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The Usage of Fe3O4 Nanoparticles Synthesized by Hydrothermal Method for Nitrate Removal from Water

Year 2020, , 323 - 332, 26.08.2020
https://doi.org/10.19113/sdufenbed.641298

Abstract

In this study, the efficiency of Fe3O4 nanoparticle synthesized by hydrothermal method on nitrate removal, the effect of environmental conditions, recovery and reusability properties of nanoparticle were investigated. Surface morphology, element content, crystal structure, specific surface area and functional groups of the magnetic nanoparticle were elucidated by scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) and Fourier transform infrared spectroscopy (FT-IR) analysis. Nitrate removal efficiency was achieved as 90.26% for optimum conditions (30 min contact time, pH 6.9 value, 1.2 g/L adsorbent dose and 100 mg/L initial nitrate concentration) as a result of batch adsorption studies. Desorption studies were performed with 0.1 M NaCl, NaOH, HNO3 and HCl and favorable results were obtained with NaCl. Nitrate adsorption with Fe3O4 was found to be more compatible with Langmuir isotherm model and maximum adsorption capacity was determined as 86.96 mg/g.

References

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Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı

Year 2020, , 323 - 332, 26.08.2020
https://doi.org/10.19113/sdufenbed.641298

Abstract

Bu çalışmada hidrotermal yöntemle sentezlenmiş Fe3O4 nanoparçacıklarının nitrat giderimindeki etkinliği, ortam şartlarının giderim verimine etkisi, kullanım sonrası geri kazanımı ve yeniden kullanılabilirliği incelenmiştir. Manyetik nanoparçacıkların yüzey morfolojisi, element içeriği, kristal yapısı, spesifik yüzey alanı ve fonksiyonel grupları, taramalı elektron mikroskobu (SEM), geçirimli elektron mikroskobu (TEM), X-ışını kırınımı (XRD), Brunauer-Emmett-Teller (BET) ve Fourier dönüşümlü kızılötesi spektroskopi (FT-IR) analizleriyle aydınlatılmıştır. Kesikli adsorpsiyon çalışmaları sonucunda, optimum ortam şartlarında (30 dk temas süresi, pH 6,9 değeri, 1,2 g/L adsorban dozu ve 100 mg/L başlangıç nitrat konsantrasyonu) %90,26 giderim verimi elde edilmiştir. Desorpsiyon çalışmaları 0,1 M’lık NaCl, NaOH, HNO3 ve HCl ile yapılmış ve NaCl ile tatminkar sonuçlar elde edilmiştir. Fe3O4 ile nitrat adsorpsiyonunun Langmuir izoterm modeliyle daha uyumlu olduğu belirlenmiş ve maksimum adsorpsiyon kapasitesi 86,96 mg/g olarak tespit edilmiştir. 

