Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği

Melike Yalılı Kılıç; Kadir Kestioğlu; Gonca Kaya

doi:10.19113/sdufbed.81680

Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği

Abstract

Bu çalışmada Balıkesir'in Edremit ilçesinde üç fazlı sisteme göre zeytinyağı üretimi yapan bir fabrikanın atıksularının (karasu) fiziko-kimyasal arıtılabilirliği araştırılmıştır. İncelenen karasuda öncelikle asit kraking işlemi yapılarak yağlı kısmın atıksudan ayrılması sağlanmıştır. Bu işlem sonucunda KOİ'de %53, AKM'de %91, fenolde ise %31 oranlarında giderim sağlanmıştır. Daha sonra asit kraking çıkışından alınan atıksuda, Chitosan, SDS (Sodyum dodesil sülfat) ve FeCl3 kullanılarak kimyasal arıtma yapılmıştır. Kimyasal arıtılabilirlik çalışması neticesinde ise, pH=6'da, 50 mg/L Chitosan, 0,6 g/L SDS ve 2500 mg/L FeCl3 dozlarında, KOİ'de %68 oranında giderme verimi elde edilmiştir. Bu arıtılabilirlik çalışmasına göre, karasuyun KOİ değeri 128000 mg/L'den 19200 mg/L değerine %85'lik bir verimle indirilebilmiştir. Karasuyun SKKY'nde verilen deşarj kriterine kadar (KOİ=230 mg/L) arıtılabilmesi için, fiziko-kimyasal arıtmadan sonra ileri arıtma tekniklerine ihtiyaç duyulduğu düşünülmektedir. Anahtar Kelimeler: Arıtılabilirlik, Chitosan, FeCl3, Fiziko-Kimyasal Arıtma, Karasu, SDS

Keywords

Arıtılabilirlik, Chitosan, FeCl3, Fiziko-Kimyasal Arıtma, Karasu, SDS

References

Aktaş, S., Imre, S., Ersoy, L. 2001. Characterization and Lime Treatment of Olive Mill Wastewater. Water Research, 35(9), 2336-2340.
Al-Malah, K., Azzam, M.O.J., Abu-Lail, N.I. 2000. Olive Mills Effluent (OME) Wastewater Post-Treatment Using Activated Clay. Separation and Purification Technology, 20, 225-234.
Anonymous 2004. Water Pollution Control Regulation. 31 December 2004 Date and 25687 Numbered Official Newspaper, Ministry of Environment and Forest, Ankara.
APHA, AWWA, WCPF 1998. Standard Methods for the Examination of Water and Wastewater. 20th Eddition American Public Health Association, Washington D.C., USA.
Arvanitoyannis, I.S., Kassaveti, A., Stefanatos, S. 2007. Olive Oil Waste Treatment: A Comparative and Critical Presentation of Methods, Advantages & Disadvantages. Critical Reviews in Food Science and Nutrition, 47,187-229.
Azzam, M.O.J., Al-Malah, K.I., Abu-Lail, N.I. 2004. Dynamic Post-Treatment Response of Olive Mill Effluent Wastewater Using Activated Carbon, Journal of Environmental Science and Health Part A-Toxic/Hazardous Substances & Environmental Engineering, A39(1), 269-280.
Boari, G., Mancini, I.M. 1990. Combined Treatments of Urban and Olive Mill Effluents in Apulia, Italy, Water Science & Technology, 22, 235-240.
Brenes, M., Garcia, A., Garcia, P., Rios, J.J., Garrido, A. 1999. Phenolic Compounds in Spanish Olive Oils. J. Agric. Food Chem., 47, 3535-3540.

