Boya Duyarlı Güneş Pillleri için Karbazol Tiyofen Türevli Moleküllerin Sentezi ve Karakterizasyonu

Year 2021, Volume: 16 Issue: 1, 179 - 188, 27.05.2021

Çiğdem Erden Kamuran Görgün

https://doi.org/10.29233/sdufeffd.751760

Abstract

Bu çalışmada ilk olarak, karbazol başlangıç maddesi kullanılarak, N-bromo süksinimid ile bromlama reaksiyonu yapılmış ve 3,6-dibromokarbazol (II) elde edilmiştir. Daha sonra, 3,6-dibromokarbazol (II) ve oktil bromür kullanılarak alkilleme reaksiyonu yapılmış ve 3,6-dibromo-9-oktilkarbazol (III) elde edilmiştir. Son aşamada ise Suzuki-Miyaura çapraz kenetlenme reaksiyonu ile farklı arilboronik asitler kullanılarak, D-A sistemine uygun literatürde olmayan yeni karbazol türevli maddeler 3,6-bis-benzo[b]tiyofen-2-il-9-oktil-9H-karbazol (IV) ve 3,6-bis-(5-kloro-tiyofen-2-il)-9-oktilkarbazol (V) sentezlenmiştir. Sentezlenen bu maddelerin yapıları 1H-NMR ve 13C-NMR spektroskopik yöntemler kullanılarak aydınlatılmıştır. Ayrıca yeni sentezlenen IV ve V numaralı moleküllerin, boya duyarlı güneş pillerinde (BDGP) boya malzemesi olarak kullanımı da araştırılmıştır. Bunun için BDGP-IV ve BDGP-V kodlu piller hazırlanıp, elektriksel karakterizasyonları yapılmıştır.

Keywords

Karbazol, Suzuki-Miyaura, Boya Duyarlı Güneş Pilleri

Thanks

Boya Duyarlı Güneş Pillerinin fabrikasyonu ve ölçümlerindeki katkılardan dolayı Eskişehir Teknik Üniversitesi Fen Fakültesi öğretim üyesi Prof. Dr. Yasemin Çağlar’a teşekkür ederiz.

Synthesis and Characterization of Carbazole Thiophene Derived Molecules for Dye Sensitized Solar Cells

Abstract

In this study, firstly, the bromination reaction with N-bromo succinimide was carried out using the carbazole as a starting material and 3,6-dibromocarbazole (II) was obtained. Then, the alkylation reaction was carried out which was using octyl bromide with 3,6-dibromocarbazole to obtain 3,6-dibromo-9-octylcarbazole (III). In the last stage, the novel carbazole-derived substances 3,6-bis-benzo[b]tiyofen-2-il-9-oktil-9H-karbazol (IV) and 3,6-bis-(5-kloro-tiyofen-2-il)-9-oktilkarbazol (V) which is suitable for the D-A system and do not exist in the literature were synthesized with Suzuki-Miyaura cross-coupling reaction by using different arylboronic acids. Characterizations of these synthesized substances were performed by using 1H-NMR and 13C-NMR spectroscopic methods. In addition, it has been investigated the usage as dye materials of these synthesized substances in dye sensitized solar cells (BDGP). In this scope, BDGP-IV and BDGP-V cells were fabricated and their electrical characterizations were performed.

Keywords

Carbazole, Suzuki-Miyaura, Dye sensitized solar cells.

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