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Tekstil atık sularından C.I. Bazik Mavi 3 boyarmaddesinin elektrokimyasal uygulama ile giderilmesi

Year 2016, Volume: 20 Issue: 3, 521 - 531, 02.09.2016

Emrah Bulut

https://doi.org/10.16984/saufenbilder.85559

Abstract

Tekstil boyama endüstrisinde kullanılan Bazik Mavi 3 boyarmaddesinin alüminyum elektrot kullanılarak elektrokimyasal olarak tekstil atık sularından giderimi üzerinde çalışılmıştır. Kesikli proses ile yapılan deneyler sonrasında 10 dakika sonunda pH8 değerinde %97’den fazla giderim etkinliği hesaplanmıştır. Elektrokimyasal işlemin 6. dakikası sonunda 50-400 mg/L aralığındaki konsantrasyonlardaki boya giderim etkinliği %92-95 arasında değişirken bu oran, 500 ve 600 mg/L için sırasıyla %72 ve %60 olarak hesaplanmıştır. 10. dakika sonunda ise bütün konsantrasyon değerlerindeki boya giderim oranı %96 civarındadır. Akım yoğunluğu değerlendirildiğinde ise boya giderim etkinliği 333 A/m2 akım yoğunluğu ile 4. dakikadan sonra (%96) işlem bitene kadar çok fazla bir artış göstermemiş ve 10. dakikada %97 seviyesine ulaşmıştır.

