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Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er<sup>3+</sup>:Y<sub>2</sub>Si<sub>2</sub>O<sub>7</sub> Nanopowders

Year 2017, Volume: 21 Issue: 1, 173 - 177, 15.04.2017

Murat Erdem , Hümeyra Örücü

https://doi.org/10.19113/sdufbed.05477
Cited By: 2

Abstract

Nanosized yttrium disilicate powders activated with trivalent erbium ions were produced by Sol-Gel known as wet chemical process. The structure and morphology of the synthesized powders were characterized by using X-ray diffraction spectroscopy (XRD), Transmission electron microscopy (TEM) and Photoluminescence spectroscopy. The XRD analysis revealed that the formation of triclinic  a-Y2Si2O7 and monoclinic  b-Y2Si2O7 polymorphs were obtained at 1050  and 1450 , respectively. The photoluminescence properties were also investigated in terms of sintering temperature and doping effect on different polymorphs.

Keywords

Yttrium disilicate Nanophosphors; Phase properties; Sol-Gel

References

  • [1] Pennenvan R.A., Rosenzweig, R.R. 1973. 13, 99–199. Structure and bonding. Volume 13, 1973, Rare earths Berlin : Springer, 13, 99-199.
  • [2] Becerro, A.I., Escudero, A., Florian, P., Massiot, D., Alba, M.D. 2004. Revisiting Y2Si2O7 and Y2SiO5 polymorphic structures by 89Y MAS-NMR spectroscopy. J. Solid State Chem 177, 2783–2789.
  • [3] Cao, M.S., Hou,.Z.L., Yuan J.L., Xiong, L.T., Shi, X.L. 2009. Low dielectric loss and non-Debye relaxation of gamma-Y2Si2O7 ceramic at elevated temperature in X-band. J.Appl. Phys. 105, 2–5.
  • [4] Ching, W.Y., Ouyang, L., Xu,Y.N. 2003 Electronic and optical properties of Y2SiO5 and Y2Si2O7 with comparisons to α-SiO2 and Y2O3. Phys. Rev. B 67, 245108.
  • [5] Wang, G.M., Equall, R.W., Cone, R.L., Leask, M.J.M., Godfrey, K.W., Wondre, F.R. 1996. Optical dephasing mechanisms in Tm3+:Y2Si2O7. Opt. Lett. 21, 818–820.
  • [6] Moya, J.S., Diaz, M., Serna, C.J., Castanho, S.M. 1998. Formation of nanocrystalline yttrium disilicate powder by an oxalate gel method J. Eur. Ceram. Soc. 18, 1–4.
  • [7] Zheng X.H., Du, Y.G., Xiao J.Y., Zhang, W.J., Zhang, L.C. 2009. Double layer oxidation resistant coating for carbon fiber reinforced silicon carbide matrix composites Appl. Surf. Sci. 255, 4250 –4254.
  • [8] Diaz,M., .Cano, I.G., Castanho,S.M., Moya,J.S., Rodríguez, M.A. 2001. Synthesis of nanocrystalline yttrium disilicate powder by a sol–gel method J. Non. Cryst.Solids. 289, 151–154.
  • [9] Seifert, H.J., Wagner, S., Fabrichnaya, O., Lukas,H.L.,Aldinger,F.L.,Ullmann.T.,Schmucker, M.; Schneider, H. 2005. Yttrium Silicate Coatings on Chemical Vapor Deposition‐SiC‐Precoated C/C–SiC: Thermodynamic Assessment and High‐Temperature Investigation. J. Am. Ceram. Soc., 88, 424–430.
  • [10] Stoner, B.R., Griggs, J.A., Neidigh, J., Piascik, J.R. 2014. Evidence of yttrium silicate inclusions in YSZ-porcelain veneers. J. Biomed. Mater. Res. Part B Appl. Biomater. 102, 441–446.
  • [11] Sun, Z., Zhou.Y, Wang, J.,Li,M. 2008. Thermal Properties and Thermal Shock Resistance of γ‐Y2Si2O7. J. Am. Ceram. Soc. 91, 2623–2629.
  • [12] Hu, H.; Zeng, Y.; Zuo, K.; Xia, Y.; Yao, D.; Günster, J.; Jürgen G.; Heinrich, S.L. 2015.Synthesis of porous Si3N4/SiC ceramics with rapid nitridation of silicon. J.Eur. Cer. Soc. 35, 3781–3787.
  • [13] Deng, Y., Song, W.; Dong, W., Dai, R., Wang, Z., Zhang, Z., Ding, Z. 2014. White light emission of Eu3+/Ag co-doped Y2Si2O7. J. Rare Earths. 32, 779–786.
  • [14] Sokolnicki, J. 2013. Rare earths (Ce, Eu, Tb) doped Y2Si2O7 phosphors for white LED.2013. J. Lumin. 134, 600–606.
  • [15] Wang, B., Wang, X.J., a De Dood, M.J., Guo, R.M., Wang, L., Vanhoutte, M., Michel, J., Kimerling, L.C., Zhou, Z. 2012. Photoluminescence quantum efficiency and energy transfer of ErRE silicate (RE = Y, Yb) thin films. J. Phys. D. Appl. Phys. 45, 165101-165106.
