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Cd(II) ve Co(II) Geçiş Metal Yapılı 1,5-pentanedithiol ve 1,8- octanedithiol Tetrasiyanonikel Bileşiklerinin Kırmızıaltı Spektroskopisi İle İncelenmesi

Year 2011, Volume: 6 Issue: 2, 99 - 111, 01.12.2011

Abstract

1,5-pentanedithiol (PDT) ve 1,8-octanedithiol (ODT) ligandlarının, iki değerlikli geçiş metal iyonları Co(II) ve Cd(II) ile oluşturdukları bileşiklerin 400-4000 cm-1 aralığındaki FT–IR spektrumları ilk kez sunulmaktadır. Ayrıca, M(PDT)Ni(CN)4 ve M(ODT)Ni(CN)4 (M = Co ve Cd) bileşiklerinin termo gravimetrik (TGA), diferansiyel termal (DTA), türetilmiş termal gravimetrik (DTG) analizleri (25-250) o C aralığında incelenmiş ve XRD desenleri ile elementel analizleri verilmiştir. Spektral ve termal özellikler, bileşiklerin, ML+2 katyonları ile bağlanmış Ni(CN)4
-2 iyonlarından oluşan sonsuz polimerik tabakalar ile Hofmann-tipi bileşiklere benzer yapıda olduğunu ortaya koymuştur.

References

  • Joo S.W., Han S.W., Kim K., 2001. Adsorption Characteristics of Aliphatic Dithiols on Silver and Gold Revealed by Ellipsometry and FT-IR Spectroscopy, Molecular Crystals and Liquid Crystals, 371 (1): 355-358.
  • Kamenicek J., Solichova P., Sindelar Z. 2001. Ni(II) and Co(II) Complexes With Aliphatic 1,2- Ethanedithiol And Selected N,P-Ligands, Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium Chemica, 40: 35-40.
  • Kwon C.K., Kim K., Kim M.S., Lee Y.S., 1989. Raman spectroscopic study of 1,2-ethanedithiol adsorbed on silver surface, Journal of Molecular Structure, 197, 171-180.
  • Kohli P., Taylor K.K., Harris J.J., Blanchard G.J., 1998. Assembly of covalently-coupled disulfide multilayers on gold, Journal of the American Chemical Society, 120 (46): 11962-11968.
  • Uygun Ü., Öztürk N., Türköz D., Bahçeli S., 2006. FT-IR spectroscopic study of M(1,2- Ethanedithiol)Ni(CN)·benzene (M=Co,Cd) clathrates, Journal of Inclusion Phenomena and Macrocyclic Chemistry, 54 (3-4): 187-192.
  • Öztürk T., Kartal Z., 2006. M(1,6-Hexanedithiol)Ni(CN)4 bileşiklerinin kırmızıaltı spektroskopisi ile incelenmesi (M=Ni, Cd, Co, Mn ve Zn), Süleyman Demirel University Journal of Science, 1 (1- 2): 50-56.
  • Iwamoto T., 1984. Inclusion Compounds, pp. 29-34, In: Atwood J.L., (Eds.: Davies J.E.D and Mc Nicol D.D), Academic Pres, Vol. I, London.
  • Iwamoto T., 1991. Inclusion Compounds, pp. 177-186, In Atwood J.L., (Eds.: Davies J.E.D and Mc Nicol D.D), Oxford University Press, Vol.5, London.
  • Iwamoto T., Shriver D.F., 1972. Benzene clathrates with a novel kind of metal complex host lattice. Cd(en)Cd(CN)4.2C6H6 and Cd(en)Hg(CN).2C6H6, Inorganic Chemistry, 11 (10): 2570-2572.
  • Öztürk N., Çırak Ç., Bahçeli S., 2005. FT-IR spectroscopic study of 1,5-Pentanedithiol and 1,6- Hexanedithiol adsorbed on NaA, CaA and NaY zeolites, Zeitschrift für Naturforschung A, 60a: 633-637.
  • Türköz D., Kartal Z. Bahçeli S., 2004. FT-IR Spectroscopic Study of Co(1-Propanethiol)2 Ni(CN)4.Benzene Clathrate'', Zeitschrift für Naturforschung A, 59a: 523-526. Kartal M(Cyclohexanethiol)2Ni(CN)4·(1,4-dioxane) clathrate (M = Mn, Co, Ni and Cd), Journal of Molecular Structure, 994 (1-3): 170-178. spectroscopic and thermal study of
  • Hajnalka J., Claudio P., Fabio M., Erzse´bet K., La´szlo´ N., Sergei T. Lorenzo P., 2003. Characterization of diorganotin(IV) complexes with captopril. The first crystallographically authenticated metal complex of this anti-hypertensive agent, Journal of Inorganic Biochemistry, 97 (4): 370-376.
  • Kartal Z., Türköz D., Bahçeli, S., 2004. An IR study of M(1-Propanethiol)2Ni(CN)4.G (M=Cd,Ni and G=Benzene) clathrates , Acta Physica Slovaca, 54 (2): 97-130.
  • McCullough R.L., Jones L.H., Crosby G.A., 1960. An analysis of the vibrational spectrum of the tetracyanonickelate(II) ion in a crystal lattice, Spectrochimica Acta, 16 (8): 929-944.
  • Karacan N., Tufan Y., 1995. Synthesis and spectroscopic studies of metal (II) tetracyanonickelate complexes with 1,3-Thiazolidine-2-thione, Spectroscopy Letters. 28 (5): 773-782.
  • Whiffen D.H., 1971. Spectroscopy, 2nd Edition, John Wiley and Sons, London, U.K. p. 599.
  • Giorgini M.G., Pelletti M.R., Paliani G., Cataliotti R.S., 1983.Vibrational spectra and assignments of ethylene-diamine and its deuterated derivatives, Journal of Raman Spectroscopy, 14 (1): 16-21.
  • Akyüz S., Dempster A.B., Morehouse R.L. 1974. Host-guest interactions and stability of Hofmann- type benzene and aniline clathrates studied by i.r. spectroscopy, Spectrochimica Acta Part A: Molecular Spectroscopy, 30 (10): 1989-2004.
  • Şenyel M., Parlak C., Alver O., 2008. FT-IR spectroscopic investigation of some Hofmann type complexes: M(1-phenylpiperazine)2Ni(CN)4 (M = Ni, Co, Cd, Pd or Mn), Spectrochimica Acta Part A: Molecular Spectroscopy, 70 (2): 367-375.
  • Yılmaz V.T., Karadağ A., 2000. Thermal decomposition of Hofmann-type complexes of di- and triethanolamine, Thermochimica Acta, 348 (1-2): 121-127.
  • Sopkova A., Bubanec J., 1977. Clathrate compounds of tetracyano complexes of nickel and platinum with phenol, Journal of Thermal Analysis and Calorimetry, 12 (1): 97-104.
  • Nishikiori S., Takahashi A., Ratcliffe C.I., Ripmeester J.A., 2002. X-ray and 2H NMR studies of structure and dynamics in the Hofmann-type and the Hofmann-(en)-type pyrrole clathrates, Journal of Supramolecular Chemistry, 2 (4-5): 483-496.
  • Nuri Öztürk e-mail: nuriozturk@sdu.edu.tr
  • Ümran Uygun Akduman e-mail: umranuygun@hotmail.com

