Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry

Nalan Tekin; Mustafa Cebe

Research Article

Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry

Year 2003, Volume: 7 Issue: 3, 132 - 136, 01.09.2003

Abstract

Bu çalışmada, dissosiasyon ortamında okzalik asit çözeltilerinin · sıcaklık ve konsantrasyon ile dissosiasyon özelliklerinin değişimi UV-VIS Spektrofotometrik yöntem ile incelenmiştir. Her çözelti sistemi için, farklı sıcaklıklarda konsantrasyon, c, ve absorbans, A, arasındaki ilişkiler belirlenmiştir. Elde edilen sonuçlar, etil alkol, n-propil alkol, iso-propil alkol and N,N-dimetilformamid çözücüleriyle hazırlanan çözeltiler için Lambert-Beer yasasının sırasıyla l.00xl0"2M ile 6.25xl0-4M; 1.00x10"2M ile 6.25x10·4M; 3.00xıo·3M ile l.875x10-4M; 3.00xl0"2M ile 1.875x10"3M derişim aralıklarında geçerli olduğunu göstermiştir. Çözeltilerin molar sönüm katsayıları Lambert-Beer kanunu yardımıyla hesaplanmıştır. Her çözelti sistemi için molar sönüm katsayısının sıcaklık bağımlılığı belirlenmiştir.

Keywords

UV-spektroskopisi, molar sönüm katsayısı, okzalik asit, dissosiasyon

References

[1]. C.N.R. Rao, Ultraviolet and Visible Spectroscopy (Bulerworhs, Landon, 1961),pp. 1-20.
[2]. J.N. Murrel, The Theory of the Electronic Spect 1 of Organic Molecules (Methuen, London, 1963), pp.4- 18.
[3].E.S., Stern., T.C.J. Timrnons, Electronic Absorbtion Spectroscopy in Organic Chemistry (StMartin's Press : NewYork, 1971), pp. 5-10.
[4]. D. H. Williarns, I. Fleming, Spectroscopic Methods in Organic Chernistry (Fourth Edition, Mc. Graw-Hill Book company, Europe, 1989), pp. 1-29.
[5]. C.M.J. Brands, B.L. Wedzicha, M.A.J.S. van Boekel, Intemational Congress Series, 1245, 249-253, (2002).
[6]. G.K.Sandhu, K.Singh, B.S. Lark, L. Gerward, RadiationPhys. And Chem. 65, 211-215, (2002).
[7]. G.M. Barrow, Physical Cheınistry (Fifty Edition, McGraw-Hill, London, 1988), pp. 541-549
[8]. S.A. Grebenyuk, I. F. Perepichka, A. F. Popov, Spectrochımıca acta Part A 58, 2913-2923, (2002).
[9]. Skoog/Leary, Principles of lnstrumental Analysis (Fourth Edition, Saunders College Publishing, Saunders, 1992), pp. 1-28.
[10]. H.H. Perkampus, UV-VIS Spectroscopy and Its Applications (Springer-Verlag Berlin Heidelberg, Springer Laboratory, 1992), pp.3-24.
[11]. F.F. Fenter, V.Catoire, R. Lesclaux and P. D. Lightfoot, J. Phys. Chem 97, 3530-3538, (1993).
[12]. M.Schwell, N.K Wachter, J.H. Rice, J.P. Galaup, S.Leach, R.Taylor, R.V. Bensasson, Chem. Phys. Lett. 339, 29-35, (2001).
[13]. N. Tekin, "Bazı Molekülsel Sistemlerin Dissosiasyon Özelliklerinin İnceleıunesi", Uludağ Üniversitesi, Fen-Bilimleri Enstitüsü, Bursa, 1997.

Year 2003, Volume: 7 Issue: 3, 132 - 136, 01.09.2003

Nalan Tekin Mustafa Cebe

Abstract

References

[1]. C.N.R. Rao, Ultraviolet and Visible Spectroscopy (Bulerworhs, Landon, 1961),pp. 1-20.
[2]. J.N. Murrel, The Theory of the Electronic Spect 1 of Organic Molecules (Methuen, London, 1963), pp.4- 18.
[3].E.S., Stern., T.C.J. Timrnons, Electronic Absorbtion Spectroscopy in Organic Chemistry (StMartin's Press : NewYork, 1971), pp. 5-10.
[4]. D. H. Williarns, I. Fleming, Spectroscopic Methods in Organic Chernistry (Fourth Edition, Mc. Graw-Hill Book company, Europe, 1989), pp. 1-29.
[5]. C.M.J. Brands, B.L. Wedzicha, M.A.J.S. van Boekel, Intemational Congress Series, 1245, 249-253, (2002).
[6]. G.K.Sandhu, K.Singh, B.S. Lark, L. Gerward, RadiationPhys. And Chem. 65, 211-215, (2002).
[7]. G.M. Barrow, Physical Cheınistry (Fifty Edition, McGraw-Hill, London, 1988), pp. 541-549
[8]. S.A. Grebenyuk, I. F. Perepichka, A. F. Popov, Spectrochımıca acta Part A 58, 2913-2923, (2002).
[9]. Skoog/Leary, Principles of lnstrumental Analysis (Fourth Edition, Saunders College Publishing, Saunders, 1992), pp. 1-28.
[10]. H.H. Perkampus, UV-VIS Spectroscopy and Its Applications (Springer-Verlag Berlin Heidelberg, Springer Laboratory, 1992), pp.3-24.
[11]. F.F. Fenter, V.Catoire, R. Lesclaux and P. D. Lightfoot, J. Phys. Chem 97, 3530-3538, (1993).
[12]. M.Schwell, N.K Wachter, J.H. Rice, J.P. Galaup, S.Leach, R.Taylor, R.V. Bensasson, Chem. Phys. Lett. 339, 29-35, (2001).
[13]. N. Tekin, "Bazı Molekülsel Sistemlerin Dissosiasyon Özelliklerinin İnceleıunesi", Uludağ Üniversitesi, Fen-Bilimleri Enstitüsü, Bursa, 1997.

There are 13 citations in total.

Details

Subjects	Engineering
Journal Section	Research Articles
Authors	Nalan Tekin This is me Mustafa Cebe This is me
Publication Date	September 1, 2003
Submission Date	January 1, 2003
Acceptance Date	April 1, 2003
Published in Issue	Year 2003 Volume: 7 Issue: 3

Cite

APA	Tekin, N., & Cebe, M. (2003). Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry. Sakarya University Journal of Science, 7(3), 132-136.
AMA	Tekin N, Cebe M. Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry. SAUJS. December 2003;7(3):132-136.
Chicago	Tekin, Nalan, and Mustafa Cebe. “Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry”. Sakarya University Journal of Science 7, no. 3 (December 2003): 132-36.
EndNote	Tekin N, Cebe M (December 1, 2003) Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry. Sakarya University Journal of Science 7 3 132–136.
IEEE	N. Tekin and M. Cebe, “Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry”, SAUJS, vol. 7, no. 3, pp. 132–136, 2003.
ISNAD	Tekin, Nalan - Cebe, Mustafa. “Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry”. Sakarya University Journal of Science 7/3 (December 2003), 132-136.
JAMA	Tekin N, Cebe M. Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry. SAUJS. 2003;7:132–136.
MLA	Tekin, Nalan and Mustafa Cebe. “Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry”. Sakarya University Journal of Science, vol. 7, no. 3, 2003, pp. 132-6.
Vancouver	Tekin N, Cebe M. Measurement Of The Spectroscopic Properties Of Oxalic Acid-Solvent Systems By Uv-Spectrophotometry. SAUJS. 2003;7(3):132-6.