Research Article
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Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography

Year 2023, , 1002 - 1007, 18.10.2023
https://doi.org/10.16984/saufenbilder.1265507

Abstract

In this study, a high performance liquid chromatography-ultraviolet detection method was introduced for the detection of cymoxanil. The experimental parameters of the procedure were thoroughly evaluated. Cymoxanil was eluted by ammonium formate buffer (50.0 mM, pH 4.0):acetonitrile (55:45 v/v) as mobile phase. Under the optimal conditions, the limits of detection and quantification (LOD and LOQ) were found as 7.4 – 24.8 µg kg-1, which allows trace determination of pesticides in food samples. Proposed method was then implemented for the determination of selected fungicide in potato flour samples with acceptable % recoveries in the range of 81.4–112.9%, while the values of relative standard deviation (RSD) were below 10% showing a satisfactory applicability for cymoxanil in such complex real samples matrix.

References

  • F. M. Al-Nasir, A. G. Jiries, G. J. Al-Rabadi, M. H. Alu'datt, C. C. Tranchant, S. A. Al-Dalain, N. Alrabadi, O. Y. Madanat, R. S. Al-Dmour, "Determination of pesticide residues in selected citrus fruits and vegetables cultivated in the Jordan Valley" LWT, vol. 123, pp. 109005, 2020.
  • A. Abbasalizadeh, S. M. Sorouraddin, M. A. Farajzadeh, M. Nemati, M. R. A. Mogoddam, "Dispersive solid phase extraction of several pesticides from fruit juices using a hydrophobic metal organic framework prior to HPLC-MS/MS determination" Journal of Food Composition and Analysis, vol. 114, pp. 104788, 2022.
  • H. Serbest, "Determination of Resmethrin in Corn Silk Matrix by Gas Chromatography-Flame Ionization Detector (GC-FID)" Sakarya University Journal of Science, vol. 26(5), pp. 1022-1028, 2022.
  • S. Amini, M. Amiri, H. Ebrahimzadeh, S. Seidi, S. H. kandeh, "Synthesis of magnetic Cu/CuFe2O4@ MIL-88A (Fe) nanocomposite and application to dispersive solid-phase extraction of chlorpyrifos and phosalone in water and food samples" Journal of Food Composition and Analysis, vol. 104, pp. 104128, 2021.
  • R.C. Gilden, K. Huffling, B. Sattler, "Pesticides and health risks" Journal of Obstetric, Gynecologic & Neonatal Nursing, vol. 39(1), pp. 103-110, 2010.
  • K. -H. Kim, E. Kabir, S. A. Jahan, "Exposure to pesticides and the associated human health effects" Science of the total environment, vol. 575, pp. 525-535, 2017.
  • V. Feigenbrugel, S. Le Calvé, P. Mirabel, "Molar absorptivities of 2, 4-D, cymoxanil, fenpropidin, isoproturon and pyrimethanil in aqueous solution in the near-UV" Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 63(1), pp. 103-110, 2006.
  • J. -Y. Yoon, J. E. Kim, H. J. Song, K. B. Oh, J. W. Jo, Y. -H. Yang, S. H. Lee, G. Kang, H. J. Kim, Y. -K. Choi, "Assessment of adsorptive behaviors and properties of grape pomace-derived biochar as adsorbent for removal of cymoxanil pesticide" Environmental Technology & Innovation, vol. 21, pp. 101242, 2021.
  • X. Jiang, H. Jin, Y. Sun, R. Gui, "Colorimetric and fluorometric dual-channel ratiometric determination of fungicide cymoxanil based on analyte-induced aggregation of silver nanoparticles and dually emitting carbon dots" Microchimica Acta, vol. 186, pp. 1-12, 2019.
  • H. Mercan, R. Inam, "Determination of Cymoxanil Fungicide in Commercial Formulation and Natural Water by Square‐wave Stripping Voltammetry" CLEAN–Soil, Air, Water, vol. 38(5‐6), pp. 558-564, 2010.
  • P. Fidente, C. D. Giovanni, S. Seccia, P. Morrica, "Determination of cymoxanil in drinking water and soil using high‐performance liquid chromatography" Biomedical Chromatography, vol. 19(10), pp. 766-770, 2005.
  • A. S. TP, K. Banerjee, M. Jadhav, R. Girame, S. Utture, S. Hingmire, D. Oulkar, "Residue dissipation and processing factor for dimethomorph, famoxadone and cymoxanil during raisin preparation" Food chemistry, vol. 170, pp. 180-185, 2015.
  • M. J. Hengel, T. Shibamoto, "Development of a gas chromatographic method for fungicide cymoxanil analysis in dried hops" Journal of agricultural and food chemistry, vol. 49(2), pp. 570-573, 2001.
  • D. Bavol, J. Zima, J. Barek, H. Dejmkova, "Voltammetric determination of cymoxanil and famoxadone at different types of carbon electrodes" Electroanalysis, vol. 28(5), pp. 1029-1034, 2016.
  • K. Dost, M. Öksüz, M. Cittan, B. Mutlu, B. Tural, "Determination of boscalid, pyraclostrobin and trifloxystrobin in dried grape and apricot by HPLC/UV method" Journal of Food Composition and Analysis, vol. 115, pp. 104926, 2023.
  • R. R. Pasupuleti, Z. -F. Wang, W. -J. Ya, C. -A. Kuo, Y. -Y Chao, Y. -L. Huang, "Extraction and detection of chlorophenols in water samples using deep eutectic solvent-based dispersive liquid–liquid microextraction coupled with HPLC-UV" Microchemical Journal, vol. 182, pp. 107843, 2022.
Year 2023, , 1002 - 1007, 18.10.2023
https://doi.org/10.16984/saufenbilder.1265507