Keywords

elektrokoagülasyon tekstil atık suları bazik mavi 3 alüminyum elektrot

References

  • T. H. Kim, C. Park, J. Yang ve S. Kim, «Comparison of disperse and reactive dye removals by chemical coagulation and Fenton oxidation,» J. Hazard. Mater., cilt 112, pp. 95-103, 2004.
  • I. D. Mall, V. C. Srivastava, N. K. Agarwal ve I. M. Mishra, «Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses,» Colloids Surf., A: Physicochem. Eng. Aspects, cilt 264, pp. 17-28, 2005.
  • S. Singh, V. C. Srivastava ve I. D. Mall, «Multistep optimization and residue disposal study for electrochemical treatment of textile wastewater using aluminum electrode,» Int. J. Chem. React. Eng., cilt 11, pp. 1-16, 2013.
  • L. Szpyrkowicz, C. Juzzolino ve S. N. Kaul, «A comparative study on oxidation of disperses dyes by electrochemical process, ozone, hypochlorite and Fenton Reagent,» Water Res., cilt 35, pp. 2129-2136, 2001.
  • C. Wu, Y. Wang, B. Gao, Y. Zhao ve Q. Yue, «Coagulation performance and floc characteristics of aluminum sulfate using sodium alginate as coagulant aid for synthetic dying wastewater treatment,» Sep.Purif. Technol., cilt 95, pp. 180-187, 2012.
  • K. Marungrueng ve P. Pavasant, «Removal of basic dye (Astrazon Blue FGRL) using macroalga Caulerpa lentillifera,» J. Environ. Manage, cilt 78, pp. 268-274, 2006.
  • C. Hessel, C. Allegre, M. Maisseu, F. Charbit ve P. Moulin, «Guidelines and legislation for dye house effluents,» J. Environ. Manage, cilt 83, pp. 171-180, 2007.
  • I. Tan, B. Hameed ve A. Ahmad, «Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon,» Chem. Eng. J., cilt 127, pp. 111-119, 2007.
  • H. Chu ve K. Chen, «Reuse of activated sludge biomass: I. Removal of basic dyes from wastewater biomass,» Process Biochem., cilt 37, pp. 595-600, 2002.
  • X. J. Zhou, W. Q. Guo, S. S. Yang ve N. Q. Ren, «A Rapid and Low Energy Consumption Method to Decolorize the High Concentration Triphenylmethane Dye Wastewater: Operational Parameters Optimization for the Ultrasonic-Assisted Ozone Oxidation Process,» Biores. Technol., cilt 105, pp. 40-47, 2012.
  • M. L. Marin, L. Santos-Juanes, A. Arques, A. M. Amat ve M. A. Miranda, «Organic Photocatalysts for the Oxidation of Pollutants and Model Compounds,» Chem. Rev., cilt 112, pp. 1710-1750, 2012.
  • C. Chen ve C. Lu, «Photocatalytic Degradation of Basic Violet 4: Degradation Efficiency, Product Distribution, and Mechanisms,» J. Phys. Chem. C, cilt 111, pp. 13922-13932, 2007.
  • S. Huo ve X. −. Yan, «Metal−Organic Frame Work MIL-100 (Fe) for the Adsorption of Malachite Green from Aqueous Solution,» J. Mater. Chem., cilt 2, pp. 7449-7455, 2012.
  • I. Ali, «New Generation Adsorbents for Water Treatment,» Chem. Rev., cilt 112, pp. 5073-5091, 2012.
  • S. Deng, Q. Zhou, G. Yu, J. Huang ve Q. Fan, «Removal of Perfluorooctanoate from Surface Water by Polyaluminium Chloride Coagulation,» Water Res., cilt 45, pp. 1774-1780, 2011.
  • M. Minhalma ve M. N. De Pinho, «Flocculation/Flotation/Ultrafiltration Integrated Process for the Treatment of Cork Processing Wastewaters,» Environ. Sci. Technol., cilt 35, pp. 4916-4921, 2001.
  • M. Huan, L. Lian−Tai, Y. Cai−Fang, S. Jin-Jin, H. Q. Yuan−Gao ve L. Shun−Peng, «Biodegradation of Malachite Green by Strain Pseudomonas sp. K9 and Cloning of the tmr2 Gene Associated with an ISPpu12,» World J. Microbiol. Biotechnol., cilt 27, pp. 1323-1329, 2011.
  • C. Chen, J. Kuo, C. Chen, Y. Huang, I. Hob ve Y. Chung, «Biological Decolorization of Dye Solution Containing Malachite Green by Pandoraea Pulmonicola YC32 Using a Batch and Continuous System,» J. Hazard. Mater., cilt 172, pp. 1439-1445, 2009.
  • J. Gregory ve J. Duan, «Hydrolyzing metal salts as coagulants,» Pure Appl. Chem., cilt 73, pp. 2017-2026, 2001.
  • J. Duan ve J. Gregory, «Coagulation by hydrolysing metal salts.,» Adv. Colloid Interface Sci., cilt 100, pp. 475-502, 2003.
  • P. Can˜izares, F. Martinez, J. Garcia-Gomez, C. Saez ve M. A. Rodrigo, «Combined electrooxidation and assisted electrochemical coagulation of aqueous phenol wastes,» J. Appl. Electrochem., cilt 32, pp. 1241-1246, 2002.
  • P. Can˜izares, F. Martinez, M. Diaz, J. Garcia-Gomez ve M. A. Rodrigo, «Electrochemical Oxidation of Aqueous Phenol Wastes Using Active and Nonactive Electrodes,» J. Electrochem. Soc., cilt 149, pp. D118-D124, 2002.
  • F. Y. Yu, C. W. Li ve S. F. Kang, «Color, dye and doc removal, and acid generation during fenton oxidation of dyes,» EnViron. Technol., cilt 26, pp. 537-544, 2005.
  • B. Mondal, V. C. Srivastava ve I. D. Mall, «lectrochemical treatment of textile printing wastewater by stainless steel electrodes: multiple response optimization and residue analysis,» J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., cilt 47, pp. 2040-2051, 2012.
  • S. Singh, V. C. Srivastava ve I. D. Mall, «Mechanistic study of electrochemical treatment of basic green 4 dye with aluminum electrodes through zeta potential, TOC, COD and color measurements, and characterization of residues,» RSC Adv., cilt 3, pp. 16426-16439, 2013.
  • M. Panizza ve G. Cerisola, «Direct and Mediated Anodic Oxidation of Organic Pollutants,» Chem. Rev., cilt 109, pp. 6541-6569, 2009.
  • S. S. Vaghela, A. D. Jethva, B. B. Mehta, S. P. Dave, S. Adimurthy ve G. Ramachandraiah, «Laboratory Studies of Electrochemical Treatment of Industrial Azo Dye Effluent,» Environ. Sci. Technol., cilt 39, pp. 2848-2855, 2005.
  • M. Panizza ve G. Cerisola, «Application of Diamond Electrodes to Electrochemical Processes,» Electrochim. Acta, cilt 51, pp. 191-199, 2005.
  • C. A. Martinez−Huitle ve S. Ferro, «Electrochemical Oxidation of Organic Pollutants for the Wastewater Treatment: Direct and Indirect Processes,» Chem. Soc. Rev., cilt 35, pp. 1324-1340, 2006.
  • G. B. Raju, M. T. Karuppiah, S. S. Latha, S. Parvathy ve S. Prabhakar, «Treatment of Wastewater from Synthetic Textile Industry by Electrocoagulation−Electrooxidation,» Chem. Eng. J., cilt 144, pp. 51-58, 2008.
  • J. P. Kushwaha, V. C. Srivastava ve I. D. Mall, «Studies on Electrochemical Treatment of Dairy Wastewater Using Aluminum Electrode,» AIChE J., cilt 57, pp. 2589-2598, 2011.
  • J. D. Rodgers, W. Jedral ve N. J. Bunce, «Electrochemical Oxidation of Chlorinated Phenols,» Environ. Sci. Technol., cilt 33, pp. 1453-1457, 1999.
  • B. Mondal, V. C. Srivastava, J. P. Kushwaha, R. Bhatnagar, S. Singh ve I. D. Mall, «Parametric and Multiple Response Optimization for the Electrochemical Treatment of Textile Printing Dye-Bath Effluent,» Sep. Purif. Technol., cilt 109, pp. 135-143, 2013.
  • E. Yuksel, M. Eyvaz ve E. Gurbulak, «Electrochemical treatment of colour index reactive orange 84 and textile wastewater by using stainless steel and iron electrodes,» Environ. Prog. Sustainable Energy, cilt 32, pp. 60-68, 2013.
  • F. Akbal ve A. Kuleyin, «Decolorization of levafix brilliant blue e-b by electrocoagulation method,» Environ. Prog. Sustainable Energy, cilt 30, pp. 29-36, 2011.
  • J. Duan ve J. Gregory, «Coagulation by hydrolysing metal salts,» Adv. Colloid Interface Sci., cilt 100, p. 475, 2003.

Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment

Year 2016, Volume: 20 Issue: 3, 521 - 531, 02.09.2016

Emrah Bulut

https://doi.org/10.16984/saufenbilder.85559

Abstract

The present study investigates the electrochemical treatment of Basic Blue 3 dyestuff from the textile waste waters. We achieved more than 97% color removal with pH8 after 10 minutes. In terms of initial dye concentrations, 92-95%, 72 and 60% dye removal efficiencies were obtained in 6 minutes for 50-400 mg/L, 500 and 600 mg/L initial dye concentrations respectively. In 10 minutes removing efficiencies became 96% for all the concentrations. When we consider the current density parameter, 96% removal efficiency was obtained with 333 A/m2 current density in 4 minutes respectively. However the removal efficiency only increases to 97% in 10 minutes.

Keywords

electrocoagulation textile waste waters basic blue 3 aluminum electrode

References

  • T. H. Kim, C. Park, J. Yang ve S. Kim, «Comparison of disperse and reactive dye removals by chemical coagulation and Fenton oxidation,» J. Hazard. Mater., cilt 112, pp. 95-103, 2004.
  • I. D. Mall, V. C. Srivastava, N. K. Agarwal ve I. M. Mishra, «Adsorptive removal of malachite green dye from aqueous solution by bagasse fly ash and activated carbon-kinetic study and equilibrium isotherm analyses,» Colloids Surf., A: Physicochem. Eng. Aspects, cilt 264, pp. 17-28, 2005.
  • S. Singh, V. C. Srivastava ve I. D. Mall, «Multistep optimization and residue disposal study for electrochemical treatment of textile wastewater using aluminum electrode,» Int. J. Chem. React. Eng., cilt 11, pp. 1-16, 2013.
  • L. Szpyrkowicz, C. Juzzolino ve S. N. Kaul, «A comparative study on oxidation of disperses dyes by electrochemical process, ozone, hypochlorite and Fenton Reagent,» Water Res., cilt 35, pp. 2129-2136, 2001.
  • C. Wu, Y. Wang, B. Gao, Y. Zhao ve Q. Yue, «Coagulation performance and floc characteristics of aluminum sulfate using sodium alginate as coagulant aid for synthetic dying wastewater treatment,» Sep.Purif. Technol., cilt 95, pp. 180-187, 2012.
  • K. Marungrueng ve P. Pavasant, «Removal of basic dye (Astrazon Blue FGRL) using macroalga Caulerpa lentillifera,» J. Environ. Manage, cilt 78, pp. 268-274, 2006.
  • C. Hessel, C. Allegre, M. Maisseu, F. Charbit ve P. Moulin, «Guidelines and legislation for dye house effluents,» J. Environ. Manage, cilt 83, pp. 171-180, 2007.
  • I. Tan, B. Hameed ve A. Ahmad, «Equilibrium and kinetic studies on basic dye adsorption by oil palm fibre activated carbon,» Chem. Eng. J., cilt 127, pp. 111-119, 2007.
  • H. Chu ve K. Chen, «Reuse of activated sludge biomass: I. Removal of basic dyes from wastewater biomass,» Process Biochem., cilt 37, pp. 595-600, 2002.
  • X. J. Zhou, W. Q. Guo, S. S. Yang ve N. Q. Ren, «A Rapid and Low Energy Consumption Method to Decolorize the High Concentration Triphenylmethane Dye Wastewater: Operational Parameters Optimization for the Ultrasonic-Assisted Ozone Oxidation Process,» Biores. Technol., cilt 105, pp. 40-47, 2012.
  • M. L. Marin, L. Santos-Juanes, A. Arques, A. M. Amat ve M. A. Miranda, «Organic Photocatalysts for the Oxidation of Pollutants and Model Compounds,» Chem. Rev., cilt 112, pp. 1710-1750, 2012.
  • C. Chen ve C. Lu, «Photocatalytic Degradation of Basic Violet 4: Degradation Efficiency, Product Distribution, and Mechanisms,» J. Phys. Chem. C, cilt 111, pp. 13922-13932, 2007.
  • S. Huo ve X. −. Yan, «Metal−Organic Frame Work MIL-100 (Fe) for the Adsorption of Malachite Green from Aqueous Solution,» J. Mater. Chem., cilt 2, pp. 7449-7455, 2012.
  • I. Ali, «New Generation Adsorbents for Water Treatment,» Chem. Rev., cilt 112, pp. 5073-5091, 2012.
  • S. Deng, Q. Zhou, G. Yu, J. Huang ve Q. Fan, «Removal of Perfluorooctanoate from Surface Water by Polyaluminium Chloride Coagulation,» Water Res., cilt 45, pp. 1774-1780, 2011.
  • M. Minhalma ve M. N. De Pinho, «Flocculation/Flotation/Ultrafiltration Integrated Process for the Treatment of Cork Processing Wastewaters,» Environ. Sci. Technol., cilt 35, pp. 4916-4921, 2001.
