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[M(1(2H)-phthalazinone)n.Cl2] (M = Co, Cu and Mn; n = 1, 2) Bileşiklerinin Kırmızıaltı ve Mikroraman Spektroskopisi ile İncelenmeleri

Year 2012, Volume: 7 Issue: 1, 1 - 8, 04.06.2012

Abstract

Bu çalışmada, 1(2H)-fitalazinon Co(II), Cu(II) ve Mn(II) metal halid bileşikleri, elemental analiz, FT-IR ve mikro-Raman spektroskopileri ile karakterize edilmiştir. M(1(2H)-fitalazinon)n.Cl2 (M = Co, Cu ve Mn; n = 1, 2) bileşikleri ilk kez hazırlanmıştır ve titreşim dalgasayıları sunulmuştur. Deneysel olarak elde edilen sonuçlar, 1(2H)-fitalazinon ile metal iyonları arasındaki koordinasyonun, Co(II) > Mn(II) > Cu(II) olarak azalan metal-oksijen gerilme frekanslarını verdiğini göstermektedir.

Anahtar kelimeler: 1(2H)-fitalazinon, IR ve Raman spektroskopileri, Elementel analiz, Metal halid bileşikleri.

References

  • Allan, J.R., Barnes, G.A.,Brown, D.H., 1971. Some transition metal complexes of pyridazine, pthalazine and 3,4-benzocinnoline, Journal of Inorganic and Nuclear Chemistry, 33 (11): 3765- 3771.
  • Riberio da Silva, M.A.V., Cabral, J.I.T.A., 2008. Experimental study on the thermochemistry of 1- (2H)-phthalazinone and phthalhydrazide, The Journal of Chemical Thermodynamics, 40 (5): 829–835.
  • Doğruer, D. S., Küpeli, E., Yeşilada, E., Şahin, M. F., 2004. Synthesis of New 2-[1(2H)-Phthalazinon- 2-yl]acetamide and 3-[1(2H)-Phthalazinon-2-yl]propanamide Derivatives as Antinociceptive and Anti-inflammatory Agents, Archive der Pharmazie: Pharmaceutical & Medicinal Chemistry, 337: 303−310.
  • Cherkez, S., Herzig, J., Yellin, H., 1986. Synthesis, saludiuretic, and antihypertensive activity of 6,7- disubstituted 1(2H)- and 3,4-dihydro-1(2H)-phthalazinones, Journal of Medicinal Chemistry, 29 (6): 947-959.
  • Kukovec, B.M., Kodrin, I., Mihalic, Z., Furic, K., Popovic, Z., 2010. Cis–trans isomerism in cobalt(II) complexes with 3-hydroxypicolinic acid. Structural, DFT and thermal studies, Inorganica Chimica Acta, 363 (8): 1887–1896.
  • Ahuja, I.S., Prasad, I., 1976. Isonicotinamide complexes with some metal(II) halides and pseudohalides, Inorganic and Nuclear Chemistry Letters, 12 (10): 777-784.
  • Büyükgüngör, O., Odabasoglu, M., Narayana, B., Vijesh, A.M., Yathirajan, H.S., 2007. Phthalazin- 1(2H)-one, Acta Crystallographica Section E: Structure Reports Online, E63 (7): o3198.
  • Gökce, H., Bahçeli, S., 2010. Analysis of molecular structure and vibrational spectra of 1(2H)- phthalazinone, Journal of Molecular Structure, 967 (1-3): 42–46.
  • Nakamoto, K., 2009. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B: Applications in Coordination, Organometallic and Bioinorganic Chemistry, 6th ed., John Wiley & Sons, Inc., New York, p. 424.
  • Stuart, B.H., 2004. Infrared Spectroscopy: Fundamentals and Applications, John Wiley & Sons, England, p. 242.
  • Silverstein, R.M., Webster, F.X., 1998. Spectroscopic Identification of Organic Compound, 6th ed., John Wiley & Sons, New York, p. 512.
  • Lane, T.J., Nakagawa, I., Walter, J.L., Kandathil, A.J., 1962. Infrared Investigation of Certain Imidazole Derivatives and their Metal Chelates, Inorganic Chemistry, 1 (2): 267-276.
  • Bardak, F., Ataç, A., Kurt, M., 2009. Infrared and Raman study of some isonicotinic acid metal(II) halide and tetracyanonickelate complexes Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71 (5): 1896–1900.
  • Berney, C.V., Weber, J.H., 1967. Complexes of sulfoxides. II. Metal-oxygen stretching vibrations in complexes of dimethyl sulfoxide and dimethyl sulfoxide-d6 and the point group of the cation, Inorganic Chemistry, 7 (2): 283-287.
  • Nuri Öztürk e-mail: nuriozturk@sdu.edu.tr

Infrared and Micro-Raman Spectroscopic Studies of [M(1(2H)- phthalazinone)n.Cl2] (M = Co, Cu and Mn; n = 1, 2) Complexes

Year 2012, Volume: 7 Issue: 1, 1 - 8, 04.06.2012

Abstract

In this study, the Co(II), Cu(II) and Mn(II) metal halide
complexes of 1(2H)-phthalazinone were characterized by elemental
analysis, FT-IR and micro-Raman spectroscopies. The
M(1(2H)-phthalazinone)n.Cl2 (M = Co, Cu and Mn; n = 1, 2) complexes have
been prepared for the first time and their vibrational wavenumbers were
reported. The results obtained experimentally indicate that the
coordination between 1(2H)-phthalazinone and different metal ions gives
different metal-oxygen stretching frequencies which decrease in the
following order Co(II) > Mn(II) > Cu(II).