  • [16] Hreniak,D., Głuchowski, P., Stręk, W., Bettinelli, M., Kozłowska, A., Kozłowski, M. 2006. Preparation and upconversion propertiesofEr3+,Yb3+:Y2Si2O7 nanocrystallites embedded in PVA polymer nanocomposites. Mater. Sci. Poland. 24, 405-412.
  • [17] Diaz, M, Pecharroman, C., Del Monte, F., Sanz, J., Iglesias, J.E., Moya, J.S., Yamagata, C., Mello-Castanho, S.2005. Synthesis, Thermal Evolution, and Luminescence Properties of Yttrium Disilicate Host Matrix.Chem. Mater.17, 1774–1782.
  • [18] Hreniak,D., Strek, W. Opalińska, A., Nyk, M., Wołcyrz, M., Lojkowski, W., Misiewicz, J. 2004.Luminescence Properties of Tb-Doped Yttrium Disilicate Prepared by the Sol–Gel Method J. Sol-Gel Sci. Technol. 32, 195–200.
  • [19] Grzeszkiewicz, K., Marciniak, L., Stręk, W., Hreniak, D. 2016. Downconversion in Y2Si2O7: Pr3+, Yb3+ polymorphs for its possible application as luminescent concentrators in photovoltaic solar-cells. J. Lumin. 177, 172-177.
  • [20] Zhou, P., Yu, X., Yang, L., Yang, S., Gao, W. 2004. Synthesis of Y2Si2O7:Eu nanocrystal and its optical properties. J. Lumin. 124, 241–244.
  • [21] Li, Y., You, B., Zhao, W., Zhang, W., Yin, M. Chinese. 2008. Synthesis and Luminescent Properties of Nano-scale Y2Si2O7:Re3+ (Re=Eu, Tb) Phosphors via Sol-Gel Method. J. Chem. Phys. 21, 376–380.
  • [22] Li, Y., Wei, X., Yin, M., Tao, M. 2011. Energy transfer processes in Ce3+ and Tb3+ co-doped Ln2Si2O7 (Ln = Y, Gd). Opt. Mater. 33, 1239–1242.
  • [23] Thanh, L.X., Phuong, P.T.M. 2012. A Study of Synthesis of Cerium-Doped Yttrium Silicate and Yttrium Disilicate Phosphors by the Ammonia-Added Sol-Gel Method. E-Journal Surf. Sci. Nanotech. 10, 248–251.
  • [24] Sokolnicki,J.2011.Upconversion luminescence from Er3+ in nanocrystalline Y2Si2O7:Er3+ and Y2Si2O7:Yb3+,Er3+ phosphors.Mater.Chem.Phys. 131, 306–312.
  • [25] Marciniak, L., Hreniak, D., Strek, W., Piccinelli, F., Speghini, A.,Bettinelli, M., Miritello, M., Lo Savio, R., Cardile, P., Priolo, F. 2016. Spectroscopic and structural properties of polycrystalline Y2Si2O7 doped with Er3+. J. Lumin. 170, 614–618.
  • [26] Erdem, M., Eryürek, G., Mergen, A., Di Bartolo, B. 2016. Pressure effects on the cooperative emission of Yb3+: Y2Si2O7nano-powders. Ceram.Int. 42, 1501–1506.
  • [27] Erdem, M., Özen, G., Tav, C.; Di Bartolo, B. 2013. Structural and Spectroscopic Properties of δ-Y2Si2O7Nanopowders Activated with Nd3+ Ions. Ceram. Int. 39, 6029–6033.
  • [28] Erdem, M., Sitt, B. 2015. Up conversion based white light emission from sol–gel derived α-Y2Si2O7 nanoparticles activated with Yb3+, Er3+ ions. Opt. Mater. 46, 260–264.
  • [29] Najar, A. Omi, H., Tawara,T. 2014. Scandium effect on the luminescence of Er-Sc silicates prepared from multi-nanolayer films. Nanoscale Res. Lett. 9, 356.
  • [30] Becerro, A., Naranjo, M., Pedrigón, A., Trillo J. 2003. Hydrothermal chemistry of silicates: Low-temperature synthesis of y-yttrium disilicate. J. Am. Ceram. Soc. 86, 1592–1594.
  • [31] Becerro,A.I., Naranjo,M., Alba,M.D., Trillo, J.M. 2003. Structure-directing effect of phyllosilicates on the synthesis of y-Y2Si2O7. Phase transitions in Y2Si2O7. J. Mater. Chem. 13, 1835-1842.
  • [32] Ito, J., Johnson, H. 1968. Synthesis and study of yttrialite. The American Mineralogist, 1968, 53, 1940-1952.
  • [33] Erdem, M., Eryürek, G., Di Bartolo, B. 2015. White light emission from sol–gel derived γ-Y2Si2O7nanoparticles. J. Alloys Compd. 639, 483–487.
  • [34] Marciniak, L.,Hreniak, D., Dobrowolska ,A.,Zych, E. 2010. Size-dependent luminescence in Y2Si2O7nanoparticles doped with Ce3+ ions.Appl. Phys. A Mater. Sci. Process. 99, 871–877.