The FT-IR Spectroscopic Investigation on Cd(II) and Co(II) Transition Metals 1,5-pentanedithiol and 1,8-octanedithiol Tetracyanonickelate Complexes

Year 2011, Volume: 6 Issue: 2, 99 - 111, 01.12.2011

Abstract

FT-IR spectra of the ligands, 1,5-pentanedithiol (PDT) and 1,8-octanedithiol (ODT), with their complexes with the divalent transition metal ions Co(II) and Cd(II) are reported for the first time in the 400-4000 cm-1 range. Furthermore the thermal behaviors of M(PDT)Ni(CN)4 and M(ODT)Ni(CN)4 (M = Co and Cd) compounds were studied by thermo-gravimetric analysis (TGA), differential thermal analysis (DTA) and derivative thermal gravimetric analysis (DTG) in the range of (25-250) o C and their XRD patterns and elemental analyses were presented. The spectral and thermal features suggest that the compounds are similar in structure to the Hofmann-type complexes with infinite polymeric layers formed with Ni(CN)4 -2 ions bridged by ML+2 cations.

References

  • Joo S.W., Han S.W., Kim K., 2001. Adsorption Characteristics of Aliphatic Dithiols on Silver and Gold Revealed by Ellipsometry and FT-IR Spectroscopy, Molecular Crystals and Liquid Crystals, 371 (1): 355-358.
  • Kamenicek J., Solichova P., Sindelar Z. 2001. Ni(II) and Co(II) Complexes With Aliphatic 1,2- Ethanedithiol And Selected N,P-Ligands, Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium Chemica, 40: 35-40.
  • Kwon C.K., Kim K., Kim M.S., Lee Y.S., 1989. Raman spectroscopic study of 1,2-ethanedithiol adsorbed on silver surface, Journal of Molecular Structure, 197, 171-180.
  • Kohli P., Taylor K.K., Harris J.J., Blanchard G.J., 1998. Assembly of covalently-coupled disulfide multilayers on gold, Journal of the American Chemical Society, 120 (46): 11962-11968.
  • Uygun Ü., Öztürk N., Türköz D., Bahçeli S., 2006. FT-IR spectroscopic study of M(1,2- Ethanedithiol)Ni(CN)·benzene (M=Co,Cd) clathrates, Journal of Inclusion Phenomena and Macrocyclic Chemistry, 54 (3-4): 187-192.
  • Öztürk T., Kartal Z., 2006. M(1,6-Hexanedithiol)Ni(CN)4 bileşiklerinin kırmızıaltı spektroskopisi ile incelenmesi (M=Ni, Cd, Co, Mn ve Zn), Süleyman Demirel University Journal of Science, 1 (1- 2): 50-56.
  • Iwamoto T., 1984. Inclusion Compounds, pp. 29-34, In: Atwood J.L., (Eds.: Davies J.E.D and Mc Nicol D.D), Academic Pres, Vol. I, London.
  • Iwamoto T., 1991. Inclusion Compounds, pp. 177-186, In Atwood J.L., (Eds.: Davies J.E.D and Mc Nicol D.D), Oxford University Press, Vol.5, London.
  • Iwamoto T., Shriver D.F., 1972. Benzene clathrates with a novel kind of metal complex host lattice. Cd(en)Cd(CN)4.2C6H6 and Cd(en)Hg(CN).2C6H6, Inorganic Chemistry, 11 (10): 2570-2572.
  • Öztürk N., Çırak Ç., Bahçeli S., 2005. FT-IR spectroscopic study of 1,5-Pentanedithiol and 1,6- Hexanedithiol adsorbed on NaA, CaA and NaY zeolites, Zeitschrift für Naturforschung A, 60a: 633-637.
  • Türköz D., Kartal Z. Bahçeli S., 2004. FT-IR Spectroscopic Study of Co(1-Propanethiol)2 Ni(CN)4.Benzene Clathrate'', Zeitschrift für Naturforschung A, 59a: 523-526. Kartal M(Cyclohexanethiol)2Ni(CN)4·(1,4-dioxane) clathrate (M = Mn, Co, Ni and Cd), Journal of Molecular Structure, 994 (1-3): 170-178. spectroscopic and thermal study of
