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Monoetanolamin Miktarının ZnO İnce Filmlerin Kristallenmesi Üzerine Etkisi

Year 2019, , 155 - 164, 31.05.2019
https://doi.org/10.29233/sdufeffd.513412

Abstract

Çinko oksit yarıiletkeni
sahip olduğu değiştirilebilir yasak enerji aralığı ve görünür ışık bölgesindeki
yüksek optik geçirgenliğinden dolayı opto-elektronik uygulamalar için çok sık
kullanılan yarıiletkenlerden biridir. Farklı miktarlarda kullanılan monoethanolamin
miktarının ZnO ince filmlerin yapısal, morfolojik ve optik özellikleri üzerine
etkileri bu çalışmada incelenmiştir. Nano-fiber yapılı ZnO ince filmler başka
herhangi bir işlem gerektirmeden cam altlık üzerine, basit sol-jel daldırma
yöntemi kullanılarak sentezlenmiştir. Monoetanolamin miktarı artırıldığında
örneklerin XRD pik şiddetlerinin arttığı ve kristal kusurlarının azaldığı
gözlemlenmiştir. Bunun yanında, monoetanolamin miktarı arttığında mikro-fiber
ZnO taneciklerinin altlık yüzeyini oldukça yoğun bir şekilde kapladığı
görünmüştür. Ayrıca optik ölçümler sonucu stabilizer olarak kullanılan monoethanolamin
miktarının artışı ile ince filmlerin görünür ışık bölgesindeki geçirgenliğinin
arttığı görülmüştür.   

