metals by fungal biomass,” Trakya University Journal of Engineering Sciences, vol. 5(1), pp. 11-17, 2004.
  • [15] Z. Aksu, İ. A. İşoğlu, “Removal of copper (II) ions from aqueous solution by biosorption onto agricultural waste sugar beet pulp,” Process Biochemistry, vol. 40(9), pp. 3031-3044, 2005.
  • [16] W. Tang, J. Gong, L. Wu, Y. Li, M. Zhang, X. Zeng, “DGGE diversity of manganese mine samples and isolation of a Lysinibacillus sp. efficient in removal of high Mn (II) concentrations,” Chemosphere, vol. 165, pp. 277-283, 2016.
  • [17] I. Kara, D. Tunc, F. Sayin, S. T. Akar, “Study on the performance of metakaolin based geopolymer for Mn (II) and Co (II) removal,” Applied Clay Science, vol. 161, pp. 184-193, 2018.
  • [18] X. Li, D. Zhang, F. Sheng, H. Qing, “Adsorption characteristics of Copper (Ⅱ), Zinc (Ⅱ) and Mercury (Ⅱ) by four kinds of immobilized fungi residues,” Ecotoxicology and Environmental Safety, vol. 147, pp. 357-366, 2018.
  • [19] Y. A. Neolaka, Y. Lawa, J. N. Naat, A. A. P. Riwu, H. Darmokoesoemo, G. Supriyanto, H. S. Kusuma, “A Cr (VI)-imprinted-poly (4-VP-co-EGDMA) sorbent prepared using precipitation polymerization and its application for selective adsorptive removal and solid phase extraction of Cr (VI) ions from electroplating industrial wastewater,” Reactive and Functional Polymers, vol. 147, pp.) 104451, 2020.
  • [20] M. R. Abukhadra, F. M. Dardir, M. Shaban, E. A. Ahmed, M. F. Soliman, “Superior removal of Co2+, Cu2+ and Zn2+ contaminants from water utilizing spongy Ni/Fe carbonate–fluorapatite; preparation, application and mechanism,” Ecotoxicology and Environmental Safety, vol. 157, pp. 358-368, 2018.
  • [21] M. Kragović, A. Daković, M. Marković. J. Krstić, G. D. Gatta, N. Rotiroti, “Characterization of lead sorption by the natural and Fe (III)-modified zeolite,” Applied Surface Science, vol. 283, pp. 764-774, 2013.
  • [22] E. C. Lima, F. Sher, A. Guleria, M. R. Saeb, I. Anastopoulos, H. N. Tran, A. Hosseini-Bandegharaei, “Is one performing the treatment data of adsorption kinetics correctly?,” Journal of Environmental Chemical Engineering, vol. 9 (2), pp. 104813, 2021.
  • [23] C. Nguyen, D. D. Do, “The Dubinin–Radushkevich equation and the underlying microscopic adsorption description,” Carbon, vol. 39(9), pp. 1327-1336, 2001.
  • [24] L. F. Maia, R. C. Hott, P. C. Ladeira, B. L. Batista, T. G. Andrade, M. S. Santos, J. L. “Rodrigues, Simple synthesis and characterization of l-Cystine functionalized δ-FeOOH for highly efficient Hg (II) removal from contamined water and mining waste,” Chemosphere, vol. 215, pp. 422-431, 2019.
  • [25] Kokkinos, K. Simeonidis, A. Zouboulis, M. Mitrakas, “Mercury removal from drinking water by single iron and binary iron-manganese oxyhydroxides,” Desalination and Water Treatment, vol. 54(8), pp. 2082-2090, 2015.
  • [26] J. Tang, Y. Huang, Y. Gong, H. Lyu, Q. Wang, J. Ma, “Preparation of a novel graphene oxide/Fe-Mn composite and its application for aqueous Hg (II) removal,” Journal of Hazardous Materials, vol. 316, pp. 151-158, 2016.
  • [27] F. S. Awad, K. M. AbouZeid, W. M. A. El-Maaty, A. M. El-Wakil, M. S. El-Shall, “Efficient removal of heavy metals from polluted water with high selectivity for mercury (II) by 2-imino-4-thiobiuret–partially reduced graphene oxide (IT-PRGO),” Acs Applied Materials & Interfaces, vol. 9(39), pp. 34230-34242, 2017.
  • [28] S. Das, A. Samanta, G. Gangopadhyay, S. Jana, “Clay-based nanocomposites as recyclable adsorbent toward Hg (II) capture: experimental and theoretical understanding,” ACS omega, vol. 3(6), pp. 6283-6292, 2018.
  • [29] E. C. Lima, A. Hosseini-Bandegharaei, J. C. Moreno-Piraján, I. Anastopoulos, “A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption,” Journal of Molecular Liquids, vol. 273, pp. 425-434, 2019.
  • [30] V. K. Gupta, “Equilibrium uptake, sorption dynamics, process development, and column operations for the removal of copper and nickel from aqueous solution and wastewater using activated slag, a low-cost adsorbent,” Industrial & Engineering Chemistry Research, vol. 37(1), pp. 192-202, 1998.
  • [31] K. G. Akpomie, F. A. Dawodu, K. O. Adebowal, “Mechanism on the sorption of heavy metals from binary-solution by a low cost montmorillonite and its desorption potential,” Alexandria Engineering Journal, vol. 54(3), pp. 757-767, 2015.
  • [32] G. De Angelis, L. Medeghini, A. M. Conte, S. Mignardi, “Recycling of eggshell waste into low-cost adsorbent for Ni removal from wastewater,” Journal of Cleaner Production, vol. 164, pp. 1497-1506, 2017.
  • [33] C. M. Santos, J. Dweck, R. S. Viotto, A. H. Rosa, L. C. de Morais, “Application of orange peel waste in the production of solid biofuels and biosorbents,” Bioresource Technology, vol. 196, pp. 469-479, 2015.
  • [34] H. Yang, R. Yan, H. Chen, D. H. Lee, C. Zheng, “Characteristics of hemicellulose, cellulose and lignin pyrolysis,” Fuel, vol. 86(12-13), pp. 1781-1788, 2007.

Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations

Year 2023, , 189 - 203, 28.02.2023
https://doi.org/10.16984/saufenbilder.1081514

Abstract

This study looks at the capacity of raw orange peel (ROP) to adsorb Hg2+ ions from aqueous solutions. According to the results obtained, it is aimed at using ROPs more efficiently by recycling them. In this way, the usability of both ROP and other agricultural wastes in adsorption processes can be investigated. The effects of many variables on adsorption efficiency were investigated in the study, including initial metal ion concentration (MIC), contact time (CT), and pH. Under optimal operating conditions for Hg2+ ion adsorption, CT, solution pH, and initial concentration were determined to be 90 minutes, 3.08, and 180 mg/L, respectively. SEM, Fourier transform infrared spectroscopy (FT-IR), energy dispersion spectroscopy, and Brunauer, Emmett, and Teller (BET) analyses were used to examine the surface features of ROP. The isotherm values were found to be appropriate for the Langmuir isotherm model, indicating chemical absorption and likely process irreversibility. At 318, 308, and 298 K, the capacity of adsorption for the Hg2+ ion was calculated to be 66.225, 63.291 and 61.728 mg/g, respectively. The pseudo-second order (PSO), which exhibited the largest regression coefficient and best described the kinetic data for the removal of Hg2+ ions, according to thermodynamic studies, it was seen that the adsorption of Hg2+ ions on ROP is a natural and endothermic process. ROP, which is abundant throughout the world, can be used effectively in its natural state without any modification or chemical treatment, together with Hg2+ adsorption, to remove other heavy metals, dyestuffs, and toxic substances. ROP has been recognized as a potent and promising material for eliminating Hg2+ ions from the aquatic environment due to its characteristics such as high adsorption capability, cheap cost, and ease of availability.

