Effect of Modifier Agents on Particle Size and Surface Functional Groups of Calcined Eggshell: Test in Adsorption of Remazol Yellow

Year 2020, , 272 - 280, 01.02.2020

Filiz Akti

https://doi.org/10.16984/saufenbilder.605170

Abstract

Calcined eggshell (CES) was modified with Pluronic 123 (P123), Pluronic 127 (F127) and polyethylene glycol
(PEG) agents and used in adsorption of Remazol Yellow. The adsorbents were
characterized by Fourier transform infrared (FTIR) and scanning electron
microscopy/energy dispersive X-ray spectroscopy (SEM/EDX). FTIR spectrums
showed that characteristic peaks corresponding to CES and modifier agents were
observed and CES was successfully modified. Modification of CES with PEG having
high chain length (or high molecular weight) was positively affected particle
size. From EDX analysis was determined the carbon
content increased from 21.44 % to 36.60 % whereas the calcium content decreased
from 21.23 % to 8.69 % with increasing of the molecular weight of modifier agents.
Removal percent of Remazol Yellow was found
as 91.79, 93.09 and 95.69 for CES-P123, CES-F127 and
CES-PEG, respectively. CES-PEG was adsorbed Remazol Yellow more than other adsorbents. Particle size and carbon
content of adsorbents was more effective in adsorption of Remazol Yellow.

Keywords

Calcined eggshell, modification, adsorption, Remazol Yellow

References

• [1] G.Z. Kyzas and M. Kostoglou, “Green Adsorbents for Wastewaters: A Critical Review,” Materials vol. 7, no. 1, pp. 333-364, 2014.
• [2] A. Khalid, R. Fozia, T.G.V. M. T. P. Cleo, T. G. Abdur R, L. S. Ana and A. Claudio, “Aluminum doped mesoporous silica SBA-15 for the removal of remazol yellow dye from water,” Microporous and Mesoporous Materials vol. 236, no. 1, pp. 167-175, 2016.
• [3] H. Weiwen, Y. Xuehua, H. Qiong, K. Jinming, L. Lianzhi and Z. Xueji, “Methyl Orange removal by a novel PEI-AuNPs-hemin nanocomposite,” Journal of Environmental Sciences vol. 53, no. 1, pp. 278-283, 2017.
• [4] F. Akti and M. Okur, “The Removal of Acid Violet 90 from Aqueous Solutions Using PANI and PANI/Clinoptilolite Composites: Isotherm and Kinetics,” Journal of Polymers and the Environment vol. 26, no. 11, pp. 4233-4242, 2018.
• [5] M. A. Al-Ghouti and N. R. Salih, “Application of eggshell wastes for boron remediation from water,” Journal of Molecular Liquids vol. 256, pp. 599–610, 2018.
• [6] P. S. Guru and S. Dash, “Sorption on eggshell waste-A review on ultrastructure, biomineralization and other applications,” Advances in Colloid and Interface Science vol. 209, pp. 49–67, 2014.
• [7] E. Altıntığ and Ö. F. Soydan, “Metheylene Blue Adsorption and Preparation Silver Bound to Activated Carbon with Sol-Gel Methods,” Sakarya University Journal of Science, vol. 22, no. 6, pp. 1812-1819, 2018.
• [8] M. Okur, F. Aktı and A. Çetintaş, “Polianilin/Aljinat Malzemesinin Asit Violet 90 Boyar Maddesinin Gideriminde Kullanılması: Kinetik ve İzoterm Değerlendirmesi,” GU J Sci, Part C, vol. 6 no. 4, pp.729-740, 2018.
• [9] L. Aref, A. H. Navarchian and D. Dadkhah, “Adsorption of Crystal Violet Dye from Aqueous Solution by Poly(Acrylamide-co-Maleic Acid)/Montmorillonite Nanocomposite,” Journal of Polymer and Environment, vol. 25, no. 3, pp. 628-639, 2017.
• [10] A. P. D. Gómez-Treviño, V. Martínez-Miranda, and M. Solache-Ríos, “Removal of remazol yellow from aqueous solutions by unmodified and stabilized iron modified clay,” Applied Clay Science vol. 80, pp. 219-225, 2013.
• [11] K. Rida, S. Bouraoui and S. Hadnine, “Adsorption of methylene blue from aqueous solution by kaolin and zeolite,” Applied Clay Science vol. 83–84, pp. 99–105, 2013.
• [12] M.F. Elkady, Amal M. Ibrahim and M.M. Abd El-Latif, “Assessment of the adsorption kinetics, equilibrium and thermodynamic for the potential removal of reactive red dye using eggshell biocomposite beads,” Desalination vol. 278, no. 1-3, pp. 412–423, 2011.
• [13] E. Panagiotou, N. Kafa, L. Koutsokeras, P. Kouis, P. Nikolaou, G. Constantinides and I. Vyrides, “Turning calcined waste egg shells and wastewater to Brushite:”Phosphorus adsorption from aqua media and anaerobic sludge leach water,” Journal of Cleaner Production vol. 178, pp. 419-428, 2018.
• [14] J. Trujillo-Reyes, V. Sánchez-Mendieta, M. J. Solache-Ríos and A. Colín-Cruz, “Removal of remazol yellow from aqueous solution using Fe–Cu and Fe–Ni nanoscale oxides and their carbonaceous composites,” Environmental Technology vol. 33, no. 5, pp. 545-554, 2012.
• [15] J. Torres-Pérez, M. Solache-Ríos and A. Colín-Cruz, “Sorption and desorption of dye remazol yellow onto a Mexican surfactant-modified clinoptilolite-rich tuff and a carbonaceous material from pirólisis of sewage sludge,” Water Air Soil Pollution vol. 187, no. 1-4, pp. 303-313, 2008.
• [16] A.R. Cestari, E. F. S. Vieira, G. S. Vieira and L. E. Almeida, “Aggregation and adsorption of reactive dyes in the presence of an anionic surfactant on mesoporous aminopropyl silica,” Journal of Colloid and Interface Science vol. 309, no. 2, pp. 402-411, 2007.
• [17] W. T. Tsai, J. M. Yang, C. W. Lai, Y. H. Cheng, C. C. Lin and C.W. Yeh, “ Characterization and adsorption properties of eggshells and eggshell membrane,” Bioresource Technology vol. 97, no. 3, pp. 488–493, 2006.
• [18] N. Tangboriboon, R. Kunanuruksapong and A. Sirivat, “Preparation and properties of calcium oxide from eggshells via calcination,” Materials Science-Poland, vol. 30, no .4, pp. 313-322, 2012.
• [19] O.A.A. Eletta, O.A. Ajayi, O.O. Ogunleyec, and I.C. Akpan, “Adsorption of cyanide from aqueous solution using calcinated eggshells: Equilibrium and optimisation studies,” Journal of Environmental Chemical Engineering vol. 4, no.1, pp. 1367–1375, 2016.
• [20] H. C. Öteyaka and M. Ö. Öteyaka, “Chemical and mechanical properties analysis of extruded polyvinyl choloride (PVC)/sepiolite composite,” Sakarya University Journal of Science vol. 23, no. 4, pp. 633-640, 2019