References

  • H. Li, J. Wang, H. Liu, C. Yang, H. Xu, X. Li, and H. Cui, “Sol-gel preparation of transparent zinc oxide films with highly preferential crystal orientation,” Vacuum, 77, 57-62, 2004.
  • A. Goktas, F. Aslan, A. Tumbul, and S. H. Gunduz, “Tuning of structural, optical and dielectric constants by various transition metal doping in ZnO:TM (TM=Mn, Co, Fe) nanostructured thin films: A comparative study,” Ceram. Int., 43, 704-713, 2016.
  • S. O’Brien, L. H. K. Koh, and G. M. Crean, “ZnO thin films prepared by a singles tep sol–gel process,” Thin Solid Films, 516, 1391-1395, 2007.
  • C. Tsay and W. Hsu, “Sol–gel derived undoped and boron-doped ZnO semiconductor thin films: Preparation and Characterization,” Ceram. Int., 39, 7425-7432, 2013.
  • V. Galstyan, E. Comini, C. Baratto, G. Faglia, and G. Sberveglieri, “Nanostructured ZnO chemical gas sensors,” Ceram. Int., 41, 14239-14244, 2015.
  • V. Kumar, R. G. Singh, F. Singh, and L. P. Purohit, “Highly transparent and conducting boron doped zinc oxide films for window of Dye Sensitized Solar Cell applications,” J. Alloy. Comp., 544, 120-124, 2012.
  • M. Wang, W. Liang, Y. Yang, J. Yang, X. Cheng, S. H. Hahn, and E. J. Kim, “Sol-gel derived transparent conducting ZnO:Al thin films: Effect of crystallite orientation on conductivity and self-assembled network texture,” J. Mater Chem. Phys., 134, 845-850, 2012. J. Huang, L. Wang, R. Xu, K.Tang, W. Shi, and Y. Xia, “Growth of p-type ZnO films and fabrication of ZnO photodiode-based UV detectors,” Semicond. Sci. Technol., 24, 075025 (5pp), 2009.
  • E. M. Bachari, G. Baud, S. B. Amor, and M. Jacquet, “Structural and optical properties of sputtered ZnO,” Thin Solid Films, 348, 165-172, 1999.
  • D. L. Jiao, X. C. Zhong, W. Q. Qui, H. Zhang, Z. W. Lui, and G. Q. Zhang, “Structure and Electric Conduction in Pulsed Laser-Deposited ZnO Thin Films Individually doped with N, P or Na,” J. Electron. Mater., 47, 3521-3528, 2018.
  • D. Adolph, T. Tinberg, and T. Ive, “Growth of ZnO(0001) on GaN(0001)/4H-SiC buffer layers by plasma-assisted hybrid molecular beam epitaxy,” J. Cryst. Growth, vol. 426, pp. 129-134, Jun. 2015.
  • V. K. Ashith, G. K. Rao, S. N. Moger, and R. Smitha, “Effect of post-deposition annealing on the properties of ZnO films obtained by high temperature, micro-controller based SILAR deposition,” Ceram. Int., 44, 10669-10676, 2018.
  • H. L. Ma, Z W. Liu, D. C. Zeng, M. L. Zhong, H. Y. Yu, and E. Mikmekova, “Nanostructured ZnO films with various morphologies prepared by ultrasonic spray pyrolysis and its growing process,” App. Surf. Sci., 283, 1006-1011, 2013.
  • N. T. Son, J. S. Noh, and S. Park, “Role of ZnO thin film in the vertically aligned growth of ZnO nanorods by chemical bath deposition,” App. Surf. Sci., 379, 440-445, 2016.
  • D. Bao, H. Gu, and A. Kuang, “Sol-gel derived c-axis ZnO thin films,” Thin Solid Films, 312, 37-39, 1997.
  • Y. Li, L. Xu, X. Li, X. Shen, and A. Wang, “Effect of aging time of ZnO sol on the structural and optical properties of ZnO thin films prepared by sol–gel method,” App. Surf. Sci., 256, 4543-4547, 2010.
  • Y. Babur, A. Tumbul, and M. Yıldırım, “Chemically derived Zn0.90-xMn0.05Fe0.05AlxO thin films: Tuning of crystallite/grain size, optical and dielectric constants and ferromagnetic properties through Al substitutions,” Mater. Sci. Semicond. Process.., 84, 1-9, 2018.