  • Hajnalka J., Claudio P., Fabio M., Erzse´bet K., La´szlo´ N., Sergei T. Lorenzo P., 2003. Characterization of diorganotin(IV) complexes with captopril. The first crystallographically authenticated metal complex of this anti-hypertensive agent, Journal of Inorganic Biochemistry, 97 (4): 370-376.
  • Kartal Z., Türköz D., Bahçeli, S., 2004. An IR study of M(1-Propanethiol)2Ni(CN)4.G (M=Cd,Ni and G=Benzene) clathrates , Acta Physica Slovaca, 54 (2): 97-130.
  • McCullough R.L., Jones L.H., Crosby G.A., 1960. An analysis of the vibrational spectrum of the tetracyanonickelate(II) ion in a crystal lattice, Spectrochimica Acta, 16 (8): 929-944.
  • Karacan N., Tufan Y., 1995. Synthesis and spectroscopic studies of metal (II) tetracyanonickelate complexes with 1,3-Thiazolidine-2-thione, Spectroscopy Letters. 28 (5): 773-782.
  • Whiffen D.H., 1971. Spectroscopy, 2nd Edition, John Wiley and Sons, London, U.K. p. 599.
  • Giorgini M.G., Pelletti M.R., Paliani G., Cataliotti R.S., 1983.Vibrational spectra and assignments of ethylene-diamine and its deuterated derivatives, Journal of Raman Spectroscopy, 14 (1): 16-21.
  • Akyüz S., Dempster A.B., Morehouse R.L. 1974. Host-guest interactions and stability of Hofmann- type benzene and aniline clathrates studied by i.r. spectroscopy, Spectrochimica Acta Part A: Molecular Spectroscopy, 30 (10): 1989-2004.
  • Şenyel M., Parlak C., Alver O., 2008. FT-IR spectroscopic investigation of some Hofmann type complexes: M(1-phenylpiperazine)2Ni(CN)4 (M = Ni, Co, Cd, Pd or Mn), Spectrochimica Acta Part A: Molecular Spectroscopy, 70 (2): 367-375.
  • Yılmaz V.T., Karadağ A., 2000. Thermal decomposition of Hofmann-type complexes of di- and triethanolamine, Thermochimica Acta, 348 (1-2): 121-127.
  • Sopkova A., Bubanec J., 1977. Clathrate compounds of tetracyano complexes of nickel and platinum with phenol, Journal of Thermal Analysis and Calorimetry, 12 (1): 97-104.
  • Nishikiori S., Takahashi A., Ratcliffe C.I., Ripmeester J.A., 2002. X-ray and 2H NMR studies of structure and dynamics in the Hofmann-type and the Hofmann-(en)-type pyrrole clathrates, Journal of Supramolecular Chemistry, 2 (4-5): 483-496.
  • Nuri Öztürk e-mail: nuriozturk@sdu.edu.tr
  • Ümran Uygun Akduman e-mail: umranuygun@hotmail.com
There are 24 citations in total.

Details

Primary Language English
Subjects Metrology, Applied and Industrial Physics
Journal Section Makaleler
Authors

Semiha Bahçeli This is me

Nuri Öztürk This is me

Ümran Uygun Akduman This is me

Publication Date December 1, 2011
Published in Issue Year 2011 Volume: 6 Issue: 2

Cite

IEEE S. Bahçeli, N. Öztürk, and Ü. Uygun Akduman, “The FT-IR Spectroscopic Investigation on Cd(II) and Co(II) Transition Metals 1,5-pentanedithiol and 1,8-octanedithiol Tetracyanonickelate Complexes”, Süleyman Demirel University Faculty of Arts and Science Journal of Science, vol. 6, no. 2, pp. 99–111, 2011.