References

  • [1] D. Dai, Z. Li, J. Yang, C. Wang, J. R. Wu, Y. Wang, Y. W. Yang, “Supramolecular assembly-induced emission enhancement for efficient mercury (II) detection and removal,” Journal of the American Chemical Society, vol. 141(11), pp. 4756-4763, 2019.
  • [2] P. Hadi, M. H. To, C. W. Hui, C. S. K. Lin, G. McKay, “Aqueous mercury adsorption by activated carbons, Water” Research, vol. 73, pp.37-55, 2015. [3] M. A. Rahman, M. S. Rahman, M. J. Uddin, A. N. M. Mamum-Or-Rashid, M. G. Pang, H. Rhim, “Emerging risk of environmental factors: insight mechanisms of Alzheimer’s diseases,” Environmental Science and Pollution Research, pp.1-14, 2020.
  • [4] A. Benhamou, M. Baudu, Z. Derriche, J. P. Basly, “Aqueous heavy metals removal on amine-functionalized Si-MCM-41 and Si-MCM-48,” Journal of Hazardous Materials, vol. 171(1-3), pp. 1001-1008, 2009.
  • [5] V. K. Gupta, S. Agarwal, I. Tyagi, D. Pathania, B. S. Rathore, G. Sharma, “Synthesis, characterization and analytical application of cellulose acetate-tin (IV) molybdate nanocomposite ion exchanger: binary separation of heavy metal ions and antimicrobial activity,” Ionics, vol. 21(7), pp. 2069-2078, 2015.
  • [6] Y. Altunkaynak, “Effectively removing Cu(II) and Ni(II) ions from aqueous solutions using chemically non-processed Midyat stone: equivalent, kinetic and thermodynamic studies,” Journal of the Iranian Chemical Society, 2022.
  • [7] S. Bhuvaneshwari, H. Hettiarachchi, J. N. Meegoda, “Crop residue burning in India: policy challenges and potential solutions,” International Journal of Environmental Research and Public Health, vol. 16(5), pp.832- 851, 2019.
  • [8] Q, Cui, W. Zhang, S. Chai, Q. Zuo, K. H. Kim, “The potential of green biochar generated from biogas residue as a heterogeneous persulfate activator and its non-radical degradation pathways: Adsorption and degradation of tetracycline,” Environmental Research, vol. 204, pp. 112335, 2022.
  • [9] X. Sheng, J. Wang, Q. Cui, W. Zhang, X. Zhu, “A feasible biochar derived from biogas residue and its application in the efficient adsorption of tetracycline from an aqueous solution,” Environmental Research, vol. 207, pp. 112175, 2022.
  • [10] A. Bhatnagar, M. Sillanpää, A. Witek-Krowiak, “Agricultural waste peels as versatile biomass for water purification–A review,” Chemical Engineering Journal, vol. 270, pp. 244-271, 2015.
  • [11] M. Rafatullah, O. Sulaiman, R. Hashim, A. Ahmad, “Adsorption of methylene blue on low-cost adsorbents: a review,” Journal of hazardous materials, vol. 177 (1-3), pp. 70-80, 2010.
  • [12] N. Feng, X. Guo, S. Liang, “Adsorption study of copper (II) by chemically modified orange peel,” Journal of Hazardous Materials, vol. 164(2-3), pp. 1286-1292, 2009.
  • [13] Y. Altunkaynak, M. Canpolat, Ö. Yavuz, “Adsorption of cobalt (II) ions from aqueous solution using orange peel waste: equilibrium, kinetic and thermodynamic studies,” Journal of the Iranian Chemical Society, pp.1-12, 2021.
  • [14] S. Ilhan, A. Cabuk, C. Filik, F. Caliskan, “Effect of pretreatment on biosorption of heavy metals by fungal biomass,” Trakya University Journal of Engineering Sciences, vol. 5(1), pp. 11-17, 2004.
  • [15] Z. Aksu, İ. A. İşoğlu, “Removal of copper (II) ions from aqueous solution by biosorption onto agricultural waste sugar beet pulp,” Process Biochemistry, vol. 40(9), pp. 3031-3044, 2005.
  • [16] W. Tang, J. Gong, L. Wu, Y. Li, M. Zhang, X. Zeng, “DGGE diversity of manganese mine samples and isolation of a Lysinibacillus sp. efficient in removal of high Mn (II) concentrations,” Chemosphere, vol. 165, pp. 277-283, 2016.
  • [17] I. Kara, D. Tunc, F. Sayin, S. T. Akar, “Study on the performance of metakaolin based geopolymer for Mn (II) and Co (II) removal,” Applied Clay Science, vol. 161, pp. 184-193, 2018.
  • [18] X. Li, D. Zhang, F. Sheng, H. Qing, “Adsorption characteristics of Copper (Ⅱ), Zinc (Ⅱ) and Mercury (Ⅱ) by four kinds of immobilized fungi residues,” Ecotoxicology and Environmental Safety, vol. 147, pp. 357-366, 2018.