References

  • Allan, J.R., Barnes, G.A.,Brown, D.H., 1971. Some transition metal complexes of pyridazine, pthalazine and 3,4-benzocinnoline, Journal of Inorganic and Nuclear Chemistry, 33 (11): 3765- 3771.
  • Riberio da Silva, M.A.V., Cabral, J.I.T.A., 2008. Experimental study on the thermochemistry of 1- (2H)-phthalazinone and phthalhydrazide, The Journal of Chemical Thermodynamics, 40 (5): 829–835.
  • Doğruer, D. S., Küpeli, E., Yeşilada, E., Şahin, M. F., 2004. Synthesis of New 2-[1(2H)-Phthalazinon- 2-yl]acetamide and 3-[1(2H)-Phthalazinon-2-yl]propanamide Derivatives as Antinociceptive and Anti-inflammatory Agents, Archive der Pharmazie: Pharmaceutical & Medicinal Chemistry, 337: 303−310.
  • Cherkez, S., Herzig, J., Yellin, H., 1986. Synthesis, saludiuretic, and antihypertensive activity of 6,7- disubstituted 1(2H)- and 3,4-dihydro-1(2H)-phthalazinones, Journal of Medicinal Chemistry, 29 (6): 947-959.
  • Kukovec, B.M., Kodrin, I., Mihalic, Z., Furic, K., Popovic, Z., 2010. Cis–trans isomerism in cobalt(II) complexes with 3-hydroxypicolinic acid. Structural, DFT and thermal studies, Inorganica Chimica Acta, 363 (8): 1887–1896.
  • Ahuja, I.S., Prasad, I., 1976. Isonicotinamide complexes with some metal(II) halides and pseudohalides, Inorganic and Nuclear Chemistry Letters, 12 (10): 777-784.
  • Büyükgüngör, O., Odabasoglu, M., Narayana, B., Vijesh, A.M., Yathirajan, H.S., 2007. Phthalazin- 1(2H)-one, Acta Crystallographica Section E: Structure Reports Online, E63 (7): o3198.
  • Gökce, H., Bahçeli, S., 2010. Analysis of molecular structure and vibrational spectra of 1(2H)- phthalazinone, Journal of Molecular Structure, 967 (1-3): 42–46.
  • Nakamoto, K., 2009. Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part B: Applications in Coordination, Organometallic and Bioinorganic Chemistry, 6th ed., John Wiley & Sons, Inc., New York, p. 424.
  • Stuart, B.H., 2004. Infrared Spectroscopy: Fundamentals and Applications, John Wiley & Sons, England, p. 242.
  • Silverstein, R.M., Webster, F.X., 1998. Spectroscopic Identification of Organic Compound, 6th ed., John Wiley & Sons, New York, p. 512.
  • Lane, T.J., Nakagawa, I., Walter, J.L., Kandathil, A.J., 1962. Infrared Investigation of Certain Imidazole Derivatives and their Metal Chelates, Inorganic Chemistry, 1 (2): 267-276.
  • Bardak, F., Ataç, A., Kurt, M., 2009. Infrared and Raman study of some isonicotinic acid metal(II) halide and tetracyanonickelate complexes Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71 (5): 1896–1900.
  • Berney, C.V., Weber, J.H., 1967. Complexes of sulfoxides. II. Metal-oxygen stretching vibrations in complexes of dimethyl sulfoxide and dimethyl sulfoxide-d6 and the point group of the cation, Inorganic Chemistry, 7 (2): 283-287.
  • Nuri Öztürk e-mail: nuriozturk@sdu.edu.tr
There are 15 citations in total.

Details

Primary Language English
Subjects Metrology, Applied and Industrial Physics
Journal Section Makaleler
Authors

Nuri Öztürk This is me

Semiha Bahçeli This is me

Publication Date June 4, 2012
Published in Issue Year 2012 Volume: 7 Issue: 1

Cite

IEEE N. Öztürk and S. Bahçeli, “Infrared and Micro-Raman Spectroscopic Studies of [M(1(2H)- phthalazinone)n.Cl2] (M = Co, Cu and Mn; n = 1, 2) Complexes”, Süleyman Demirel University Faculty of Arts and Science Journal of Science, vol. 7, no. 1, pp. 1–8, 2012.