References

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  • [2] Mohsenipour, M., Shahid, S., Ebrahimi, K. 2014. Removal Techniques of Nitrate from Water. Asian Journal of Chemistry, 26(23), 7881-7886.
  • [3] Liu, A., Ming, J., Ankumah, R.O. 2005. Nitrate contamination in private wells in rural Alabama, United States. Science of the Total Environment, 346(1-3), 112-120.
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  • [5] Bhatnagar, A., Ji, M., Choi, Y., Jung, W., Lee, S., Kim, S., Lee, G., Suk, H., Kim, H., Min, B., Kim, S-H., Jeon, B., Kang, J. 2008. Removal of nitrate from water by adsorption onto zinc chloride treated activated carbon. Separation Science and Technology, 43(4), 886-907.
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  • [8] Fenton, O., Richards, K. G., Kirwan, L., Khalil, M. I., Healy, M. G. 2009. Factors affecting nitrate distribution in shallow groundwater under a beef farm in South Eastern Ireland. Journal of Environmental Management, 90(10), 3135-3146.
  • [9] Hekmatzadeh, A. A., Karimi-Jashani, A., Talebbeydokhti, N., Kløve, B. 2012. Modeling of nitrate removal for ion exchange resin in batch and fixed bed experiments. Desalination, 284, 22-31.
  • [10] Hwang, Y.-H., Kim, D.-G., Shin, H.-S. 2011. Mechanism study of nitrate reduction by nano zero valent iron. Journal of Hazardous Materials, 185(2-3), 1513-1521.
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  • [25] Cheng, I. F., Muftikian, R., Fernando, Q., Korte, N. 1997. Reduction of nitrate to ammonia by zero-valent iron. Chemosphere, 35(11), 2689-2695.
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  • [27] Kumar, M., Chakraborty, S. 2006. Chemical denitrification of water by zero-valent magnesium powder. Journal of Hazardous Materials, 135(1-3), 112-121.
  • [28] Oh, S. Y., Seo, Y. D., Kim, B., Kim, I. Y., Cha, D. K. 2016. Microbial reduction of nitrate in the presence of zero-valent iron and biochar. Bioresource Technology, 200, 891-896.
  • [29] Shi, J., Yi, S., He, H., Long, C., Li, A. 2013. Preparation of nanoscale zero-valent iron supported on chelating resin with nitrogen donor atoms for simultaneous reduction of Pb2+ and NO3. Chemical Engineering Journal, 230, 166-171.
  • [30] Mohammadi, A. A., Alinejad, A., Kamarehie, B., Javan, S., Ghaderpoury, A., Ahmadpour, M., Ghaderpoori, M. 2017. Metal-organic framework Uio-66 for adsorption of methylene blue dye from aqueous solutions. International Journal of Environmental Science and Technology, 14(9), 1959-1968.
  • [31] Bhatnagar, A., Kumar, E.,. Sillanpää, M. 2010. Nitrate removal from water by nano-alumina: Characterization and sorption studies. Chemical Engineering Journal, 163(3), 317-323.
  • [32] Cengeloglu, Y., Tor, A., Ersoz, M., Arslan, G. 2006. Removal of nitrate from aqueous solution by using red mud. Separation and Purification Technology, 51(3), 374-378.
  • [33] Islam, M., Mishra, P.C., Patel, R. 2010. Physicochemical characterization of hydroxyapatite and its application towards removal of nitrate from water. Journal of Environmental Management, 91(9), 1883-1891.
  • [34] Tuutijärvi, T., Lu, J., Sillanpää, M., Chen, G. 2009. As (V) adsorption on maghemite nanoparticles. Journal of Hazardous Materials, 166(2-3), 1415-1420.
  • [35] Poursaberi, T., Karimi, M., Hassanisadi, M., Sereshti, H. 2013. Magnetic removal of nitrate ions from aqueous solution using amino-silica coated magnetic nanoparticles modified by oxovanadium (IV) porphyrin. Journal of Porphyrins and Phthalocyanines, 17(05), 359-366.
  • [36] Hadei, M., Aalipour, M., Mengli Zadeh, N., Pourzamani, H. 2016. Ethylbenzene removal from aqueous solutions by nano magnetic particles. Archives of Hygiene Sciences, 5(1), 22-32.
  • [37] Feng, Y., Gong, J. L., Zeng, G. M., Niu, Q. Y., Zhang, H. Y., Niu, C. G., Yan, M. 2010. Adsorption of Cd (II) and Zn (II) from aqueous solutions using magnetic hydroxyapatite nanoparticles as adsorbents. Chemical Engineering Journal, 162(2), 487-494.
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  • [39] Mahdavi, M., Ahmad, M. B., Haron, M. J., Gharayebi, Y., Shameli, K., Nadi, B. 2013. Fabrication and characterization of SiO 2/(3-aminopropyl) triethoxysilane-coated magnetite nanoparticles for lead (II) removal from aqueous solution. Journal of Inorganic and Organometallic Polymers and Materials, 23(3), 599-607.
  • [40] El Ghandoor, H., Zidan, H. M., Khalil, M. M., Ismail, M. I. M. 2012. Synthesis and some physical properties of magnetite (Fe3O4) nanoparticles. Int. J. Electrochem. Sci, 7(6), 5734-5745.
  • [41] Kumari, M., Pittman Jr, C.U., Mohan, D. 2015. Heavy metals [chromium (VI) and lead (II)] removal from water using mesoporous magnetite (Fe3O4) nanospheres. Journal of Colloid and Interface Science, 442, 120-132.
  • [42] Yuwei, C., Jianlong, W. 2011. Preparation and characterization of magnetic chitosan nanoparticles and its application for Cu (II) removal. Chemical Engineering Journal, 168(1), 286-292.
  • [43] Malkoc, E., Nuhoglu, Y. 2006. Fixed bed studies for the sorption of chromium (VI) onto tea factory waste. Chemical Engineering Science, 61(13), 4363-4372.
  • [44] Banerjee, S.S., Chen, D.-H. 2007. Fast removal of copper ions by gum arabic modified magnetic nano-adsorbent. Journal of Hazardous Materials, 147(3), 792-799.
  • [45] Panneerselvam, P., Morad, N., Tan, K.A. 2011. Magnetic nanoparticle (Fe3O4) impregnated onto tea waste for the removal of nickel (II) from aqueous solution. Journal of Hazardous Materials, 186(1), 160-168.
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There are 63 citations in total.

Details

Primary Language Turkish
Subjects Engineering
Journal Section Articles
Authors

Mehmet Türkyılmaz This is me 0000-0001-5484-571X

Sezen Küçükçongar 0000-0001-6444-4397

İlkay Özaytekin This is me 0000-0002-0352-9458

Publication Date August 26, 2020
Published in Issue Year 2020

Cite

APA Türkyılmaz, M., Küçükçongar, S., & Özaytekin, İ. (2020). Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 24(2), 323-332. https://doi.org/10.19113/sdufenbed.641298
AMA Türkyılmaz M, Küçükçongar S, Özaytekin İ. Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı. Süleyman Demirel Üniv. Fen Bilim. Enst. Derg. August 2020;24(2):323-332. doi:10.19113/sdufenbed.641298
Chicago Türkyılmaz, Mehmet, Sezen Küçükçongar, and İlkay Özaytekin. “Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 24, no. 2 (August 2020): 323-32. https://doi.org/10.19113/sdufenbed.641298.
EndNote Türkyılmaz M, Küçükçongar S, Özaytekin İ (August 1, 2020) Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 24 2 323–332.
IEEE M. Türkyılmaz, S. Küçükçongar, and İ. Özaytekin, “Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı”, Süleyman Demirel Üniv. Fen Bilim. Enst. Derg., vol. 24, no. 2, pp. 323–332, 2020, doi: 10.19113/sdufenbed.641298.
ISNAD Türkyılmaz, Mehmet et al. “Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 24/2 (August 2020), 323-332. https://doi.org/10.19113/sdufenbed.641298.
JAMA Türkyılmaz M, Küçükçongar S, Özaytekin İ. Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı. Süleyman Demirel Üniv. Fen Bilim. Enst. Derg. 2020;24:323–332.
MLA Türkyılmaz, Mehmet et al. “Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 24, no. 2, 2020, pp. 323-32, doi:10.19113/sdufenbed.641298.
Vancouver Türkyılmaz M, Küçükçongar S, Özaytekin İ. Hidrotermal Yöntemle Sentezlenmiş Fe3O4 Nanoparçacıklarının Sulardan Nitrat Gideriminde Kullanımı. Süleyman Demirel Üniv. Fen Bilim. Enst. Derg. 2020;24(2):323-32.

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