  • W. R. Saleh, N. M. Saeed, W. A. Twej, and M. Alwan, “Synthesis Sol-Gel Derived Highly Transparent ZnO Thin Films for Optoelectronic Applications,” Adv. Mater. Phys. and Chem., 2, 11-16, 2012.
  • H. Makino and H. Shimizu, “Influence of crystallographic polarity on the opto-electrical properties of polycrystalline ZnO thin films deposited by magnetron sputtering,” App. Surf. Sci., 439, 839-844, 2018.
  • F. Aslan, A. Tumbul, A. Goktas, R. Budakoglu, and I. H. Mutlu, “Growth of ZnO nanorod arrays by one-step sol–gel process,” J. Sol-Gel Sci. Technol., 80, 389-395, 2016.
  • M. Soylu and M. J. Coskun, “Controlling the properties of ZnO thin films by varying precursor concentration,” J. Alloy. Comp., 741, 957-968, 2018.
  • P. H. Vajargah, V. Abdizadeh, R. Ebrahimifard, and M. R. Golobostanfard, “Sol–gel derived ZnO thin films: Effect of amino-additives,” App. Surf. Sci., 285, 732-743, 2013.
  • A. G. Nunez, S. A. Gil, C. Lopez, P. Roura, and A. Vila, “Role of Ethanolamine on the Stability of a Sol−Gel ZnO Ink,” J. Phys. Chem., 121, 23839-23846, 2017.
  • D. Shikha, V. Metha, S. C. Sood, and J. Sharma, “Structural and optical properties of ZnO thin films deposited by sol–gel method: effect of stabilizer concentration,” J. Mater. Sci.: Mater Electron, 26, 4902-4907, 2015.
  • J. Sengupta, R. K. Sahoo, and C. D. Mukherjee, “Effect of annealing on the structural, topographical and optical properties of sol–gel derived ZnO and AZO thin films,” Mater. Lett., 83, 84-87, 2012.
  • V. Kumar, N. Singh, R. M. Mehra, A. Kapoor, L. P. Purohit, and H. C. Swart, “Role of film thickness on the properties of ZnO thin films grown by sol-gel method,” Thin Solid Films, 539, 161-165, 2013.
  • L. Spanhel, “Colloidal ZnO nanostructures and functional coatings: A survey,” J. Sol-Gel Sci. Technol., 39, 7-24, 2006.
  • P. Bindu and S. Thomas, “Estimation of lattice strain in ZnO nanoparticles: X-ray peak profile analysis,” J. Theor. Appl. Phys., 8, 123-134, 2014.
  • M. Voigt, M. Klaumünzer, H. Theim, and W. Peukert, “Detailed analysis of the growth kinetics of ZnO Nanorods in methanol,” J. Phys. Chem., 114, 49-63, 2010.
  • R. Zamiri, A. Rebelo, G. Zamiri, A. Adnani, A. Kuashal, M. S. Belsley, and J. M. F. Ferreira, “Far-infrared optical constants of ZnO and ZnO/Ag nanostructures,” RSC Adv., 4, 2902-2908, 2014.
  • J. G. Q. Galvan, I. M. S. Jimenez, H. T. Huitle, L. A. H. Hernandez, F. M. Flores, A. H. Hernandez, E. C. Gonzalez, A. G. Cervantes, A. Z. Angel, and J. J. A. Ibarra, “Effect of precursor solution and annealing temperature on the physical properties of Sol–Gel- deposited ZnO thin films,” Result Phys., 88, 1-5, 2013.
  • X. T. Zhang, Y. C. Liu, Z. Z. Zhi, J. Y. Zhang, Y. M. Lu, D. Z. Shen, W. Xu, G. Z. Zhong, X. W. Fan, and X. G. Kong, “Resonant Raman scattering and photoluminescence from high-quality nanocrystalline ZnO thin films prepared by thermal oxidation of ZnS thin films,” J. Phys. D: Appl. Phys., vol. 34, pp. 3430-3433, Dec. 2001.
  • L. Znaidi, “Sol–gel-deposited ZnO thin films: A review,” Mater. Sci. Eng. B, vol. 174, pp. 18-30, Jul. 2010.
  • K. Sivakumar, V. S. Kumar, N. Muthukumarasamy, M. Thambidurai, and T. S. Senthil, “Influence of pH on ZnO nanocrystalline thin films prepared by sol–gel dip coating method,” Bull. Mater. Sci., vol. 35, 327-331, 2012.
  • J. Tauc, Amorphous and Liquid Semiconductors, New York: Plenum Press, 1974.