  • [19] Y. A. Neolaka, Y. Lawa, J. N. Naat, A. A. P. Riwu, H. Darmokoesoemo, G. Supriyanto, H. S. Kusuma, “A Cr (VI)-imprinted-poly (4-VP-co-EGDMA) sorbent prepared using precipitation polymerization and its application for selective adsorptive removal and solid phase extraction of Cr (VI) ions from electroplating industrial wastewater,” Reactive and Functional Polymers, vol. 147, pp.) 104451, 2020.
  • [20] M. R. Abukhadra, F. M. Dardir, M. Shaban, E. A. Ahmed, M. F. Soliman, “Superior removal of Co2+, Cu2+ and Zn2+ contaminants from water utilizing spongy Ni/Fe carbonate–fluorapatite; preparation, application and mechanism,” Ecotoxicology and Environmental Safety, vol. 157, pp. 358-368, 2018.
  • [21] M. Kragović, A. Daković, M. Marković. J. Krstić, G. D. Gatta, N. Rotiroti, “Characterization of lead sorption by the natural and Fe (III)-modified zeolite,” Applied Surface Science, vol. 283, pp. 764-774, 2013.
  • [22] E. C. Lima, F. Sher, A. Guleria, M. R. Saeb, I. Anastopoulos, H. N. Tran, A. Hosseini-Bandegharaei, “Is one performing the treatment data of adsorption kinetics correctly?,” Journal of Environmental Chemical Engineering, vol. 9 (2), pp. 104813, 2021.
  • [23] C. Nguyen, D. D. Do, “The Dubinin–Radushkevich equation and the underlying microscopic adsorption description,” Carbon, vol. 39(9), pp. 1327-1336, 2001.
  • [24] L. F. Maia, R. C. Hott, P. C. Ladeira, B. L. Batista, T. G. Andrade, M. S. Santos, J. L. “Rodrigues, Simple synthesis and characterization of l-Cystine functionalized δ-FeOOH for highly efficient Hg (II) removal from contamined water and mining waste,” Chemosphere, vol. 215, pp. 422-431, 2019.
  • [25] Kokkinos, K. Simeonidis, A. Zouboulis, M. Mitrakas, “Mercury removal from drinking water by single iron and binary iron-manganese oxyhydroxides,” Desalination and Water Treatment, vol. 54(8), pp. 2082-2090, 2015.
  • [26] J. Tang, Y. Huang, Y. Gong, H. Lyu, Q. Wang, J. Ma, “Preparation of a novel graphene oxide/Fe-Mn composite and its application for aqueous Hg (II) removal,” Journal of Hazardous Materials, vol. 316, pp. 151-158, 2016.
  • [27] F. S. Awad, K. M. AbouZeid, W. M. A. El-Maaty, A. M. El-Wakil, M. S. El-Shall, “Efficient removal of heavy metals from polluted water with high selectivity for mercury (II) by 2-imino-4-thiobiuret–partially reduced graphene oxide (IT-PRGO),” Acs Applied Materials & Interfaces, vol. 9(39), pp. 34230-34242, 2017.
  • [28] S. Das, A. Samanta, G. Gangopadhyay, S. Jana, “Clay-based nanocomposites as recyclable adsorbent toward Hg (II) capture: experimental and theoretical understanding,” ACS omega, vol. 3(6), pp. 6283-6292, 2018.
  • [29] E. C. Lima, A. Hosseini-Bandegharaei, J. C. Moreno-Piraján, I. Anastopoulos, “A critical review of the estimation of the thermodynamic parameters on adsorption equilibria. Wrong use of equilibrium constant in the Van't Hoof equation for calculation of thermodynamic parameters of adsorption,” Journal of Molecular Liquids, vol. 273, pp. 425-434, 2019.
  • [30] V. K. Gupta, “Equilibrium uptake, sorption dynamics, process development, and column operations for the removal of copper and nickel from aqueous solution and wastewater using activated slag, a low-cost adsorbent,” Industrial & Engineering Chemistry Research, vol. 37(1), pp. 192-202, 1998.
  • [31] K. G. Akpomie, F. A. Dawodu, K. O. Adebowal, “Mechanism on the sorption of heavy metals from binary-solution by a low cost montmorillonite and its desorption potential,” Alexandria Engineering Journal, vol. 54(3), pp. 757-767, 2015.
  • [32] G. De Angelis, L. Medeghini, A. M. Conte, S. Mignardi, “Recycling of eggshell waste into low-cost adsorbent for Ni removal from wastewater,” Journal of Cleaner Production, vol. 164, pp. 1497-1506, 2017.
  • [33] C. M. Santos, J. Dweck, R. S. Viotto, A. H. Rosa, L. C. de Morais, “Application of orange peel waste in the production of solid biofuels and biosorbents,” Bioresource Technology, vol. 196, pp. 469-479, 2015.
  • [34] H. Yang, R. Yan, H. Chen, D. H. Lee, C. Zheng, “Characteristics of hemicellulose, cellulose and lignin pyrolysis,” Fuel, vol. 86(12-13), pp. 1781-1788, 2007.
There are 33 citations in total.