  • M. Huan, L. Lian−Tai, Y. Cai−Fang, S. Jin-Jin, H. Q. Yuan−Gao ve L. Shun−Peng, «Biodegradation of Malachite Green by Strain Pseudomonas sp. K9 and Cloning of the tmr2 Gene Associated with an ISPpu12,» World J. Microbiol. Biotechnol., cilt 27, pp. 1323-1329, 2011.
  • C. Chen, J. Kuo, C. Chen, Y. Huang, I. Hob ve Y. Chung, «Biological Decolorization of Dye Solution Containing Malachite Green by Pandoraea Pulmonicola YC32 Using a Batch and Continuous System,» J. Hazard. Mater., cilt 172, pp. 1439-1445, 2009.
  • J. Gregory ve J. Duan, «Hydrolyzing metal salts as coagulants,» Pure Appl. Chem., cilt 73, pp. 2017-2026, 2001.
  • J. Duan ve J. Gregory, «Coagulation by hydrolysing metal salts.,» Adv. Colloid Interface Sci., cilt 100, pp. 475-502, 2003.
  • P. Can˜izares, F. Martinez, J. Garcia-Gomez, C. Saez ve M. A. Rodrigo, «Combined electrooxidation and assisted electrochemical coagulation of aqueous phenol wastes,» J. Appl. Electrochem., cilt 32, pp. 1241-1246, 2002.
  • P. Can˜izares, F. Martinez, M. Diaz, J. Garcia-Gomez ve M. A. Rodrigo, «Electrochemical Oxidation of Aqueous Phenol Wastes Using Active and Nonactive Electrodes,» J. Electrochem. Soc., cilt 149, pp. D118-D124, 2002.
  • F. Y. Yu, C. W. Li ve S. F. Kang, «Color, dye and doc removal, and acid generation during fenton oxidation of dyes,» EnViron. Technol., cilt 26, pp. 537-544, 2005.
  • B. Mondal, V. C. Srivastava ve I. D. Mall, «lectrochemical treatment of textile printing wastewater by stainless steel electrodes: multiple response optimization and residue analysis,» J. Environ. Sci. Health, Part A: Toxic/Hazard. Subst. Environ. Eng., cilt 47, pp. 2040-2051, 2012.
  • S. Singh, V. C. Srivastava ve I. D. Mall, «Mechanistic study of electrochemical treatment of basic green 4 dye with aluminum electrodes through zeta potential, TOC, COD and color measurements, and characterization of residues,» RSC Adv., cilt 3, pp. 16426-16439, 2013.
  • M. Panizza ve G. Cerisola, «Direct and Mediated Anodic Oxidation of Organic Pollutants,» Chem. Rev., cilt 109, pp. 6541-6569, 2009.
  • S. S. Vaghela, A. D. Jethva, B. B. Mehta, S. P. Dave, S. Adimurthy ve G. Ramachandraiah, «Laboratory Studies of Electrochemical Treatment of Industrial Azo Dye Effluent,» Environ. Sci. Technol., cilt 39, pp. 2848-2855, 2005.
  • M. Panizza ve G. Cerisola, «Application of Diamond Electrodes to Electrochemical Processes,» Electrochim. Acta, cilt 51, pp. 191-199, 2005.
  • C. A. Martinez−Huitle ve S. Ferro, «Electrochemical Oxidation of Organic Pollutants for the Wastewater Treatment: Direct and Indirect Processes,» Chem. Soc. Rev., cilt 35, pp. 1324-1340, 2006.
  • G. B. Raju, M. T. Karuppiah, S. S. Latha, S. Parvathy ve S. Prabhakar, «Treatment of Wastewater from Synthetic Textile Industry by Electrocoagulation−Electrooxidation,» Chem. Eng. J., cilt 144, pp. 51-58, 2008.
  • J. P. Kushwaha, V. C. Srivastava ve I. D. Mall, «Studies on Electrochemical Treatment of Dairy Wastewater Using Aluminum Electrode,» AIChE J., cilt 57, pp. 2589-2598, 2011.
  • J. D. Rodgers, W. Jedral ve N. J. Bunce, «Electrochemical Oxidation of Chlorinated Phenols,» Environ. Sci. Technol., cilt 33, pp. 1453-1457, 1999.
  • B. Mondal, V. C. Srivastava, J. P. Kushwaha, R. Bhatnagar, S. Singh ve I. D. Mall, «Parametric and Multiple Response Optimization for the Electrochemical Treatment of Textile Printing Dye-Bath Effluent,» Sep. Purif. Technol., cilt 109, pp. 135-143, 2013.
  • E. Yuksel, M. Eyvaz ve E. Gurbulak, «Electrochemical treatment of colour index reactive orange 84 and textile wastewater by using stainless steel and iron electrodes,» Environ. Prog. Sustainable Energy, cilt 32, pp. 60-68, 2013.
  • F. Akbal ve A. Kuleyin, «Decolorization of levafix brilliant blue e-b by electrocoagulation method,» Environ. Prog. Sustainable Energy, cilt 30, pp. 29-36, 2011.
  • J. Duan ve J. Gregory, «Coagulation by hydrolysing metal salts,» Adv. Colloid Interface Sci., cilt 100, p. 475, 2003.
There are 36 citations in total.