Effect of Monoethanolamine Content on the Crystallinity of ZnO Thin Films

Year 2019, , 155 - 164, 31.05.2019
https://doi.org/10.29233/sdufeffd.513412

Abstract

ZnO
is one of the most widely used semiconductors for opto-electronic applications
due to its tunable band gap energy, high
optical transparency in visible region. The effect of different monoethanolamine (MEA)
ratio on structural, morphological and optical properties of ZnO thin films was
investigated in this study. A nano-fiber like structured ZnO was fabricated
through facile sol-gel dip coating process on glass substrates without any
further treatment. We observed that the peak intensity of samples increased and
the amount of defects in the crystal could be further decreased by rising its of
monoethanolamine. Besides, the micro-fiber like grains of the ZnO covered the
glass surface quite densely when the monoethanolamine content increased. The
optical study showed that the transparency of the films could be enhanced by
increasing the amount of stabilizer.

References

  • H. Li, J. Wang, H. Liu, C. Yang, H. Xu, X. Li, and H. Cui, “Sol-gel preparation of transparent zinc oxide films with highly preferential crystal orientation,” Vacuum, 77, 57-62, 2004.
  • A. Goktas, F. Aslan, A. Tumbul, and S. H. Gunduz, “Tuning of structural, optical and dielectric constants by various transition metal doping in ZnO:TM (TM=Mn, Co, Fe) nanostructured thin films: A comparative study,” Ceram. Int., 43, 704-713, 2016.
  • S. O’Brien, L. H. K. Koh, and G. M. Crean, “ZnO thin films prepared by a singles tep sol–gel process,” Thin Solid Films, 516, 1391-1395, 2007.
  • C. Tsay and W. Hsu, “Sol–gel derived undoped and boron-doped ZnO semiconductor thin films: Preparation and Characterization,” Ceram. Int., 39, 7425-7432, 2013.
  • V. Galstyan, E. Comini, C. Baratto, G. Faglia, and G. Sberveglieri, “Nanostructured ZnO chemical gas sensors,” Ceram. Int., 41, 14239-14244, 2015.
  • V. Kumar, R. G. Singh, F. Singh, and L. P. Purohit, “Highly transparent and conducting boron doped zinc oxide films for window of Dye Sensitized Solar Cell applications,” J. Alloy. Comp., 544, 120-124, 2012.
  • M. Wang, W. Liang, Y. Yang, J. Yang, X. Cheng, S. H. Hahn, and E. J. Kim, “Sol-gel derived transparent conducting ZnO:Al thin films: Effect of crystallite orientation on conductivity and self-assembled network texture,” J. Mater Chem. Phys., 134, 845-850, 2012. J. Huang, L. Wang, R. Xu, K.Tang, W. Shi, and Y. Xia, “Growth of p-type ZnO films and fabrication of ZnO photodiode-based UV detectors,” Semicond. Sci. Technol., 24, 075025 (5pp), 2009.
  • E. M. Bachari, G. Baud, S. B. Amor, and M. Jacquet, “Structural and optical properties of sputtered ZnO,” Thin Solid Films, 348, 165-172, 1999.
  • D. L. Jiao, X. C. Zhong, W. Q. Qui, H. Zhang, Z. W. Lui, and G. Q. Zhang, “Structure and Electric Conduction in Pulsed Laser-Deposited ZnO Thin Films Individually doped with N, P or Na,” J. Electron. Mater., 47, 3521-3528, 2018.
  • D. Adolph, T. Tinberg, and T. Ive, “Growth of ZnO(0001) on GaN(0001)/4H-SiC buffer layers by plasma-assisted hybrid molecular beam epitaxy,” J. Cryst. Growth, vol. 426, pp. 129-134, Jun. 2015.
  • V. K. Ashith, G. K. Rao, S. N. Moger, and R. Smitha, “Effect of post-deposition annealing on the properties of ZnO films obtained by high temperature, micro-controller based SILAR deposition,” Ceram. Int., 44, 10669-10676, 2018.
  • H. L. Ma, Z W. Liu, D. C. Zeng, M. L. Zhong, H. Y. Yu, and E. Mikmekova, “Nanostructured ZnO films with various morphologies prepared by ultrasonic spray pyrolysis and its growing process,” App. Surf. Sci., 283, 1006-1011, 2013.
  • N. T. Son, J. S. Noh, and S. Park, “Role of ZnO thin film in the vertically aligned growth of ZnO nanorods by chemical bath deposition,” App. Surf. Sci., 379, 440-445, 2016.
  • D. Bao, H. Gu, and A. Kuang, “Sol-gel derived c-axis ZnO thin films,” Thin Solid Films, 312, 37-39, 1997.
  • Y. Li, L. Xu, X. Li, X. Shen, and A. Wang, “Effect of aging time of ZnO sol on the structural and optical properties of ZnO thin films prepared by sol–gel method,” App. Surf. Sci., 256, 4543-4547, 2010.
