Electrospun PVDF Membranes Incorporated with Functionalized Carbon-based Material for Removal of Cationic Dyes

Year 2023, Volume: 27 Issue: 2, 386 - 397, 30.04.2023

Fatma Demirci , Burçak Kaya Özsel

https://doi.org/10.16984/saufenbilder.1195528

Cited By: 1

Abstract

In this study, polyvinylidene fluoride (PVDF) polymeric membranes with addition of functionalized carbon-based material (CBM) were fabricated by using electrospinning technique for the removal of cationic dyes from wastewater. CBM was prepared through a two-step carbonization process from cotton linter as an agricultural waste biomass. The characterization of CBM was performed by using Brunauer–Emmett–Teller (BET) surface analysis, fourier transform infrared spectrometry (FTIR) and elemental analysis. The morphologies of electrospun membranes were observed by scanning electron microscope (SEM) which clearly revealed that nanofibers with a smooth surface were produced by incorporation of CBM. According to the results obtained from FTIR and differential scanning calorimetry (DSC), crystallization behavior of PVDF membranes was promoted by increasing the percentage of CBM in the membrane. PVDF membrane prepared with the addition of 3 wt % CBM exhibited the highest water flux performance with a dye rejection of 74.6 % in comparison with the pure PVDF one.

Keywords

Electrospinning, membrane, carbon-based material, dye removal

References

• [1] E. Santoso, R. Ediati, Y. Kusumawati, H. Bahruji, D. O. Sulistiono, D. Prasetyoko, “Review on recent advances of carbon based adsorbent for methylene blue removal from wastewater,” Materials Today Chemistry, vol. 16, no. 100233, 2020.
• [2] J. Li, L. Huang, X. Jiang, L. Zhang, X. Sun, “Preparation and characterization of ternary Cu/Cu2O/C composite: An extraordinary adsorbent for removing anionic organic dyes from water,” Chemical Engineering Journal, vol. 404, no. 127091, 2021.
• [3] K. B Tan, M. Vakili, B. A. Horri, P. E. Poh, A. Z. Abdullah, B. Salamatinia, “Adsorption of dyes by nanomaterials: recent developments and adsorption mechanisms,” Separation and Purification Technology, vol. 150, pp. 229-242, 2015.
• [4] P. Verma, S. K. Samanta, “Microwave-enhanced advanced oxidation processes for the degradation of dyes in water,” Environmental chemistry letters, vol. 16, no. 3, pp. 969-1007, 2018.
• [5] J. Zhao, H. Liu, P. Xue, S. Tian, S. Sun, X. Lv, “Highly-efficient PVDF adsorptive membrane filtration based on chitosan@ CNTs-COOH simultaneous removal of anionic and cationic dyes,” Carbohydrate Polymers, vol. 274, no. 118664, 2021.
• [6] H. D. Bouras, Z. Isik, E. B. Arikan, N. Bouras, A. Chergui, H. C. Yatmaz, N. Dizge, “Photocatalytic oxidation of azo dye solutions by impregnation of ZnO on fungi,” Biochemical Engineering Journal, vol. 146, pp. 150-159, 2019.
• [7] A. Nasar, F. Mashkoor, “Application of polyaniline-based adsorbents for dye removal from water and wastewater—a review,” Environmental Science and Pollution Research, vol. 26, no. 6, pp. 5333-5356, 2019.
• [8] F. Demirci, A. Aydın, M. Orhan, H. B. Koçer, “Production of ultrafiltration membranes exhibiting antibacterial properties by the incorporation of novel N‐halamine copolymers,” Journal of Applied Polymer Science, vol. 139, no. 31, no. e52727, 2022.
• [9] J. Wang, Q. Zhang, X. Shao, J. Ma, G. Tian, “Properties of magnetic carbon nanomaterials and application in removal organic dyes,” Chemosphere, vol. 207, pp. 377-384, 2018.
• [10] F. Baskoro, S. R. Kumar, S. J. Lue, “Grafting thin layered graphene oxide onto the surface of nonwoven/PVDF-PAA composite membrane for efficient dye and macromolecule separations,” Nanomaterials, vol. 10, no. 4, pp. 792, 2020.