Details

Primary Language English
Subjects Chemical Engineering
Journal Section Research Articles
Authors

Yalçın Altunkaynak 0000-0003-2562-9297

Publication Date February 28, 2023
Submission Date March 2, 2022
Acceptance Date December 30, 2022
Published in Issue Year 2023

Cite

APA Altunkaynak, Y. (2023). Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations. Sakarya University Journal of Science, 27(1), 189-203. https://doi.org/10.16984/saufenbilder.1081514
AMA Altunkaynak Y. Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations. SAUJS. February 2023;27(1):189-203. doi:10.16984/saufenbilder.1081514
Chicago Altunkaynak, Yalçın. “Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations”. Sakarya University Journal of Science 27, no. 1 (February 2023): 189-203. https://doi.org/10.16984/saufenbilder.1081514.
EndNote Altunkaynak Y (February 1, 2023) Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations. Sakarya University Journal of Science 27 1 189–203.
IEEE Y. Altunkaynak, “Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations”, SAUJS, vol. 27, no. 1, pp. 189–203, 2023, doi: 10.16984/saufenbilder.1081514.
ISNAD Altunkaynak, Yalçın. “Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations”. Sakarya University Journal of Science 27/1 (February 2023), 189-203. https://doi.org/10.16984/saufenbilder.1081514.
JAMA Altunkaynak Y. Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations. SAUJS. 2023;27:189–203.
MLA Altunkaynak, Yalçın. “Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations”. Sakarya University Journal of Science, vol. 27, no. 1, 2023, pp. 189-03, doi:10.16984/saufenbilder.1081514.
Vancouver Altunkaynak Y. Using Chemically Unprocessed Orange Peel to Effectively Remove Hg(II) Ions From Aqueous Solutions: Equivalent, Thermodynamic, And Kinetic Investigations. SAUJS. 2023;27(1):189-203.

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