THE EFFECT OF THE ROTATION ENERGİES OF H2+ MOLECULE ON THE Ne + H2+ --> NeH+ + H REACTION

Year 2018, , 1552 - 1558, 01.12.2018

Ezman Karabulut

https://doi.org/10.16984/saufenbilder.340849

Abstract

The noble gas atoms such
as He, Ne and Ar have significantly electronic ionization values around liquid
nitrogen temperature (at low temperature values). Because of this feature, the
noble gases which are used for some gas detectors, and which is related certain
chemical process occurring in the low temperature regions of atmosphere are
encouraged to be researched. The chemical reactions subjected to these noble
gas atoms have been believed to exhibit important behaviors at the same
temperature values. The investigation of their quantum effects in particular
energy range and the dependence on temperature of chemical reactions consisting
of atom-diatom molecular systems include the subject of reaction dynamics. The
title reaction has showed stable structure feature in the interaction region
which is the nearest inter-atomic distance. For this reason, it causes to be
examined of dynamic effects by depending on quantum states of initial hydrogen
ion. The contributions of angular behaviors of hydrogen ion related to total
angular momentum and the effects of these behaviors to reaction formations are
examined via three dimensional quantum mechanical methods. 

Keywords

Noble gas, Zero-point energy, Reaction probabilities, Angular momentum

H2+ MOLEKÜLÜNÜN DÖNME ENERJİLERİNİN Ne + H2+  NeH+ + H REAKSİYONU ÜZERİNDEKİ ETKİSİ

Abstract

He, Ne ve Ar gibi soy gaz atomları, sıvı nitrojen
sıcaklığında (düşük sıcaklık değerlerinde) önemli ölçüde elektronik iyonlaşma
değerlerine sahiptirler. Bu özellikten dolayı, bazı gaz detektörleri için
kullanılan ve atmosferin düşük sıcaklık bölgelerinde meydana gelen bazı
kimyasal süreçlerle ilgili asal gazlar araştırılmaya teşvik edilmektedir. Bu
soy gazlara konu olan kimyasal reaksiyonlar, aynı sıcaklık değerlerinde önemli
davranışlar sergilediği düşünülür. Belirli enerji aralığındaki kuantum
etkilerinin araştırılması ve atom- iki atom moleküler sistemlerinden oluşan
kimyasal reaksiyonların sıcaklığına bağımlılığının araştırılması, reaksiyon
dinamiği konusunu içerir. Başlık reaksiyonu, en yakın atomlar arası mesafedeki
etkileşim bölgesinde kararlı yapı özelliğini göstermiştir. Bu nedenle
başlangıçtaki hidrojen iyonunun kuantum durumlarına bağlı olarak dinamik
etkilerin incelenmesine neden olur. Toplam açısal momentum ile ilgili hidrojen
iyonunun açısal davranışlarının katkıları ve bu davranışların reaksiyon
oluşumlarına etkisi üç boyutlu kuantum mekanik yöntemlerle incelenmiştir.

Keywords

Soy gaz, Sıfır nokta enerjisi, Reaksiyon ihtimaliyetleri, Açısal momentum

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