• [11] L. Zhou, Y. He, H. Shi, G. Xiao, S. Wang, Z. Li, J. Chen, “One-pot route to synthesize HNTs@ PVDF membrane for rapid and effective separation of emulsion-oil and dyes from waste water,” Journal of hazardous materials, vol. 380, no. 120865, 2019.
• [12] Y. Song, Y. Wang, N. Zhang, X. Li, X. Bai, T. Li, “Quaternized carbon-based nanoparticles embedded positively charged composite membranes towards efficient removal of cationic small-sized contaminants,” Journal of Membrane Science, vol. 630, no. 119332, 2021.
• [13] F. Liu, N. A. Hashim, Y. Liu, M. M. Abed, K. Li, “Progress in the production and modification of PVDF membranes,” Journal of Membrane Science, vol. 375, no. 1-2, pp. 1-27, 2011.
• [14] S. Mohamadi, N. Sharifi-Sanjani, “Crystallization of PVDF in graphene-filled electrospun PVDF/PMMA nanofibers processed at three different conditions,” Fibers and Polymers, vol. 17, no. 4, pp. 582-592, 2016.
• [15] M. Nasir, R. I. Sugatri, P. P. P. Asri, F. Dara, “Nanostructure and surface characteristic of electrospun carbon black/PVDF copolymer nanocomposite,” Journal of Silicate Based and Composite Materials, vol. 70, no. 209-213, 2018.
• [16] G. Yang, D. Zhang, G. Zhu, T. Zhou, M. Song, L. Qu, K. Xiong, H. Li, “A Sm-MOF/GO nanocomposite membrane for efficient organic dye removal from wastewater,” RSC Advances, vol. 10, no. 14, pp. 8540-8547, 2020.
• [17] S. Tahazadeh, T. Mohammadi, M. A. Tofighy, S. Khanlari, H. Karimi, H. B. M. Emrooz, “Development of cellulose acetate/metal-organic framework derived porous carbon adsorptive membrane for dye removal applications,” Journal of Membrane Science, vol. 638, no. 119692, 2021.
• [18] M. A. Lalabadi, H. Peyman, H. Roshanfekr, S. Azizi, M. Maaza, “Polyethersulfone nanofiltration membrane embedded by magnetically modified MOF (MOF@ Fe3O4): fabrication, characterization and performance in dye removal from water using factorial design experiments,” Polymer Bulletin, pp. 1-21, 2022.
• [19] A. K. Shukla, J. Alam, F. A. A. Ali, M. Alhoshan, “Efficient soluble anionic dye removal and antimicrobial properties of ZnO embedded‐Polyphenylsulfone membrane,” Water and Environment Journal, vol. 35, no. 2, pp. 670-684, 2021.
• [20] S. Gholami, J. L. Llacuna, V. Vatanpour, A. Dehqan, S. Paziresh, J. L. Cortina, “Impact of a new functionalization of multiwalled carbon nanotubes on antifouling and permeability of PVDF nanocomposite membranes for dye wastewater treatment,” Chemosphere, vol. 294, pp. 133699, 2022.
• [21] M. M. Fu, C. H. Mo, H. Li, Y. N. Zhang, W. X. Huang, M. H. Wong, “Comparison of physicochemical properties of biochars and hydrochars produced from food wastes,” Journal of Cleaner Production, vol. 236, no. 117637, 2019.
• [22] X. Zhang, Y. Zhang, H. H. Ngo, W. Guo, H. Wen, D. Zhang, C. Li, L. Qi, “Characterization and sulfonamide antibiotics adsorption capacity of spent coffee grounds based biochar and hydrochar,” Science of the Total Environment, vol. 716, no. 137015, 2020.
• [23] A. Jain, R. Balasubramanian, M. P. Srinivasan, “Hydrothermal conversion of biomass waste to activated carbon with high porosity: A review,” Chemical Engineering Journal, vol. 283, pp. 789-805, 2016.
• [24] R. O. Araujo, J. da Silva Chaar, L. S. Queiroz, G. N. da Rocha Filho, C. E. F. da Costa, G. C da Silva, R. Landers, M. J. Costa, A. A. Gonçalves, L. K. de Souza, “Low temperature sulfonation of acai stone biomass derived carbons as acid catalysts for esterification reactions,” Energy Conversion and Management, vol 196, pp. 821-830, 2019.
