Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu

Müge Sarı Yılmaz

doi:10.19113/sdufbed.69265

Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu

Abstract

Bu çalışmada, saf silika kaynağından üretilen mezogözenekli silika MCM-41’in yüzeyi aşılama yöntemiyle amin grupları ile fonksiyonelleştirilmiştir. Fonksiyonelleştirilen ürünün karakterizasyonu X-ışınları difraktometresi (XRD), termogravimetri/diferansiyel termal analiz (TG/DTA), Fourier dönüşümlü infrared spektroskopisi (FTIR) ve Brunauer-Emmett-Teller (BET) cihazında gerçekleştirilmiştir. Fonksiyonelleştirilen ve fonksiyonelleştirilmemiş MCM-41 adsorbanlarının CO₂ adsorpsiyon kapasiteleri 25, 75 ve 100°C’de TG/DTA cihazı ile belirlenmiştir. Sonuç olarak, fonksiyonelleştirilen MCM-41’in daha yüksek CO₂ adsorpsiyon kapasitesine sahip olduğu görülmüştür.

Keywords

MCM-41,CO2; Adsorpsiyon; Aşılama; Amin grubu

References

[1] Chang, A.C.C., Chuang, S.S.C., Gray, M., Soong, Y., 2003. In-Situ Infrared Study of CO2 adsorption on SBA-15 grafted with γ-(Aminopropyl) triethoxysilane. Energy Fuels, 17(2003), 468-476.
[2] Metz, S.B., Davidson, O., de Coninck, H., Loos, M. Meyer, L., 2005. IPCC special report on carbon dioxide capture and storage. Cambridge University Press.
[3] Harlick, J. E. P., Tezel, F. H., 2004. An experimental adsorbent screening study for CO2 removal from N2. Microporous and Mesoporous Materials, 76(2004), 71-79.
[4] Jaramillo, E., Chandross, M., 2004. Adsorption of Small Molecules in LTA Zeolites. 1. NH3, CO2, and H2O in Zeolite 4A. The Journal of Physical Chemistry B, 108(2004), 20155-20159.
[5] Siriwardane, R. V., Shen, M. S., Fisher, E. P., Poston, J.A., 2001. Adsorption of CO2 on molecular sieves and activated carbon. Energy and Fuels, 15(2001), 279-284.
[6] Na, B. K., Lee, H., Koo, K. K., Song, H. K., 2002. Effect of
rinse and recycle methods on the pressure swing adsorption process to recover CO2 from power plant flue gas using activated carbon. Industrial and Engineering Chemistry Research, 41(2002), 5498-5503.
[7] Gomes V. G., Yee, K. W. K., 2002. Pressure swing adsorption for carbon dioxide sequestration from exhaust gases. Separation and Purification Technology, 28(2002), 161-171.

