Research Article
BibTex RIS Cite

Bromlu fenstatin türevlerinin seryum (IV) amonyum nitrat/lityum bromür (CAN/LiBr) ile sentezi ve yoğunluk fonksiyonel teorisi (DFT) ile incelenmesi

Year 2017, , 481 - 488, 01.06.2017

Yasin Çetinkaya

https://doi.org/10.16984/saufenbilder.270715
Cited By: 1

Abstract

 Bu
çalışmada, Eaton reaktifi (CH3SO3H/P2O5)
kullanılarak fenstatin türevi olan (3,4-dimetoksifenil)(3,4,5-trimetoksifenil)metanon
(7) sentezlendi. Diarilmetanon 7’nin seryum (IV) amonyum nitrat (CAN/LiBr)
kullanılarak bromlanması ile  (2-brom-3,4,5-trimetoksifenil)(3,4-dimetoksifenil)metanon
(10) ve (2,6-dibrom-3,4,5-trimetoksifenil) (3,4-dimetoksifenil)metanon (11)
sentezlendi. Sentezlenen bileşiklerin yapıları IR, HRMS,  1H ve 13C NMR
spektroskopisi ile aydınlatıldı. Bileşiklerin geometrik parametreleri GAUSSIAN
09W paket programı kullanılarak, yoğunluk fonksiyonel teorisi (DFT)
B3LYP/6-311G(d,p) metodu ile optimize edildi ve yapısal parametreleri (bağ
açıları, bağ uzunlukları ve dihedral açıları) incelendi.

Keywords

Fenstatin brominasyon seryum (IV) amonyum nitrat (CAN) Eaton reaktifi

Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT)

Year 2017, , 481 - 488, 01.06.2017

Yasin Çetinkaya

https://doi.org/10.16984/saufenbilder.270715
Cited By: 1

Abstract

In this study,
(3,4-dimethoxyphenyl) (3,4,5-trimethoxyphenyl) methanone (7) being phenstatin
derivation  was synthesized using Eaton's
reagent (CH3SO3H / P2O5). Novel
compound (2-bromo-3,4,5-trimethoxyphenyl) (3,4-dimethoxyphenyl) methanone (10)
and (2,6-dibromo-3,4,5-trimethoxyphenyl) (3,4-dimethoxyphenyl) methanone (11)
were   synthesized with the bromination of
diarylmethanone 7 with ceric (IV) ammonium nitrate (CAN/LiBr).  In order to determine the structures of the
compounds synthesized, IR, HRMS, 1H and 13C NMR
spectroscopic analysis were used. Geometrical
parameters of the products were optimized with the density functional theory
(DFT) B3LYP method using the 6-311G(d,p) basis set implemented Gaussian 09 and
analyzed their structural parameters (bond lenghts, bond angles, dihedral
angles).

Keywords

Phenstatin bromination serium (IV) ammonium nitrate (CAN) Eaton’s reagent

There are 0 citations in total.

Details

Subjects Engineering
Journal Section Research Articles
Authors

Yasin Çetinkaya

Publication Date June 1, 2017
Submission Date December 1, 2016
Acceptance Date March 21, 2017
Published in Issue Year 2017

Cite

APA Çetinkaya, Y. (2017). Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). Sakarya University Journal of Science, 21(3), 481-488. https://doi.org/10.16984/saufenbilder.270715
AMA Çetinkaya Y. Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). SAUJS. June 2017;21(3):481-488. doi:10.16984/saufenbilder.270715
Chicago Çetinkaya, Yasin. “Synthesis of Brominated Phenstatin Derivatives via Cerium (IV) Ammonium Nitrate / Lithium Bromide (CAN/LiBr) and Investigation With the Density Functional Theory (DFT)”. Sakarya University Journal of Science 21, no. 3 (June 2017): 481-88. https://doi.org/10.16984/saufenbilder.270715.
EndNote Çetinkaya Y (June 1, 2017) Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). Sakarya University Journal of Science 21 3 481–488.
IEEE Y. Çetinkaya, “Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT)”, SAUJS, vol. 21, no. 3, pp. 481–488, 2017, doi: 10.16984/saufenbilder.270715.
ISNAD Çetinkaya, Yasin. “Synthesis of Brominated Phenstatin Derivatives via Cerium (IV) Ammonium Nitrate / Lithium Bromide (CAN/LiBr) and Investigation With the Density Functional Theory (DFT)”. Sakarya University Journal of Science 21/3 (June 2017), 481-488. https://doi.org/10.16984/saufenbilder.270715.
JAMA Çetinkaya Y. Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). SAUJS. 2017;21:481–488.
MLA Çetinkaya, Yasin. “Synthesis of Brominated Phenstatin Derivatives via Cerium (IV) Ammonium Nitrate / Lithium Bromide (CAN/LiBr) and Investigation With the Density Functional Theory (DFT)”. Sakarya University Journal of Science, vol. 21, no. 3, 2017, pp. 481-8, doi:10.16984/saufenbilder.270715.
Vancouver Çetinkaya Y. Synthesis of brominated phenstatin derivatives via cerium (IV) ammonium nitrate / lithium bromide (CAN/LiBr) and investigation with the density functional theory (DFT). SAUJS. 2017;21(3):481-8.

Cited By

AlCl3-Catalyzed Cascade Reactions of 1,2,3-Trimethoxybenzene and Adipoyl Chloride: Spectroscopic Investigations and Density Functional Theory Studies
ACS Omega
https://doi.org/10.1021/acsomega.2c04612

30930 This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.