Removal of Remazol Brilliant Blue R (RBBR) dyes with a low cost adsorbent, cigarette ash

Year 2018, Volume: 22 Issue: 2, 174 - 180, 01.04.2018

Rabia Köklü , Çiğdem Özer

https://doi.org/10.16984/saufenbilder.329234

Cited By: 1

Abstract

The treatment of wastewaters contaminated with dye from the widespread use of dyestuff is an important environmental issue.  Smoking is also a harmful habit that many people have nowadays. This study aimed to investigate the Remazol Brillant Blue R (RBBR) adsorb ability of the cigarette ash to gain a use area for waste ash generated during smoking and to introduce a new, alternative and low cost adsorbent in the removal of dyestuff by adsorption method.  For this purpose, the conditions of RBBR adsorption on the cigarette ash, which is a costless adsorbent, were investigated according to pH, initial dyestuff concentration, contact time and adsorbent dose and maximum adsorption capacity was determined as 178,57 mg/g. In addition, the suitability of experimental data with isotherm and kinetic models was analyzed and the parameters of these models were calculated. Adsorption of RBBR dye with cigarette ash has been shown to be better expressed by Langmuir isotherm.

Keywords

RBBR, adsorption, cigarette ash, isotherm and kinetic

Remazol Brillant Blue R (RBBR) boyarmaddesinin düşük maliyetli bir adsorban olan sigara külü ile giderimi

Abstract

Boyarmaddelerin geniş kullanımı sebebiyle ortaya çıkan boyalı atıksuların arıtılması önemli bir çevre sorunudur. Sigara kullanımı da günümüzde birçok kişinin sahip olduğu zararlı bir alışkanlıktır. Sigara kullanımı sırasında ortaya çıkan atık küllere bir kullanım alanı yaratmak ve boyarmaddelerin adsorpsiyon yöntemi ile gideriminde yeni, alternatif ve düşük maliyetli bir adsorban ortaya koymak amacıyla yola çıkılan bu çalışmada, sigara külünün Remazol Brillant Blue R (RBBR) boyarmaddesini adsorplama yeteneği araştırılmıştır.  Bu amaçla, RBBR boyarmaddesinin maliyetsiz bir adsorban olan sigara külü üzerine adsorbsiyon şartları pH, başlangıç boyarmadde konsantrasyonu, karıştırma süresi ve adsorbent dozuna bağlı olarak incelenmiş ve maksimum adsorbsiyon kapasitesi 178,57 mg/g olarak belirlenmiştir. Bunun yanında deneysel verilerin izoterm ve kinetik modellere uygunluğu araştırılmış ve bu modellere ait parametreler hesaplanmıştır. RBBR boyarmaddesinin sigara külü ile adsorpsiyonunun Langmiur izotermi ile daha iyi ifade edildiği görülmüştür. 