Details

Journal Section Research Articles
Authors

Emrah Bulut

Publication Date September 2, 2016
Submission Date May 30, 2016
Published in Issue Year 2016 Volume: 20 Issue: 3

Cite

APA Bulut, E. (2016). Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment. Sakarya University Journal of Science, 20(3), 521-531. https://doi.org/10.16984/saufenbilder.85559
AMA Bulut E. Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment. SAUJS. November 2016;20(3):521-531. doi:10.16984/saufenbilder.85559
Chicago Bulut, Emrah. “Removal of C.I. Basic Blue 3 Dyestuff from Textile Waste Waters by Electrochemical Treatment”. Sakarya University Journal of Science 20, no. 3 (November 2016): 521-31. https://doi.org/10.16984/saufenbilder.85559.
EndNote Bulut E (November 1, 2016) Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment. Sakarya University Journal of Science 20 3 521–531.
IEEE E. Bulut, “Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment”, SAUJS, vol. 20, no. 3, pp. 521–531, 2016, doi: 10.16984/saufenbilder.85559.
ISNAD Bulut, Emrah. “Removal of C.I. Basic Blue 3 Dyestuff from Textile Waste Waters by Electrochemical Treatment”. Sakarya University Journal of Science 20/3 (November 2016), 521-531. https://doi.org/10.16984/saufenbilder.85559.
JAMA Bulut E. Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment. SAUJS. 2016;20:521–531.
MLA Bulut, Emrah. “Removal of C.I. Basic Blue 3 Dyestuff from Textile Waste Waters by Electrochemical Treatment”. Sakarya University Journal of Science, vol. 20, no. 3, 2016, pp. 521-3, doi:10.16984/saufenbilder.85559.
Vancouver Bulut E. Removal of C.I. Basic Blue 3 dyestuff from textile waste waters by electrochemical treatment. SAUJS. 2016;20(3):521-3.

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