Year 2013, Volume 8 , Issue 2, Pages 175 - 189 2013-12-05

Synthesis and Investigation Absorption Features of Some Novel Hetarylazo Dyes Derived from Calix[4]resorcinarene

İzzet Şener [1] , Koray Şarkaya [2]


In this study, several derivatives of amines were diazotized and coupled with 3aminocrotonitrile to give 2-arylhydrazon-3-ketiminocrotononitrile. The synthesized components were then refluxed with hydrazine hydrate in ethanol to give a series of dyes 5-amino-4-arylazo-3-ethyl-1'HPyrazole. The synthesized dyes were diazotised and coupled with resorcinarene, which was obtained from condensation of between resorcinol and acetaldehyde, to give a new synthesis of azo dyes based on resorcinarene. The structures of synthesized dyes based on resorcinarene were characterized by spectral methods. The effect of varying solvents, acid and base upon the absorption spectra of resultant dyes has been investigated
In this study, several derivatives of amines were diazotized and coupled with 3-aminocrotonitrile to give 2-arylhydrazon-3-ketiminocrotononitrile. The synthesized components were then refluxed with hydrazine hydrate in ethanol to give a series of dyes 5-amino-4-arylazo-3-ethyl-1'H-Pyrazole. The synthesized dyes were diazotised and coupled with resorcinarene, which was obtained from condensation of between resorcinol and acetaldehyde, to give a new synthesis of azo dyes based on resorcinarene. The structures of synthesized dyes based on resorcinarene were characterized by spectral methods. The effect of varying solvents, acid and base upon the absorption spectra of resultant dyes has been investigated. Key words: Resorcinarene, Azo Dyes, Absorption Spectra, Solvent Effect, Acid-Base Effect Rezorsinaren Bazlı Azo Boyarmaddelerin Sentezi ve Absorpsiyon Özelliklerinin İncelenmesi Özet: Bu çalışmada, çeşitli amin türevleri diazolanmış ve 3-aminokrotonitril ile kenetlenerek 2-arilhidrazon-3-ketiminokrotononitril bileşikleri elde edilmiştir. Elde edilen bileşikler, hidrazinhidrat ile etanol içerisinde reflaks edilerek bir seri 5-amino-4-arilazo-3-metil-1'H-pirazol boyaları elde edilmiştir. Elde edilen boyalar diazonlarak rezorsinol ve asetaldehit arasındaki kondenzasyondan elde edilen rezorsinaren bileşiği ile kenetlenmiş ve rezorsinaren bazlı azo boyarmaddeler sentezlenmiştir. Sentezlenen rezorsinaren bazlı azoboyarmaddelerin yapıları spektrofotometrik yöntemler kullanılarak incelendi. Sentezlenen boyarmaddelerin görünür bölge absorpsiyon spektrumları üzerine değişik çözücü, asit ve baz etkileri incelendi. Anahtar kelimeler: Rezorsiaren, Azo Boyarmadde, Absorpsiyon Spektrumu, Çözücü Etkisi, Asit-Baz Etkisi
Rezorsiaren, Azo Boyarmadde, Absorpsiyon Spektrumu, Çözücü Etkisi, Asit-Baz Etkisi
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Primary Language en
Subjects Engineering, Chemical
Journal Section Makaleler
Authors

Author: İzzet Şener

Author: Koray Şarkaya

Dates

Publication Date : December 5, 2013

Bibtex
APA Şener, İ , Şarkaya, K . (). . , 8 (2) , 175-189 . Retrieved from https://dergipark.org.tr/en/pub/sdufeffd/issue/11278/134767
MLA Şener, İ , Şarkaya, K . "". 8 ( ): 175-189 <https://dergipark.org.tr/en/pub/sdufeffd/issue/11278/134767>
Chicago Şener, İ , Şarkaya, K . "". 8 ( ): 175-189
RIS TY - JOUR T1 - AU - İzzet Şener , Koray Şarkaya Y1 - 2013 PY - 2013 N1 - DO - T2 - Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi JF - Journal JO - JOR SP - 175 EP - 189 VL - 8 IS - 2 SN - -1306-7575 M3 - UR - Y2 - 2019 ER -
EndNote %0 Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi %A İzzet Şener , Koray Şarkaya %T %D 2013 %J Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi %P -1306-7575 %V 8 %N 2 %R %U
ISNAD Şener, İzzet , Şarkaya, Koray . "". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 8 / 2 (December 2013): 175-189 .
AMA Şener İ , Şarkaya K . . SDÜFEFFD. 2013; 8(2): 175-189.
Vancouver Şener İ , Şarkaya K . . Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi. 2013; 8(2): 189-175.