BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ

Ahmet Aydın

doi:10.29233/sdufeffd.134656

BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ

Abstract

Özet: Praseodimyum (III) nitrat hekzahidrat [Pr(NO3)3.6H2O] (4) ile ditiyofosfonik asit [Ar(RO)PS2]- [Ar: p-C6H4OMe, R: Et, nPr] anyonlarının (3a-b) stokiometrik oranda THF ortamındaki reaksiyonundan paramagnetik, Pr3+ kompleksleri (5a-b) hazırlandı. Hazırlanan, bileşiklerin yapıları; element analizi, FT-IR, [1H, 13C, 31P] NMR spektroskopisi ve magnetik süsseptibilite ölçümleri ile aydınlatıldı Anahtar kelimeler: Ditiyofosfonat, ditiyofosfonik asit, organoditiyo bileşikleri, lantanit kompleksleri, praseodimyum(III) kompleksleri SPECTROSCOPIC INVESTIGATIONS OF PARAMAGNETIC PRASEODYMIUM(III) COMPLEXES OF SOME DITHIOPHOSPHONATES O-ALKYL ESTERS Abstract: Paramagnetic Pr3+ complexes (5a-b) have been prepared by reacting praseodymium(III) nitrate hexahydrate [Pr(NO3)3.6H2O] (4) with dithiophosphonic acids [Ar(RO)PS2]- [Ar: p-C6H4OMe, R: Et, nPr] (3a-b) stoichiometrically in THF solution (5a-b). Compounds were characterized by elemental analysis, FT-IR, [1H, 13C, 31P] NMR spectroscopy and magnetic susceptibility. Key words: Dithiophosphonate, phosphonodithioic acids, organothio compounds lanthanide complexes, praseodymium(III) complexes

Keywords

Ditiyofosfonat, ditiyofosfonik asit, organoditiyo bileşikleri, lantanit kompleksleri, praseodimyum(III) kompleksleri

References

ÇEKİRDEK P, SOLAK AO, KARAKUŞ M, AYDIN A, YILMAZ H, 2006. Investigation of Electrochemical Behavior of Some Dithiophosphonates in Acetonitrile on the Platinum and Gold Electrodes. Electroanalysis, 18, 2314- 2323
GRAY IP, MILTON HL, SHAVIN AM, WOLLINS JD, 2004. Synthesis and Structure of [An(OR)PS2]- Complexes. Dalton Transactions, 2477-2486.
KOTYNSKI A, KUDZIN ZH, CIESIELSKI W, 2004. Analysis of Organophosphorus Compounds 1. Aplication of Iodine–azide Reaction for Detection of Thiophosphoroorganic Compounds in Thin-layer Chromotography. Acta Universitatis Lodziensıs Follia Chimica, 13, 135-141.
PETROVA J, MOMCHILOVA S, HAUPT ETK, KOPF J, EGGERS G, 2002. Syntehesis and Structure of The Diethyl Esters of 2-Dimethylamino-2- Oxoethylphosphonic Acid with Lanthanide Nitrates. Phosphorus, Sulfur and Silicon, 177, 1337-1347
VAN ZYL WE, FACLER JP, 2000. A General and Convenient Route to Dithiophosphonate Salt Derivatives Phosphourus, Sulfur and Silicon and Related Elements, 167, 117-132.

Details

Primary Language

Turkish

Subjects

-

Journal Section

-

Authors

Ahmet Aydın This is me

Publication Date

December 1, 2008

Submission Date

February 25, 2009

Acceptance Date

-

Published in Issue

Year 2008 Volume: 3 Number: 2

DOI

https://doi.org/10.29233/sdufeffd.134656

IZ

https://izlik.org/JA42EF82ZG

Cite

RIS / Bibtex

APA

Aydın, A. (2008). BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ. Süleyman Demirel University Faculty of Arts and Science Journal of Science, 3(2), 205-210. https://doi.org/10.29233/sdufeffd.134656

AMA

1.Aydın A. BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ. Süleyman Demirel University Faculty of Arts and Science Journal of Science. 2008;3(2):205-210. doi:10.29233/sdufeffd.134656

Chicago

Aydın, Ahmet. 2008. “BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ”. Süleyman Demirel University Faculty of Arts and Science Journal of Science 3 (2): 205-10. https://doi.org/10.29233/sdufeffd.134656.

EndNote

Aydın A (December 1, 2008) BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ. Süleyman Demirel University Faculty of Arts and Science Journal of Science 3 2 205–210.

IEEE

[1]A. Aydın, “BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ”, Süleyman Demirel University Faculty of Arts and Science Journal of Science, vol. 3, no. 2, pp. 205–210, Dec. 2008, doi: 10.29233/sdufeffd.134656.

ISNAD

Aydın, Ahmet. “BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ”. Süleyman Demirel University Faculty of Arts and Science Journal of Science 3/2 (December 1, 2008): 205-210. https://doi.org/10.29233/sdufeffd.134656.

JAMA

1.Aydın A. BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ. Süleyman Demirel University Faculty of Arts and Science Journal of Science. 2008;3:205–210.

MLA

Aydın, Ahmet. “BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ”. Süleyman Demirel University Faculty of Arts and Science Journal of Science, vol. 3, no. 2, Dec. 2008, pp. 205-10, doi:10.29233/sdufeffd.134656.

Vancouver

1.Ahmet Aydın. BAZI DİTİYOFOSFONAT -O-ALKİL ESTERLERİNİN PARAMAGNETİK PRASEODİMYUM(III) KOMPLEKSLERİNİN SPEKTROSKOPİK İNCELENMESİ. Süleyman Demirel University Faculty of Arts and Science Journal of Science. 2008 Dec. 1;3(2):205-10. doi:10.29233/sdufeffd.134656