Research Article
BibTex RIS Cite

Synthesis and the Spectral Investigations of Spiro, Ansa and Bridged Derivatives of Cyclochlorotriphosphazenes

Year 2011, Volume: 15 Issue: 2, 113 - 120, 01.12.2011

Abstract

-

References

  • Part 63. W. F. Deutsch and R. A. Shaw, Phosphorus
  • Sulphur Silicon, 1990, 47, 119. [2]. A. H. Alkubaisi, H. G. Parkes and R. A. Shaw, Heterocycles, 1989, 28, 347.
  • A. J. Kirby, Advances in Physical Organic Chemistry, vol. 17, pp. 208. (eds. V. Gold and D. Bethell) 1980, Academic Press, London, New York, Toronto.
  • W. C. Still, M. Kahn, and A. Milton, J. Org. Chem. 1978, 43, 2923.
  • T. Chivers and C. Hedgeland, Can J. Chem., 1972, 50, 1017.
  • V. Chandrasekhar, S. Khartikeyan, S. S. Krisnamurthy and M. Woods, Indian J. Chem. Soc., 1985, 24A, 379.
  • P. Castera, J. P. Faucher, M. R. Granier and J. F. Labarre, Phosphorus Sulfur, 1987, 32, 37.
  • S. Beşli, S. J. Coles, D. B. Davies, A. O. Erkovan, M. B. Hursthouse and A. Kılıç, Polyhedron, 2009, 28,3593.s
  • E. Tanrıverdi, A. Kılıç, S. Harbeck, and G. Y. Çiftçi, Heterocycles, 2009, 78, 2277.
  • H. İbişoğlu, G. Y. Çiftçi, A. Kılıç, E. Tanrıverdi, İ. Ün, H. Dal and T.Hökelek, J. Chem.Soc., 2009, 121(2), 125. [11]. S. Beşli, S. J. Coles, D. B. Davies, A. O. Erkovan, M. B. Hursthouse and A. Kılıç, Inorganic Chemistry, 2008, 47, 5042.
  • S. Beşli, S. J. Coles, D. B. Davies, M. B. Hursthouse, A. Kılıç and R. A. Shaw,Dalton Trans., 2007, 26, 2792.
  • S. Beşli, S. J. Coles, D. Davarcı, D. B. Davies, M. B. Hursthouse and A. Kılıç, Polyhedron, 2007, 26, 5283.

Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları.

Year 2011, Volume: 15 Issue: 2, 113 - 120, 01.12.2011

Abstract

The reactions of hexachlorocyclotriphosphazatriene, N3P3Cl6 (1) with 2,2-dimethylpropane-1,3-diol yield 9 new cyclophosphazene derivatives. One monospiro, N3P3Cl4[(OCH2)2-CMe2], dispiro, N3P3Cl2[(OCH2)2-CMe2]2 and tris-spiro N3P3[(OCH2)2-CMe2]3 derivatives. An ansa, N3P3Cl4[(OCH2)2-CMe2], and a spiro-ansa, N3P3Cl2[(OCH2)2-CMe2]2 isomers. One dangling, N3P3Cl5[(OCH2)2-CMe2OH], one singly-bridged, N3P3Cl5[(OCH2)2-CMe2] N3P3Cl5, one doubly-bridged, N3P3Cl4[(OCH2)2-CMe2]2N3P3Cl4, and one triple-bridged compounds, N3P3Cl3[(OCH2)2-CMe2]2N3P3Cl3 were also isolated. Product types and relative yields were compared with those arising from propane-1,3-diol. The yields of the spiro, ansa and the bridged products from the reactions of the dimethylpropane-diol system seem to be considerably enhanced relative to those of its unmethylated analogue. The structures of the compounds were determined by using the data obtained from 31P, 1H and 13C N.M.R.

References

  • Part 63. W. F. Deutsch and R. A. Shaw, Phosphorus
  • Sulphur Silicon, 1990, 47, 119. [2]. A. H. Alkubaisi, H. G. Parkes and R. A. Shaw, Heterocycles, 1989, 28, 347.
  • A. J. Kirby, Advances in Physical Organic Chemistry, vol. 17, pp. 208. (eds. V. Gold and D. Bethell) 1980, Academic Press, London, New York, Toronto.
  • W. C. Still, M. Kahn, and A. Milton, J. Org. Chem. 1978, 43, 2923.
  • T. Chivers and C. Hedgeland, Can J. Chem., 1972, 50, 1017.
  • V. Chandrasekhar, S. Khartikeyan, S. S. Krisnamurthy and M. Woods, Indian J. Chem. Soc., 1985, 24A, 379.
  • P. Castera, J. P. Faucher, M. R. Granier and J. F. Labarre, Phosphorus Sulfur, 1987, 32, 37.
  • S. Beşli, S. J. Coles, D. B. Davies, A. O. Erkovan, M. B. Hursthouse and A. Kılıç, Polyhedron, 2009, 28,3593.s
  • E. Tanrıverdi, A. Kılıç, S. Harbeck, and G. Y. Çiftçi, Heterocycles, 2009, 78, 2277.
  • H. İbişoğlu, G. Y. Çiftçi, A. Kılıç, E. Tanrıverdi, İ. Ün, H. Dal and T.Hökelek, J. Chem.Soc., 2009, 121(2), 125. [11]. S. Beşli, S. J. Coles, D. B. Davies, A. O. Erkovan, M. B. Hursthouse and A. Kılıç, Inorganic Chemistry, 2008, 47, 5042.
  • S. Beşli, S. J. Coles, D. B. Davies, M. B. Hursthouse, A. Kılıç and R. A. Shaw,Dalton Trans., 2007, 26, 2792.
  • S. Beşli, S. J. Coles, D. Davarcı, D. B. Davies, M. B. Hursthouse and A. Kılıç, Polyhedron, 2007, 26, 5283.
There are 12 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Research Articles
Authors

Sedat Ture This is me

Publication Date December 1, 2011
Submission Date March 14, 2014
Published in Issue Year 2011 Volume: 15 Issue: 2

Cite

APA Ture, S. (2011). Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları. Sakarya University Journal of Science, 15(2), 113-120. https://doi.org/10.16984/saufbed.95105
AMA Ture S. Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları. SAUJS. December 2011;15(2):113-120. doi:10.16984/saufbed.95105
Chicago Ture, Sedat. “ Ansa Ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri Ve Spectroskopik Araştırmaları”. Sakarya University Journal of Science 15, no. 2 (December 2011): 113-20. https://doi.org/10.16984/saufbed.95105.
EndNote Ture S (December 1, 2011) Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları. Sakarya University Journal of Science 15 2 113–120.
IEEE S. Ture, “ Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları”., SAUJS, vol. 15, no. 2, pp. 113–120, 2011, doi: 10.16984/saufbed.95105.
ISNAD Ture, Sedat. “ Ansa Ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri Ve Spectroskopik Araştırmaları”. Sakarya University Journal of Science 15/2 (December 2011), 113-120. https://doi.org/10.16984/saufbed.95105.
JAMA Ture S. Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları. SAUJS. 2011;15:113–120.
MLA Ture, Sedat. “ Ansa Ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri Ve Spectroskopik Araştırmaları”. Sakarya University Journal of Science, vol. 15, no. 2, 2011, pp. 113-20, doi:10.16984/saufbed.95105.
Vancouver Ture S. Spiro, Ansa ve Bino Sikloklorotrifosfazen Türevlerinin Sentezleri ve Spectroskopik Araştırmaları. SAUJS. 2011;15(2):113-20.