Keywords

RBBR, adsorpsiyon, sigara külü, izoterm ve kinetik

References

• [1] K. C. Bedin, S. P. de Azevedo, P. K. T. Leandro, A. L. Cazetta, and V. C. Almeida, “Bone char prepared by CO 2 atmosphere: Preparation optimization and adsorption studies of Remazol Brilliant Blue R,” J. Clean. Prod., vol. 161, pp. 288–298, 2017.
• [2] K. Chinoune, K. Bentaleb, Z. Bouberka, A. Nadim, and U. Maschke, “Adsorption of reactive dyes from aqueous solution by dirty bentonite,” Appl. Clay Sci., vol. 123, pp. 64–75, 2016.
• [3] G. C. Upadhye and R. S. Yamgar, “Analytical study of agricultural waste as non- conventional low cost adsorbent removal of dyes from aqueous solutions,” Int. J. Chem. Stud., vol. 4, no. 1, pp. 128–133, 2016.
• [4] M. A. A. El-kawi, A. M. Hafez, I. G. A. Rashed, and E. E. Aboelnaga, “Removal of reactive blue 19 from aqueous solution using rice straw fly ash,” J. Mater. Environ. Sci., vol. 7, no. 3, pp. 1023–1036, 2016.
• [5] M. T. Yagub, T. K. Sen, S. Afroze, and H. M. Ang, “Dye and its removal from aqueous solution by adsorption: A review,” Adv. Colloid Interface Sci., vol. 209, pp. 172–184, 2014.
• [6] M. Dehvari, M. Ghaneian, A. Ebrahimi, B. Jamshidi, and M. Mootab, “Removal of reactive blue 19 dyes from textile wastewater by pomegranate seed powder: Isotherm and kinetic studies,” Int. J. Environ. Health Eng., vol. 5, no. 1, p. 5, 2016.
• [7] N. A. Rahmat, A. A. Ali, Salmiati, N. Hussain, M. S. Muhamad, R. A. Kristanti, and T. Hadibarata, “Removal of Remazol Brilliant Blue R from Aqueous Solution by Adsorption Using Pineapple Leaf Powder and Lime Peel Powder,” Water. Air. Soil Pollut., vol. 227, no. 4, 2016.
• [8] R. K. Ghosh and D. D. Reddy, “Tobacco stem ash as an adsorbent for removal of methylene blue from aqueous solution: Equilibrium, kinetics, and mechanism of adsorption,” Water. Air. Soil Pollut., vol. 224, no. 6, 2013.
• [9] E. Mourid, M. Lakraimi, E. El Khattabi, L. Benaziz, and M. Berraho, “Removal of Remazol Brilliant Blue R From Aqueous Solution by Adsorption Using a Calcined Layered Double Hydroxides [ Zn 2 -Al-CO 3 ],” J. Mater. Environ. Sci., vol. 8, no. 3, pp. 921–930, 2017.
• [10] M. A. Moreira, K. J. Ciuf, V. Rives, M. A. Vicente, R. Trujillano, A. Gil, S. A. Korili, and E. H. De Faria, “Applied Clay Science Effect of chemical modi fi cation of palygorskite and sepiolite by 3-aminopropyltriethoxisilane on adsorption of cationic and anionic dyes,” vol. 135, pp. 394–404, 2017.
• [11] M. Wawrzkiewicz, P. Bartczak, and T. Jesionowski, “International Journal of Biological Macromolecules Enhanced removal of hazardous dye form aqueous solutions and real textile wastewater using bifunctional chitin / lignin biosorbent,” Int. J. Biol. Macromol., vol. 99, pp. 754–764, 2017.
• [12] K. Z. Elwakeel, A. Ismail, and A. M. Morshidy, “Magnetic chitosan grafted with polymerized thiourea for remazol brilliant blue R recovery : Effects of uptake conditions,” J. Dispers. Sci. Technol., vol. 38, no. 7, pp. 943–952, 2017.
• [13] A. Asfaram, M. Ghaedi, F. Yousefi, and M. Dastkhoon, “Ultrasonics Sonochemistry Experimental design and modeling of ultrasound assisted simultaneous adsorption of cationic dyes onto ZnS : Mn-NPs-AC from binary mixture,” Ultrason. - Sonochemistry, vol. 33, pp. 77–89, 2016.
• [14] T. Maneerung, J. Liew, Y. Dai, S. Kawi, C. Chong, and C. Wang, “Bioresource Technology Activated carbon derived from carbon residue from biomass gasification and its application for dye adsorption : Kinetics , isotherms and thermodynamic studies,” vol. 200, pp. 350–359, 2016.
• [15] D. Robati, M. Rajabi, O. Moradi, F. Naja, I. Tyagi, S. Agarwal, and V. Kumar, “Kinetics and thermodynamics of malachite green dye adsorption from aqueous solutions on graphene oxide and reduced graphene oxide,” vol. 214, pp. 259–263, 2016.
• [16] A. R. Omran, M. A. Baiee, S. A. Juda, J. M. Salman, and A. F. Alkaim, “Removal of Congo red dye from aqueous solution using a new adsorbent surface developed from aquatic plant ( Phragmites australis ),” vol. 9, no. 4, pp. 334–342, 2016.
• [17] C. Muthukumaran and V. Murugaiyan, “Journal of the Taiwan Institute of Chemical Engineers Adsorption isotherms and kinetic studies of crystal violet dye removal from aqueous solution using surfactant modified magnetic nanoadsorbent,” vol. 63, pp. 354–362, 2016.
• [18] M. A. Tahir, H. Nawaz, and M. Iqbal, “Journal of Environmental Chemical Engineering Solar Red and Brittle Blue direct dyes adsorption onto Eucalyptus angophoroides bark : Equilibrium , kinetics and thermodynamic studies,” Biochem. Pharmacol., vol. 4, no. 2, pp. 2431–2439, 2016.
• [19] N. Khairuladli, A. Fisal, H. Mohdsukri, N. Khairunisa, and A. Ma, “Adsorption of Chemically Prepared Cocoa Nibs Based Activated Carbon Onto Methylene Blue : Equilibrium and Kinetic Studies,” vol. 1, no. 1, pp. 15–18.
• [20] S. Mohammadreza, S. Kordmirza, and G. Mckay, “Methylene blue adsorption via maize silk powder : Kinetic , equilibrium , thermodynamic studies and,” Process Saf. Environ. Prot., vol. 106, pp. 191–202, 2017.