  • Y. Babur, A. Tumbul, and M. Yıldırım, “Chemically derived Zn0.90-xMn0.05Fe0.05AlxO thin films: Tuning of crystallite/grain size, optical and dielectric constants and ferromagnetic properties through Al substitutions,” Mater. Sci. Semicond. Process.., 84, 1-9, 2018.
  • W. R. Saleh, N. M. Saeed, W. A. Twej, and M. Alwan, “Synthesis Sol-Gel Derived Highly Transparent ZnO Thin Films for Optoelectronic Applications,” Adv. Mater. Phys. and Chem., 2, 11-16, 2012.
  • H. Makino and H. Shimizu, “Influence of crystallographic polarity on the opto-electrical properties of polycrystalline ZnO thin films deposited by magnetron sputtering,” App. Surf. Sci., 439, 839-844, 2018.
  • F. Aslan, A. Tumbul, A. Goktas, R. Budakoglu, and I. H. Mutlu, “Growth of ZnO nanorod arrays by one-step sol–gel process,” J. Sol-Gel Sci. Technol., 80, 389-395, 2016.
  • M. Soylu and M. J. Coskun, “Controlling the properties of ZnO thin films by varying precursor concentration,” J. Alloy. Comp., 741, 957-968, 2018.
  • P. H. Vajargah, V. Abdizadeh, R. Ebrahimifard, and M. R. Golobostanfard, “Sol–gel derived ZnO thin films: Effect of amino-additives,” App. Surf. Sci., 285, 732-743, 2013.
  • A. G. Nunez, S. A. Gil, C. Lopez, P. Roura, and A. Vila, “Role of Ethanolamine on the Stability of a Sol−Gel ZnO Ink,” J. Phys. Chem., 121, 23839-23846, 2017.
  • D. Shikha, V. Metha, S. C. Sood, and J. Sharma, “Structural and optical properties of ZnO thin films deposited by sol–gel method: effect of stabilizer concentration,” J. Mater. Sci.: Mater Electron, 26, 4902-4907, 2015.
  • J. Sengupta, R. K. Sahoo, and C. D. Mukherjee, “Effect of annealing on the structural, topographical and optical properties of sol–gel derived ZnO and AZO thin films,” Mater. Lett., 83, 84-87, 2012.
  • V. Kumar, N. Singh, R. M. Mehra, A. Kapoor, L. P. Purohit, and H. C. Swart, “Role of film thickness on the properties of ZnO thin films grown by sol-gel method,” Thin Solid Films, 539, 161-165, 2013.
  • L. Spanhel, “Colloidal ZnO nanostructures and functional coatings: A survey,” J. Sol-Gel Sci. Technol., 39, 7-24, 2006.
  • P. Bindu and S. Thomas, “Estimation of lattice strain in ZnO nanoparticles: X-ray peak profile analysis,” J. Theor. Appl. Phys., 8, 123-134, 2014.
  • M. Voigt, M. Klaumünzer, H. Theim, and W. Peukert, “Detailed analysis of the growth kinetics of ZnO Nanorods in methanol,” J. Phys. Chem., 114, 49-63, 2010.
  • R. Zamiri, A. Rebelo, G. Zamiri, A. Adnani, A. Kuashal, M. S. Belsley, and J. M. F. Ferreira, “Far-infrared optical constants of ZnO and ZnO/Ag nanostructures,” RSC Adv., 4, 2902-2908, 2014.
  • J. G. Q. Galvan, I. M. S. Jimenez, H. T. Huitle, L. A. H. Hernandez, F. M. Flores, A. H. Hernandez, E. C. Gonzalez, A. G. Cervantes, A. Z. Angel, and J. J. A. Ibarra, “Effect of precursor solution and annealing temperature on the physical properties of Sol–Gel- deposited ZnO thin films,” Result Phys., 88, 1-5, 2013.
  • X. T. Zhang, Y. C. Liu, Z. Z. Zhi, J. Y. Zhang, Y. M. Lu, D. Z. Shen, W. Xu, G. Z. Zhong, X. W. Fan, and X. G. Kong, “Resonant Raman scattering and photoluminescence from high-quality nanocrystalline ZnO thin films prepared by thermal oxidation of ZnS thin films,” J. Phys. D: Appl. Phys., vol. 34, pp. 3430-3433, Dec. 2001.
  • L. Znaidi, “Sol–gel-deposited ZnO thin films: A review,” Mater. Sci. Eng. B, vol. 174, pp. 18-30, Jul. 2010.
  • K. Sivakumar, V. S. Kumar, N. Muthukumarasamy, M. Thambidurai, and T. S. Senthil, “Influence of pH on ZnO nanocrystalline thin films prepared by sol–gel dip coating method,” Bull. Mater. Sci., vol. 35, 327-331, 2012.
  • J. Tauc, Amorphous and Liquid Semiconductors, New York: Plenum Press, 1974.
There are 34 citations in total.

Details

Primary Language English
Subjects Metrology, Applied and Industrial Physics
Journal Section Makaleler
Authors

Ahmet Tumbul 0000-0003-3790-9667

Publication Date May 31, 2019
Published in Issue Year 2019

Cite

IEEE A. Tumbul, “Effect of Monoethanolamine Content on the Crystallinity of ZnO Thin Films”, Süleyman Demirel University Faculty of Arts and Science Journal of Science, vol. 14, no. 1, pp. 155–164, 2019, doi: 10.29233/sdufeffd.513412.