Azot ve fosforun negatif iyonlarının temel hallerinin ince yapı seviyeleri

Leyla Özdemir; Nurgül Atik; Gülay Günday Konan

doi:10.16984/saufbed.81654

Research Article

The fine structure levels for ground states of negative ions of nitrogen and phosphorus

Year 2013, Volume: 17 Issue: 1, 139 - 146, 01.04.2013

Leyla Özdemir Nurgül Atik Gülay Günday Konan

Abstract

The fine structure levels for negative ions (anions) of nitrogen and phosphorus have been investigated using multiconfiguration Hartree-Fock method within the framework of Breit-Pauli Hamiltonian (MCHF+BP). Nitrogen and phosphorus have half-filled outer shell in ground state 1s2s 2p S and 1s2s 2p 3s 3p S, respectively. It has been stated in most works that the negative ion of nitrogen is instable whereas the negative ion of phosphorus is stable. The results obtained have been compared with other works.

Keywords

MCHF method, Breit-Pauli Hamiltonian, electron affinity, fine structure levels

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