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SILAR yöntemi ile büyütülen katkısız ve Zn katkılı CdO yarıiletken ince filmlerinin yapısal, optik ve morfolojik özelliklerinin incelenmesi

Year 2017, Volume 21, Issue 6, 1544 - 1549, 01.12.2017
https://doi.org/10.16984/saufenbilder.312291

Abstract

Yapılan çalışmada SILAR yöntemi ile oda sıcaklığında katkısız ve farklı oranlarda Zn katkılı CdO yarıiletken ince filmlerinin büyütülebildiği gösterilmiştir. Numunelerde Zn katkısının yapısal, optik ve morfolojik özelliklere nasıl etki ettiğinin gözlemlenebilmesi için numunelerin XRD, soğurma ve SEM ölçümleri alınmıştır. XRD ölçümleri ile numunelerin kübik yapıda ve 33° ve (111), 38° ve (200), 55° ve (220), 66° ve (311), 69° ve (222) derece ve düzlemlerde kristal yapıya sahip olduğu gözlenmiştir. Soğurma ölçümleri ile hesaplanan direkt band aralıklarının CdO yapısı içerisinde Zn katkısı ile önce azaldığı ve sonrasında Zn katkı oranına bağlı olarak arttığı gözlenmiştir. Alınan SEM ölçümleri ile katkısız ve Zn katkılı CdO yüzey morfolojisinin Zn katkısı ile değişim sergilediği gözlenmiştir.

References

  • Referans1 Z. Zhang, D. A. Blom, Z. Gai, J. R. Thompson, J. Shen, S. Dai, High-yield solvothermal formation of magnetic CoPt alloy nanowires. Journal of the American Chemical Society, 125(25), 7528-7529, 2003.
  • Referans2 B. Şahin, F. Bayansal, M. Yüksel, H. A. Çetinkara, Influence of annealing to the properties of un-doped and Co-doped CdO films. Materials Science in Semiconductor Processing, 18, 135-140, 2014.
  • Referans3 R. S. Rusu, and G. I. Rusu, On the electrical and optical characteristics of CdO thin films. Journal of optoelectronics and Advanced materials, 7(2), 823-828, 2005.
  • Referans4 R. R. Salunkhe, and C. D. Lokhande, Effect of film thickness on liquefied petroleum gas (LPG) sensing properties of SILAR deposited CdO thin films. Sensors and Actuators B: Chemical, 129(1), 345-351, 2008.
  • Referans5 B. Sahin, F. Bayansal, M. Yüksel, A novel approach to enhancement of surface properties of CdO films by using surfactant: dextrin. Philosophical Magazine, 95(34), 3888-3895, 2015.
  • Referans6 B. Sahin, F. Bayansal, M. Yüksel, H. A. Çetinkara, Influence of annealing to the properties of un-doped and Co-doped CdO films. Materials Science in Semiconductor Processing, 18, 135-140, 2014.
  • Referans7 A. A. Ziabari, and F. E. Ghodsi, Optical and Structural Studies of Sol-Gel Deposited Nanostructured CdO Thin Films: Annealing Effect. Acta Physica Polonica A, 120(3), 536-540, 2011.
  • Referans8 J. Feng, S. Xiong, Y. Qian, L. Yin, Synthesis of nanosized cadmium oxide (CdO) as a novel high capacity anode material for Lithium-ion batteries: influence of carbon nanotubes decoration and binder choice. Electrochimica Acta, 129, 107-112, 2014.
  • Referans9 M. M. Rahman, S. B. Khan, H. M. Marwani, A. M. Asiri, K. A. Alamry, M. A. Rub, A. Khan, A.A.P. Khan, N. Azum, Facile synthesis of doped ZnO-CdO nanoblocks as solid-phase adsorbent and efficient solar photo-catalyst applications. Journal of Industrial and Engineering Chemistry, 20(4), 2278-2286, 2014.
  • Referans10 I. Akyuz, S. Kose, E. Ketenci, V. Bilgin, F. Atay, Optical, structural and surface characterization of ultrasonically sprayed CdO: F films. Journal of Alloys and Compounds, 509(5), 1947-1952, 2011.
  • Referans11 R. K. Gupta, F. Yakuphanoglu, F. M. Amanullah, Band gap engineering of nanostructure Cu doped CdO films. Physica E: Low-dimensional Systems and Nanostructures, 43(9), 1666-1668, 2011.
  • Referans12 B. J. Zheng, J. S. Lian, L. Zhao, Q. Jiang, Optical and electrical properties of Sn-doped CdO thin films obtained by pulse laser deposition. Vacuum, 85(9), 861-865, 2011.
  • Referans13 H. Güney, and Ç. Duman, Influence of Te and Se doping on ZnO films growth by SILAR method. AIP Conference Proceedings (Vol. 1726, No. 1, p. 020122, 2016.
  • Referans14 H. Güney ZnO’nun Seyreltilmiş Manyetik Yariiletken Olarak Elektrokimyasal Yöntemle Büyütülmesi Ve Karakterizasyonu. Atatürk Üniversitesi Fen Bilimleri Enstitüsü. Doktora Tezi, 2012.
  • Referans15 K. Usharani, and A. R. Balu, Structural, optical, and electrical properties of Zn-doped CdO thin films fabricated by a simplified spray pyrolysis technique. Acta Metallurgica Sinica (English Letters), 28(1), 64-71, 2015.
  • Referans16 H. Gomez, A. Maldonado, M. D. L. L. Olvera, D. R. Acosta, Gallium-doped ZnO thin films deposited by chemical spray. Solar energy materials and solar cells, 87(1), 107-116, 2005.
  • Referans17 A. Zaoui, M. Zaoui, S. Kacimi, A. Boukortt, B. Bouhafs, Stability and electronic properties of Zn x Cd 1− x O alloys. Materials Chemistry and Physics, 120(1), 98-103, 2010.

Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method

Year 2017, Volume 21, Issue 6, 1544 - 1549, 01.12.2017
https://doi.org/10.16984/saufenbilder.312291

Abstract

In the study, it was shown that undoped and Zn-doped CdO semiconductor thin films can be grown at room temperature by SILAR method. XRD, absorption and SEM measurements of the samples were taken to observe how the Zn addition affects the structural, optical and morphological properties of the samples. With XRD measurements it was observed that the samples had cubic structure and crystal structure at 33° and (111), 38° and (200), 55° and (220), 66° and (311), 69° and (222) degrees and planes respectively. It was observed that the direct band gaps calculated by the absorption measurements decreased with the Zn doping in the CdO structure and then increased with the Zn doping ratio. It was observed that the undoped and Zn-doped CdO surface morphology exhibited a change with the doping Zn.

References

  • Referans1 Z. Zhang, D. A. Blom, Z. Gai, J. R. Thompson, J. Shen, S. Dai, High-yield solvothermal formation of magnetic CoPt alloy nanowires. Journal of the American Chemical Society, 125(25), 7528-7529, 2003.
  • Referans2 B. Şahin, F. Bayansal, M. Yüksel, H. A. Çetinkara, Influence of annealing to the properties of un-doped and Co-doped CdO films. Materials Science in Semiconductor Processing, 18, 135-140, 2014.
  • Referans3 R. S. Rusu, and G. I. Rusu, On the electrical and optical characteristics of CdO thin films. Journal of optoelectronics and Advanced materials, 7(2), 823-828, 2005.
  • Referans4 R. R. Salunkhe, and C. D. Lokhande, Effect of film thickness on liquefied petroleum gas (LPG) sensing properties of SILAR deposited CdO thin films. Sensors and Actuators B: Chemical, 129(1), 345-351, 2008.
  • Referans5 B. Sahin, F. Bayansal, M. Yüksel, A novel approach to enhancement of surface properties of CdO films by using surfactant: dextrin. Philosophical Magazine, 95(34), 3888-3895, 2015.
  • Referans6 B. Sahin, F. Bayansal, M. Yüksel, H. A. Çetinkara, Influence of annealing to the properties of un-doped and Co-doped CdO films. Materials Science in Semiconductor Processing, 18, 135-140, 2014.
  • Referans7 A. A. Ziabari, and F. E. Ghodsi, Optical and Structural Studies of Sol-Gel Deposited Nanostructured CdO Thin Films: Annealing Effect. Acta Physica Polonica A, 120(3), 536-540, 2011.
  • Referans8 J. Feng, S. Xiong, Y. Qian, L. Yin, Synthesis of nanosized cadmium oxide (CdO) as a novel high capacity anode material for Lithium-ion batteries: influence of carbon nanotubes decoration and binder choice. Electrochimica Acta, 129, 107-112, 2014.
  • Referans9 M. M. Rahman, S. B. Khan, H. M. Marwani, A. M. Asiri, K. A. Alamry, M. A. Rub, A. Khan, A.A.P. Khan, N. Azum, Facile synthesis of doped ZnO-CdO nanoblocks as solid-phase adsorbent and efficient solar photo-catalyst applications. Journal of Industrial and Engineering Chemistry, 20(4), 2278-2286, 2014.
  • Referans10 I. Akyuz, S. Kose, E. Ketenci, V. Bilgin, F. Atay, Optical, structural and surface characterization of ultrasonically sprayed CdO: F films. Journal of Alloys and Compounds, 509(5), 1947-1952, 2011.
  • Referans11 R. K. Gupta, F. Yakuphanoglu, F. M. Amanullah, Band gap engineering of nanostructure Cu doped CdO films. Physica E: Low-dimensional Systems and Nanostructures, 43(9), 1666-1668, 2011.
  • Referans12 B. J. Zheng, J. S. Lian, L. Zhao, Q. Jiang, Optical and electrical properties of Sn-doped CdO thin films obtained by pulse laser deposition. Vacuum, 85(9), 861-865, 2011.
  • Referans13 H. Güney, and Ç. Duman, Influence of Te and Se doping on ZnO films growth by SILAR method. AIP Conference Proceedings (Vol. 1726, No. 1, p. 020122, 2016.
  • Referans14 H. Güney ZnO’nun Seyreltilmiş Manyetik Yariiletken Olarak Elektrokimyasal Yöntemle Büyütülmesi Ve Karakterizasyonu. Atatürk Üniversitesi Fen Bilimleri Enstitüsü. Doktora Tezi, 2012.
  • Referans15 K. Usharani, and A. R. Balu, Structural, optical, and electrical properties of Zn-doped CdO thin films fabricated by a simplified spray pyrolysis technique. Acta Metallurgica Sinica (English Letters), 28(1), 64-71, 2015.
  • Referans16 H. Gomez, A. Maldonado, M. D. L. L. Olvera, D. R. Acosta, Gallium-doped ZnO thin films deposited by chemical spray. Solar energy materials and solar cells, 87(1), 107-116, 2005.
  • Referans17 A. Zaoui, M. Zaoui, S. Kacimi, A. Boukortt, B. Bouhafs, Stability and electronic properties of Zn x Cd 1− x O alloys. Materials Chemistry and Physics, 120(1), 98-103, 2010.