[8] Ram Reddy, M. K., Xu, Z. P., Lu, G. Q., Diniz da Costa, J. C., 2006. Layered double hydroxides for CO2 capture: structure evolution and regeneration. Industrial and Engineering Chemistry Research, 45(2006), 7504-7509.
[9] Feng, B., An, H., Tan, E., 2007. Screening of CO2 adsorbing materials for zero emission power generation systems. Energy and Fuels, 21(2007), 426-434.
[10] Torrisi, A., Bell, R. G., Draznieks, C. M., 2010. Functionalized MOFs for enhanced CO2 capture. Crystal Growth and Design, 10(2010), 2839-2841.
[11] Hicks, J. C., Drese, J. H., Fauth, D. J., Gray, M. L., Qi, G., Jones, C. W., 2008. Designing adsorbents for CO2 capture from flue gas-hyperbranched aminosilicas capable of capturing CO2 reversibly. Journal of American Chemical Society, 130(2008), 2902-2903.
[12] Chakma, A., 1997. CO2 capture processes-opportunities for improved energy efficiencies. Energy Conversion and Management, 38(1997), S51-S56.
[13] Veawab, A., Tontiwachwuthikul, P., Chakma, A. 1999. Corrosion behavior of carbon steel in the CO2 absorption process using aqueous amine solutions. Industrial and Engineering Chemistry Research, 38(1999), 3917-3924.
[14] Bello, A., Idem R.O., 2006. Comprehensive study of the kinetics of the oxidative degradation of CO2 loaded and concentrated aqueous monoethanolamine (MEA) with and without sodium metavanadate during CO2 absorption from flue gases. Industrial and Engineering Chemistry Research, 45(2006), 2569-2579.
[15] Surble, S., Millange, Serre, F.C., Duren, T., Latroche, M., Bourrelly, S., Llewellyn, P. L., Ferey, G. 2006. Synthesis of MIL-102, a chromium carboxylate metal−organic framework, with gas sorption analysis. Journal of American Chemical Society, 128(2006), 14889−14896.
[16] Ciesla, U., Schuth, F., 1999. Ordered mesoporous materials. Microporous and Mesoporous Materials, 27(1999), 131.
[17] Beck, J. S., Vartuli, C., Roth, W. J., Leonowicz, M. E., Kresge, C. T., Schmitt, K. D., Chu, C. T. W., Olson, D. H., Sheppard E. W., McCullen, S. B., Higgins, J. B., Schlenker, J. L., 1992. A new family of mesoporous molecular sieves prepared with liquid crystal templates. Journal of American Chemical Society, 114(1992), 10834-10843.
[18] Corma, A., Martinez, A., Martinezsoria, V. Monton, J.B., 1995. Hydrocracking of vacuum gasoil on the novel mesoporous MCM-41 aluminosilicate catalyst. Journal of Catalysis, 153(1995), 25-31.
[19] Vallet-Regi, M., Rámila, A., Real del R.P., 2001. A new property of MCM-41: drug delivery system. Chemistry of Materials, 13(2001), 308–311.
[20] Mundaca-Uribe, R., Bustos-Ramírez, F., Zaror-Zaror, C., Aranda-Bustos, M., Neira-Hinojosa, J., Peña-Farfal, C., 2014. Development of a bienzymatic amperometric biosensor to determine uric acid in human serum, based on mesoporous silica (MCM-41) for enzyme immobilization, Sensors and Actuators B: Chemical, 195(2014), 58–62.
[21] Belmabkhout, Y., Serna-Guerrero, R. and Sayari, A., 2009. Adsorption of CO2 from dry gases on MCM-41 silica at ambient temperature and high pressure. 1: pure CO2 adsorption. Chemical Engineering Science, 64(2009), 3721–3728.
[22] Wu, Y., Zhang, M., Zhao, H., Yang, S. Arkin, A., 2014. Functionalized mesoporous silica material and anionic dye adsorption: MCM-41 incorporated with amine groups for competitive adsorption of acid fuchsine and acid orange II. RSC Advances, 4(2014), 61256-61267.
[23] Kim, S., Marand, E., 2008. High permeability nano-composite membranes based on mesoporous MCM-41 nanoparticles in a polysulfone matrix. Microporous and Mesoporous Materials, 114(2008), 129–136.
[24] Kresge, C., Leonowicz, M., Roth, W., Vartuli, J. C., Beck, J. S., 1992. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature, 359(1992), 710-712.
[25] Araki, S. Doi, H. Sano, Y., Tanaka, S., Miyake, Y., 2009. Preparation and CO2 adsorption properties of aminopropyl-functionalized mesoporous silica microspheres. Journal of Colloid and Interface Science, 339(2009), 382.
[26] Vartuli, J. C., Kresge, C. T., Roth, W. J., Sheppard E. W., 1996. Designed synthesis of mesoporous molecular sieve systems using surfactant-directing agents. Advanced catalysts and nanostructured materials. Academic Press.
[27] Vartuli, J. C., Malek, A., Roth, W. J., Kresge, C. T., McCullen, S. B., 2001. The sorption properties of as-synthesized and calcined MCM-41 and MCM-48. Microporous Mesoporous Materials, 44(2001), 691.
[28] Vartuli, J. C., Shih, S. S., Kresge, C. T., Beck J. S., 1998. Potential applications for M41S type mesoporous molecular sieves. Studies in Surface Science and Catalysis, 117(1998), 13.
[29] Mokhonoana, M. P., Coville, N. J., 2010. Synthesis of [Si]-MCM-41 from TEOS and water glass: the water glass-enhanced condensation of TEOS under alkaline conditions. Journal of Sol-Gel Science and Technology, 54(2010), 83.
[30] Santos, C. T., Bourrelly, S., Llewellyn, P. L., Carneiroa, J. ´W. M., Ronconi, C. M., 2015. Adsorption of CO2 on amine-functionalised MCM-41: experimental and theoretical studies. Physical Chemistry Chemical Physics, 17(2015), 11095.
[31] Mello, M. R., Phanon, D., Silveira, G. Q., Llewellyn P. L., Ronconi, C., M., 2011. Amine-modified MCM-41 mesoporous silica for carbon dioxide capture. Microporous Mesoporous Materials, 143(2011), 174-179.
[32] Ishikawa, T., Matsuda, M., Yasukawa, A., Kandori, K., Inagaki, S., Fukushima, T., Kondo, S., 1996. Surface silanol groups of mesoporous silica FSM-16. Journal of the Chemical Society, Faraday Transactions, 92(1996), 1985-1989.
[33] Anbia, M., Lashgari, M., 2009. Synthesis of amino-modified ordered mesoporous silica as a new nano sorbent for the removal of chlorophenols from aqueous media, Chemical Engineering Journal, 150(2009), 555–560.
[34] Blitz, J., Murthy, P., Shreedhara, R. S., Leyden D. E. 1988. The role of amine structure on catalytic activity for silylation reactions with Cab-O-Sil Journal of Colloid and Interface Science, 126(1988), 387–439.