Bressan, M., Liberatore, L., D’Alessandro, N., Tonucci, L., Belli, C., Ranalli, G. 2004. Improved Combined Chemical and Biological Treatments of Olive Oil Mill Wastewaters. J. Agric. Food Chem., 52, 1228-1233.
Canizares, P., Lobato, J., Paz, R., Rodrigo, M.A., Saez, C. 2007. Advanced Oxidation Processes for the Treatment of Olive-Oil Mills Wastewater. Chemosphere, 67, 832-838.
Cossu, R., Blakey, N., Cannas, P. 1993. Influence of Codisposal of Municipal Solid Waste and Olive Vegetation Water on the Anaerobic Digestion of a Sanitary Landfill. Water Science & Technology, 27, 261-271.
De Rosa, S., Giordano, G., Granato, T., Katovic, A., Siciliano, A., Tripicchio, F. 2005. Chemical Pretreatment of Olive Oil Mill Wastewater Using A Metal-Organic Framework Catalyst. J. Agric. Food Chem., 53, 8306-8309.
Ergüder, T.H., Güven, E., Demirer, G.N. 2000. Anaerobic Treatment of Olive Mill Wastes in Batch Reactors. Process Biochemistry, 36, 243248.
Fadil, K., Chahlaoui, A., Ouahbi, A., Zaid, A., Borja, R. 2003. Aerobic Biodegradation and Detoxication of Wastewaters from the Olive Oil Industry. International Biodeterioration & Biodegradation, 51, 37-41.
Ginos, A., Manios, T., Mantzavinos, D. 2006. Treatment of Olive Mill Effluents by Coagulation– Focculation–Hydrogen Peroxide Oxidation and Effect on Phytotoxicity. Journal of Hazardous Materials B, 133, 135-142.
Hamdi, M. 1993. Thermoacidic Precipitation of Darkly Coloured Polyphenols of Olive Mill Wastewaters. Environmental Technology, 14, 495-500.
Inan, H., Dimoglo, A., Şimşek, H., Karpuzcu, M. 2004. Olive Oil Mill Wastewater Treatment by Means of Electro-Coagulation. Separation and Purification Technology, 36, 23-31.
Kavaklı, M. 2002. Environmental Problems Resulting from Olive Oil Production and Selective Disposal Alternatives. In: Azbar N, Vardar N, Akın M, Cevilan I, editors. Proceedings of the First International Workshop on Environmental Problems in Olive Oil Production and Solutions, 07-09 June 2002, Balıkesir, 109-120.
Kestioğlu, K., Yonar, T., Azbar, N. 2005. Feasibility of Physico-Chemical Treatment and Advanced Oxidation Processes (AOPs) as a Means of Pretreatment of Olive Mill Effluent (OME). Process Biochemistry, 40, 2409-2416.
Khoufi, S., Aouissaoui, H., Penninckx, M., Sayadi, S. 2004. Application of Electro-Fenton Oxidation for the Detoxification of Olive Mill Wastewater Phenolic Compounds. Water Science and Technology, 49(4), 97-102.
Khoufi, S., Aloui, F., Sayadi, S. 2006. Treatment of Olive Oil Mill Wastewater by Combined Process Electro-Fenton Reaction and Anaerobic Digestion. Water Research, 40, 2007-2016.
Kocaer, F.O., Uçaroğlu, S., Başkaya, H.S. 2004. Land Disposal of Olive Oil Vegetation Water. University of Uludag Journal of the Faculty of Engineering and Architecture, 9(2), 69-77.
Kotsou, M., Kyriacou, A., Lasaridi, K., Pilidis, G. 2004. Integrated Aerobic Biological Treatment and Chemical Oxidation with Fenton’s Reagent for the Processing of Green Table Olive Wastewater. Process Biochemistry, 39, 1653-1660.
Meyssami, B., Kasaeian, A.B. 2005. Use of Coagulants in Treatment of Olive Oil Wastewater Model Solutions by Induced Air Fotation. Bioresource Technology, 96, 303-307.
Oktav, E., Şengül, F. 2003. Treatment of Olive Oil Mill Wastewaters by Distillation Method. Journal of Water Pollution Control, 13(3), 8-17.
Oktav, E., Çatalkaya, E., Şengül, F. 2003. Treatment of Olive Oil Mill Wastewaters with Chemical Treatment Methods. University of Dokuz Eylül Faculty of Engineering Journal of Science and Engineering, 5(3), 11-21.
Paraskeva, P., Diamadopoulos, E. 2006. Review Technologies for Olive Mill Wastewater (OMW) Treatment: A Review. Journal of Chemical Technology and Biotechnology, 81, 1475-1485.
Paraskeva, C.A., Papadakis, V.G., Tsarouchi, E., Kanellopoulou, D.G., Koutsoukos, P.G. 2007. Membrane Processing for Olive Mill Wastewater Fractionation. Desalination, 213, 218-229.
Rizzo, L., Lofrano, G., Grassi, M., Belgiorno, V. 2008. Pre-treatment of Olive Mill Wastewater by Chitosan Coagulation and Advanced Oxidation Processes. Separation and Purification Technology, 63, 648-653.
Sarika, R., Kalogerakis, N., Mantzavinos, D. 2005. Treatment of Olive Mill Effluents Part II. Complete Removal of Solids by Direct Flocculation with Poly-Electrolytes. Environment International, 31, 297-304.
Scioli, C., Vollaro, L. 1997. Use of Yarrowia Lipolytica to Reduce Pollution in Olive Mill Wastewaters. Water Research, 31(10), 2520-2524.
Şengül, F., Oktav, E., Çokay Çatalkaya, E. 2002. Waste Characteristics of Varius OOM: Treatment and Disposal Technologies of OOMW. In: Azbar N, Vardar N, Akın M, Cevilan I, editors. Proceedings of the First International Workshop on Environmental Problems in Olive Oil Production and Solutions, 07-09 June 2002, Balıkesir, 35-49.
Tezcan Ün, Ü., Uğur, S., Koparal, A.S., Bakır Öğütveren, Ü. 2006. Electrocoagulation of Olive Mill Wastewaters. Separation and Purification Technology, 52, 136-141.
Tsonis, S.P., Girigeropoulos, S.G. 1993. Anaerobic Treatability of Olive Oil Mill Wastewater. Water Science & Technology, 28, 35-44.
Tziotzios, G., Michailakis, S., Vayenas, D.V. 2007. Aerobic Biological Treatment of Olive Mill Wastewater by Olive Pulp Bacteria, International Biodeterioration & Biodegradation, 60, 209-214.