• [25] T. Foyle, L. Jennings, P. Mulcahy, “Compositional analysis of lignocellulosic materials: Evaluation of methods used for sugar analysis of waste paper and straw,” Bioresource Technology, vol. 98, no. 16, pp. 3026-3036, 2007. [26] M. M. A. D. Maciel, K. C. C Benini, H. J. C. Voorwald, M. O. H. Cioffi, “Obtainment and characterization of nanocellulose from an unwoven industrial textile cotton waste: Effect of acid hydrolysis conditions,” International Journal of Biological Macromolecules, vol. 126, pp. 496-506, 2019.
• [27] C. Samori, A. Parodi, E. Tagliavini, P. Galletti, “Recycling of post-use starch-based plastic bags through pyrolysis to produce sulfonated catalysts and chemicals,” Journal of Analytical and Applied Pyrolysis, vol. 155, no. 105030, 2021.
• [28] R. F. Susanti, A. A. Arie, H. Kristianto, M. Erico, G. Kevin, H. Devianto, “Activated carbon from citric acid catalyzed hydrothermal carbonization and chemical activation of salacca peel as potential electrode for lithium ion capacitor’s cathode”, Ionics, vol. 25, pp. 3915-3925, 2019.
• [29] H. Simsir, N. Eltugral, S. Karagoz, “Effects of acidic and alkaline metal triflates on the hydrothermal carbonization of glucose and cellulose,” Energy & Fuels, vol. 33, no. 8, pp. 7473-7479, 2019.
• [30] Z. Hoseinabadi, S. A. Pourmousavi, “Synthesis of Starch Derived Sulfonated Carbon-based Solid Acid as a Novel and Efficient Nanocatalyst for the Synthesis of Dihydropyrimidinones,” Warasan Khana Witthayasat Maha Witthayalai Chiang Mai, vol. 46, no. 1, pp. 132-143, 2019.
• [31] Z. Liu, Z. Liu, “Comparison of hydrochar-and pyrochar-based solid acid catalysts from cornstalk: Physiochemical properties, catalytic activity and deactivation behavior,” Bioresource Technology, vol. 297, no. 122477, 2020.
• [32] R. S. Salama, S. M. El-Bahy, M. A. Mannaa, “Sulfamic acid supported on mesoporous MCM-41 as a novel, efficient and reusable heterogenous solid acid catalyst for synthesis of xanthene, dihydropyrimidinone and coumarin derivatives,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 628, no. 127261, 2021.
• [33] Y. J. Hwang, S. Choi, H. S. Kim, “Structural deformation of PVDF nanoweb due to electrospinning behavior affected by solvent ratio,” e-Polymers, vol. 18, no. 4, pp. 339-345, 2018.
• [34] J. Hwang, J. Muth, T. Ghosh, “Electrical and mechanical properties of carbon‐black‐filled, electrospun nanocomposite fiber webs,” Journal of Applied Polymer Science, vol. 104 no. 4, pp. 2410-2417, 2007.
• [35] E. Tarasova, A. Byzova, N. Savest, M. Viirsalu, V. Gudkova, T. Maertson, A. Krumme, “Influence of preparation process on morphology and conductivity of carbon black-based electrospun nanofibers,” Fullerenes, Nanotubes and Carbon Nanostructures, vol. 23, no. 8, pp. 695-700, 2014.
• [36] M. M. Tao, F. Liu, B. R. Ma, L. X. Xue, “Effect of solvent power on PVDF membrane polymorphism during phase inversion,” Desalination, vol. 316, pp. 137-145, 2013.
• [37] R. Moradi, J. Karimi-Sabet, M. Shariaty-Niassar, M. A. Koochaki, “Preparation and characterization of polyvinylidene fluoride/graphene superhydrophobic fibrous films”, Polymers, vol. 7, no. 8, pp. 1444-1463, 2015.
• [38] N. Mehranbod, M. Khorram, S. Azizi, N. Khakinezhad, “Modification and superhydrophilization of electrospun polyvinylidene fluoride membrane using graphene oxide-chitosan nanostructure and performance evaluation in oil/water separation”, Journal of Environmental Chemical Engineering, vol. 9, no. 5, pp. 106245, 2021.
• [39] J. A. Park, A. Nam, J. H. Kim, S. T. Yun, J. W. Choi, S. H. Lee, “Blend-electrospun graphene oxide/Poly (vinylidene fluoride) nanofibrous membranes with high flux, tetracycline removal and anti-fouling properties”, Chemosphere, vol. 207, pp. 347-356, 2018.