Details

Primary Language

Turkish

Subjects

-

Journal Section

-

Authors

Müge Sarı Yılmaz

Publication Date

March 31, 2017

Submission Date

October 13, 2016

Acceptance Date

-

Published in Issue

Year 2017 Volume: 21 Number: 3

DOI

https://doi.org/10.19113/sdufbed.69265

IZ

https://izlik.org/JA55UW58JE

Cite

RIS / Bibtex

APA

Sarı Yılmaz, M. (2017). Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21(3), 961-966. https://doi.org/10.19113/sdufbed.69265

AMA

1.Sarı Yılmaz M. Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu. J. Nat. Appl. Sci. 2017;21(3):961-966. doi:10.19113/sdufbed.69265

Chicago

Sarı Yılmaz, Müge. 2017. “Amin Grupları Ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21 (3): 961-66. https://doi.org/10.19113/sdufbed.69265.

EndNote

Sarı Yılmaz M (December 1, 2017) Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21 3 961–966.

IEEE

[1]M. Sarı Yılmaz, “Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu”, J. Nat. Appl. Sci., vol. 21, no. 3, pp. 961–966, Dec. 2017, doi: 10.19113/sdufbed.69265.

ISNAD

Sarı Yılmaz, Müge. “Amin Grupları Ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21/3 (December 1, 2017): 961-966. https://doi.org/10.19113/sdufbed.69265.

JAMA

1.Sarı Yılmaz M. Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu. J. Nat. Appl. Sci. 2017;21:961–966.

MLA

Sarı Yılmaz, Müge. “Amin Grupları Ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 21, no. 3, Dec. 2017, pp. 961-6, doi:10.19113/sdufbed.69265.

Vancouver

1.Müge Sarı Yılmaz. Amin Grupları ile Fonksiyonelleştirilmiş MCM-41 Mezogözenekli Silika Üzerine CO2 Adsorpsiyonu. J. Nat. Appl. Sci. 2017 Dec. 1;21(3):961-6. doi:10.19113/sdufbed.69265