Abstract

References

  • F. M. Al-Nasir, A. G. Jiries, G. J. Al-Rabadi, M. H. Alu'datt, C. C. Tranchant, S. A. Al-Dalain, N. Alrabadi, O. Y. Madanat, R. S. Al-Dmour, "Determination of pesticide residues in selected citrus fruits and vegetables cultivated in the Jordan Valley" LWT, vol. 123, pp. 109005, 2020.
  • A. Abbasalizadeh, S. M. Sorouraddin, M. A. Farajzadeh, M. Nemati, M. R. A. Mogoddam, "Dispersive solid phase extraction of several pesticides from fruit juices using a hydrophobic metal organic framework prior to HPLC-MS/MS determination" Journal of Food Composition and Analysis, vol. 114, pp. 104788, 2022.
  • H. Serbest, "Determination of Resmethrin in Corn Silk Matrix by Gas Chromatography-Flame Ionization Detector (GC-FID)" Sakarya University Journal of Science, vol. 26(5), pp. 1022-1028, 2022.
  • S. Amini, M. Amiri, H. Ebrahimzadeh, S. Seidi, S. H. kandeh, "Synthesis of magnetic Cu/CuFe2O4@ MIL-88A (Fe) nanocomposite and application to dispersive solid-phase extraction of chlorpyrifos and phosalone in water and food samples" Journal of Food Composition and Analysis, vol. 104, pp. 104128, 2021.
  • R.C. Gilden, K. Huffling, B. Sattler, "Pesticides and health risks" Journal of Obstetric, Gynecologic & Neonatal Nursing, vol. 39(1), pp. 103-110, 2010.
  • K. -H. Kim, E. Kabir, S. A. Jahan, "Exposure to pesticides and the associated human health effects" Science of the total environment, vol. 575, pp. 525-535, 2017.
  • V. Feigenbrugel, S. Le Calvé, P. Mirabel, "Molar absorptivities of 2, 4-D, cymoxanil, fenpropidin, isoproturon and pyrimethanil in aqueous solution in the near-UV" Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, vol. 63(1), pp. 103-110, 2006.
  • J. -Y. Yoon, J. E. Kim, H. J. Song, K. B. Oh, J. W. Jo, Y. -H. Yang, S. H. Lee, G. Kang, H. J. Kim, Y. -K. Choi, "Assessment of adsorptive behaviors and properties of grape pomace-derived biochar as adsorbent for removal of cymoxanil pesticide" Environmental Technology & Innovation, vol. 21, pp. 101242, 2021.
  • X. Jiang, H. Jin, Y. Sun, R. Gui, "Colorimetric and fluorometric dual-channel ratiometric determination of fungicide cymoxanil based on analyte-induced aggregation of silver nanoparticles and dually emitting carbon dots" Microchimica Acta, vol. 186, pp. 1-12, 2019.
  • H. Mercan, R. Inam, "Determination of Cymoxanil Fungicide in Commercial Formulation and Natural Water by Square‐wave Stripping Voltammetry" CLEAN–Soil, Air, Water, vol. 38(5‐6), pp. 558-564, 2010.
  • P. Fidente, C. D. Giovanni, S. Seccia, P. Morrica, "Determination of cymoxanil in drinking water and soil using high‐performance liquid chromatography" Biomedical Chromatography, vol. 19(10), pp. 766-770, 2005.
  • A. S. TP, K. Banerjee, M. Jadhav, R. Girame, S. Utture, S. Hingmire, D. Oulkar, "Residue dissipation and processing factor for dimethomorph, famoxadone and cymoxanil during raisin preparation" Food chemistry, vol. 170, pp. 180-185, 2015.
  • M. J. Hengel, T. Shibamoto, "Development of a gas chromatographic method for fungicide cymoxanil analysis in dried hops" Journal of agricultural and food chemistry, vol. 49(2), pp. 570-573, 2001.
  • D. Bavol, J. Zima, J. Barek, H. Dejmkova, "Voltammetric determination of cymoxanil and famoxadone at different types of carbon electrodes" Electroanalysis, vol. 28(5), pp. 1029-1034, 2016.
  • K. Dost, M. Öksüz, M. Cittan, B. Mutlu, B. Tural, "Determination of boscalid, pyraclostrobin and trifloxystrobin in dried grape and apricot by HPLC/UV method" Journal of Food Composition and Analysis, vol. 115, pp. 104926, 2023.
  • R. R. Pasupuleti, Z. -F. Wang, W. -J. Ya, C. -A. Kuo, Y. -Y Chao, Y. -L. Huang, "Extraction and detection of chlorophenols in water samples using deep eutectic solvent-based dispersive liquid–liquid microextraction coupled with HPLC-UV" Microchemical Journal, vol. 182, pp. 107843, 2022.
There are 16 citations in total.

