Year 2020, Volume 15 , Issue 1, Pages 177 - 193 2020-05-31

The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions
Birinci Sıra Geçiş Metali İyonlarını İçeren ONO, ONNO ve O3N3 Tipi Schiff Bazı Komplekslerinin Elektron İyonlaştırma Kütle Spektrumları

Emine Kübra İNAL [1] , Orhan ATAKOL [2] , Mehmet Abdulkadir AKAY [3]


Mono-, di- and trinuclear complexes of Fe(III), Co(II), Ni(II), and Cu(II) ions with Bis-N,N'(salicylidene)-1,3-diaminopropane (LH2), Bis-N,N'(salicylidene)-2,2'-dimethyl-1,3-diaminopropane (LDMH2), N(salicylidene)-2-hydroxyaniline (SAP), and Tris-N,N',N''(salicylidene)-2,2',2''-aminoethylamine (Trensal) were prepared and ionized with 30-110 eV electrons in direct inlet (DI). Compounds with metal-oxygen covalent bonds were observed to give molecular peaks, whereas polynuclear complexes containing coordinative bonds did not have such peaks. It was concluded that the coordinative bonds were dissociated by electron impact (EI). The thermogravimetric analysis reveals that the molecular peak observed for the mononuclear complexes which are stable up to 300 °C is also the base peak. The peaks obtained for the di- and trinuclear complexes that decomposed at these temperatures could not be observed as a molecular signal. The resulting fragments were evaluated and compared with the literature data.
Bis-N,N'(salisiliden)-1,3-diaminopropan (LH2), Bis-N,N'(salisiliden)-2,2'-dimetil-1,3-diaminopropan (LDMH2), N(salisiliden)-2-hidroksianilin (SAP) ve Tris-N,N',N''(salisiliden)-2,2',2''-aminoetilamin (Trensal) ile tek, iki ve üç çekirdekli Fe(III), Co(II), Ni(II) ve Cu(II) kompleksleri hazırlanmış ve direkt inlet (DI) giriş sisteminde 30-110 eV enerjili elektronlarla iyonlaştırılmıştır. Metal-oksijen kovalent bağı içeren bileşiklerde moleküler pik gözlenirken koordinatif bağ içeren çok çekirdekli komplekslerde bu pikler görülmemiştir. Koordinatif bağların elektron etkisi (EI) ile parçalandığı sonucuna varılmıştır. Termogravimetrik analiz, 300 °C'ye kadar kararlı olan tek çekirdekli kompleksler için gözlenen moleküler pikin ayrıca temel pik olduğunu da ortaya koymaktadır. Bu sıcaklıklarda parçalanan iki ve üç çekirdekli kompleksler için elde edilen pikler, moleküler sinyal olarak gözlenememiştir. Elde edilen fragmentler değerlendirilerek literatür verileri ile karşılaştırılmıştır.
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Primary Language en
Subjects Engineering, Chemical
Journal Section Makaleler
Authors

Orcid: 0000-0001-8334-2791
Author: Emine Kübra İNAL (Primary Author)
Institution: ANKARA UNIVERSITY
Country: Turkey


Orcid: 0000-0003-0977-6588
Author: Orhan ATAKOL
Institution: ANKARA UNIVERSITY
Country: Turkey


Orcid: 0000-0001-5763-4379
Author: Mehmet Abdulkadir AKAY
Institution: ANKARA UNIVERSITY
Country: Turkey


Supporting Institution Ankara University Scientific Research Projects Coordination Unit
Project Number 16L0430008
Thanks Authors thank to TUBITAK for financial support of E. K. İnal (Ph.D. Student).
Dates

Publication Date : May 31, 2020

Bibtex @research article { sdufeffd684472, journal = {Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi}, issn = {}, eissn = {1306-7575}, address = {}, publisher = {Süleyman Demirel University}, year = {2020}, volume = {15}, pages = {177 - 193}, doi = {10.29233/sdufeffd.684472}, title = {The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions}, key = {cite}, author = {İnal, Emine Kübra and Atakol, Orhan and Akay, Mehmet Abdulkadir} }
APA İnal, E , Atakol, O , Akay, M . (2020). The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions . Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi , 15 (1) , 177-193 . DOI: 10.29233/sdufeffd.684472
MLA İnal, E , Atakol, O , Akay, M . "The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions" . Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 15 (2020 ): 177-193 <https://dergipark.org.tr/en/pub/sdufeffd/issue/54573/684472>
Chicago İnal, E , Atakol, O , Akay, M . "The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 15 (2020 ): 177-193
RIS TY - JOUR T1 - The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions AU - Emine Kübra İnal , Orhan Atakol , Mehmet Abdulkadir Akay Y1 - 2020 PY - 2020 N1 - doi: 10.29233/sdufeffd.684472 DO - 10.29233/sdufeffd.684472 T2 - Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi JF - Journal JO - JOR SP - 177 EP - 193 VL - 15 IS - 1 SN - -1306-7575 M3 - doi: 10.29233/sdufeffd.684472 UR - https://doi.org/10.29233/sdufeffd.684472 Y2 - 2020 ER -
EndNote %0 Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions %A Emine Kübra İnal , Orhan Atakol , Mehmet Abdulkadir Akay %T The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions %D 2020 %J Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi %P -1306-7575 %V 15 %N 1 %R doi: 10.29233/sdufeffd.684472 %U 10.29233/sdufeffd.684472
ISNAD İnal, Emine Kübra , Atakol, Orhan , Akay, Mehmet Abdulkadir . "The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions". Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi 15 / 1 (May 2020): 177-193 . https://doi.org/10.29233/sdufeffd.684472
AMA İnal E , Atakol O , Akay M . The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions. SDÜFEFFD. 2020; 15(1): 177-193.
Vancouver İnal E , Atakol O , Akay M . The Electron Ionization Mass Spectra of ONO, ONNO and O3N3 Type Schiff Base Complexes Containing First Row Transition Metal Ions. Süleyman Demirel Üniversitesi Fen Edebiyat Fakültesi Fen Dergisi. 2020; 15(1): 177-193.