Details

Subjects Physics, Applied
Published Date Aralık 2017
Journal Section Research Articles
Authors

Harun GÜNEY>
Ağrı İbrahim Çeçen Üniversitesi, Merkezi Uygulama ve Araştırma Laboratuvarı,
Türkiye


Demet İSKENDEROĞLU This is me
ATATÜRK ÜNİVERSİTESİ, DOĞU ANADOLU YÜKSEK TEKNOLOJİ UYGULAMA VE ARAŞTIRMA MERKEZİ
Türkiye

Publication Date December 1, 2017
Submission Date May 15, 2017
Acceptance Date October 23, 2017
Published in Issue Year 2017, Volume 21, Issue 6

Cite

Bibtex @ { saufenbilder312291, journal = {Sakarya University Journal of Science}, eissn = {2147-835X}, address = {}, publisher = {Sakarya University}, year = {2017}, volume = {21}, number = {6}, pages = {1544 - 1549}, doi = {10.16984/saufenbilder.312291}, title = {Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method}, key = {cite}, author = {Güney, Harun and İskenderoğlu, Demet} }
APA Güney, H. & İskenderoğlu, D. (2017). Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method . Sakarya University Journal of Science , 21 (6) , 1544-1549 . DOI: 10.16984/saufenbilder.312291
MLA Güney, H. , İskenderoğlu, D. "Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method" . Sakarya University Journal of Science 21 (2017 ): 1544-1549 <https://dergipark.org.tr/en/pub/saufenbilder/issue/26999/312291>
Chicago Güney, H. , İskenderoğlu, D. "Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method". Sakarya University Journal of Science 21 (2017 ): 1544-1549
RIS TY - JOUR T1 - Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method AU - HarunGüney, Demetİskenderoğlu Y1 - 2017 PY - 2017 N1 - doi: 10.16984/saufenbilder.312291 DO - 10.16984/saufenbilder.312291 T2 - Sakarya University Journal of Science JF - Journal JO - JOR SP - 1544 EP - 1549 VL - 21 IS - 6 SN - -2147-835X M3 - doi: 10.16984/saufenbilder.312291 UR - https://doi.org/10.16984/saufenbilder.312291 Y2 - 2017 ER -
EndNote %0 Sakarya University Journal of Science Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method %A Harun Güney , Demet İskenderoğlu %T Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method %D 2017 %J Sakarya University Journal of Science %P -2147-835X %V 21 %N 6 %R doi: 10.16984/saufenbilder.312291 %U 10.16984/saufenbilder.312291
ISNAD Güney, Harun , İskenderoğlu, Demet . "Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method". Sakarya University Journal of Science 21 / 6 (December 2017): 1544-1549 . https://doi.org/10.16984/saufenbilder.312291
AMA Güney H. , İskenderoğlu D. Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method. SAUJS. 2017; 21(6): 1544-1549.
Vancouver Güney H. , İskenderoğlu D. Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method. Sakarya University Journal of Science. 2017; 21(6): 1544-1549.
IEEE H. Güney and D. İskenderoğlu , "Investigation of structural, optical and morphological properties of undoped and Zn doped CdO semiconductor thin films grown by SILAR method", Sakarya University Journal of Science, vol. 21, no. 6, pp. 1544-1549, Dec. 2017, doi:10.16984/saufenbilder.312291

Sakarya University Journal of Science (SAUJS)