Details

Primary Language

English

Subjects

-

Journal Section

-

Authors

Melike Yalılı Kılıç This is me

Kadir Kestioğlu This is me

Gonca Kaya This is me

Publication Date

February 26, 2014

Submission Date

February 26, 2014

Acceptance Date

-

Published in Issue

Year 2009 Volume: 13 Number: 3

DOI

https://doi.org/10.19113/sdufbed.81680

IZ

https://izlik.org/JA73SM85UT

Cite

RIS / Bibtex

APA

Yalılı Kılıç, M., Kestioğlu, K., & Kaya, G. (2014). Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 13(3), 271-276. https://doi.org/10.19113/sdufbed.81680

AMA

1.Yalılı Kılıç M, Kestioğlu K, Kaya G. Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği. J. Nat. Appl. Sci. 2014;13(3):271-276. doi:10.19113/sdufbed.81680

Chicago

Yalılı Kılıç, Melike, Kadir Kestioğlu, and Gonca Kaya. 2014. “Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13 (3): 271-76. https://doi.org/10.19113/sdufbed.81680.

EndNote

Yalılı Kılıç M, Kestioğlu K, Kaya G (February 1, 2014) Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13 3 271–276.

IEEE

[1]M. Yalılı Kılıç, K. Kestioğlu, and G. Kaya, “Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği”, J. Nat. Appl. Sci., vol. 13, no. 3, pp. 271–276, Feb. 2014, doi: 10.19113/sdufbed.81680.

ISNAD

Yalılı Kılıç, Melike - Kestioğlu, Kadir - Kaya, Gonca. “Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 13/3 (February 1, 2014): 271-276. https://doi.org/10.19113/sdufbed.81680.

JAMA

1.Yalılı Kılıç M, Kestioğlu K, Kaya G. Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği. J. Nat. Appl. Sci. 2014;13:271–276.

MLA

Yalılı Kılıç, Melike, et al. “Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 13, no. 3, Feb. 2014, pp. 271-6, doi:10.19113/sdufbed.81680.

Vancouver

1.Melike Yalılı Kılıç, Kadir Kestioğlu, Gonca Kaya. Zeytin Karasuyunun Fiziko-Kimyasal Arıtılabilirliği. J. Nat. Appl. Sci. 2014 Feb. 1;13(3):271-6. doi:10.19113/sdufbed.81680