Details

Primary Language English
Subjects Analytical Chemistry (Other)
Journal Section Research Articles
Authors

Tuğçe Unutkan Gösterişli 0000-0002-1143-4192

Early Pub Date October 5, 2023
Publication Date October 18, 2023
Submission Date March 15, 2023
Acceptance Date July 3, 2023
Published in Issue Year 2023

Cite

APA Unutkan Gösterişli, T. (2023). Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. Sakarya University Journal of Science, 27(5), 1002-1007. https://doi.org/10.16984/saufenbilder.1265507
AMA Unutkan Gösterişli T. Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. SAUJS. October 2023;27(5):1002-1007. doi:10.16984/saufenbilder.1265507
Chicago Unutkan Gösterişli, Tuğçe. “Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography”. Sakarya University Journal of Science 27, no. 5 (October 2023): 1002-7. https://doi.org/10.16984/saufenbilder.1265507.
EndNote Unutkan Gösterişli T (October 1, 2023) Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. Sakarya University Journal of Science 27 5 1002–1007.
IEEE T. Unutkan Gösterişli, “Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography”, SAUJS, vol. 27, no. 5, pp. 1002–1007, 2023, doi: 10.16984/saufenbilder.1265507.
ISNAD Unutkan Gösterişli, Tuğçe. “Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography”. Sakarya University Journal of Science 27/5 (October 2023), 1002-1007. https://doi.org/10.16984/saufenbilder.1265507.
JAMA Unutkan Gösterişli T. Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. SAUJS. 2023;27:1002–1007.
MLA Unutkan Gösterişli, Tuğçe. “Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography”. Sakarya University Journal of Science, vol. 27, no. 5, 2023, pp. 1002-7, doi:10.16984/saufenbilder.1265507.
Vancouver Unutkan Gösterişli T. Development of an Analytical Method for the Determination of Cymoxanil in Potato Flour Samples by High Performance Liquid Chromatography. SAUJS. 2023;27(5):1002-7.

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