Year 2017, Volume: 21 Issue: 1, 173 - 177, 15.04.2017

Murat Erdem , Hümeyra Örücü

https://doi.org/10.19113/sdufbed.05477
Cited By: 2

Abstract

References

  • [1] Pennenvan R.A., Rosenzweig, R.R. 1973. 13, 99–199. Structure and bonding. Volume 13, 1973, Rare earths Berlin : Springer, 13, 99-199.
  • [2] Becerro, A.I., Escudero, A., Florian, P., Massiot, D., Alba, M.D. 2004. Revisiting Y2Si2O7 and Y2SiO5 polymorphic structures by 89Y MAS-NMR spectroscopy. J. Solid State Chem 177, 2783–2789.
  • [3] Cao, M.S., Hou,.Z.L., Yuan J.L., Xiong, L.T., Shi, X.L. 2009. Low dielectric loss and non-Debye relaxation of gamma-Y2Si2O7 ceramic at elevated temperature in X-band. J.Appl. Phys. 105, 2–5.
  • [4] Ching, W.Y., Ouyang, L., Xu,Y.N. 2003 Electronic and optical properties of Y2SiO5 and Y2Si2O7 with comparisons to α-SiO2 and Y2O3. Phys. Rev. B 67, 245108.
  • [5] Wang, G.M., Equall, R.W., Cone, R.L., Leask, M.J.M., Godfrey, K.W., Wondre, F.R. 1996. Optical dephasing mechanisms in Tm3+:Y2Si2O7. Opt. Lett. 21, 818–820.
  • [6] Moya, J.S., Diaz, M., Serna, C.J., Castanho, S.M. 1998. Formation of nanocrystalline yttrium disilicate powder by an oxalate gel method J. Eur. Ceram. Soc. 18, 1–4.
  • [7] Zheng X.H., Du, Y.G., Xiao J.Y., Zhang, W.J., Zhang, L.C. 2009. Double layer oxidation resistant coating for carbon fiber reinforced silicon carbide matrix composites Appl. Surf. Sci. 255, 4250 –4254.
  • [8] Diaz,M., .Cano, I.G., Castanho,S.M., Moya,J.S., Rodríguez, M.A. 2001. Synthesis of nanocrystalline yttrium disilicate powder by a sol–gel method J. Non. Cryst.Solids. 289, 151–154.
  • [9] Seifert, H.J., Wagner, S., Fabrichnaya, O., Lukas,H.L.,Aldinger,F.L.,Ullmann.T.,Schmucker, M.; Schneider, H. 2005. Yttrium Silicate Coatings on Chemical Vapor Deposition‐SiC‐Precoated C/C–SiC: Thermodynamic Assessment and High‐Temperature Investigation. J. Am. Ceram. Soc., 88, 424–430.
  • [10] Stoner, B.R., Griggs, J.A., Neidigh, J., Piascik, J.R. 2014. Evidence of yttrium silicate inclusions in YSZ-porcelain veneers. J. Biomed. Mater. Res. Part B Appl. Biomater. 102, 441–446.
  • [11] Sun, Z., Zhou.Y, Wang, J.,Li,M. 2008. Thermal Properties and Thermal Shock Resistance of γ‐Y2Si2O7. J. Am. Ceram. Soc. 91, 2623–2629.
  • [12] Hu, H.; Zeng, Y.; Zuo, K.; Xia, Y.; Yao, D.; Günster, J.; Jürgen G.; Heinrich, S.L. 2015.Synthesis of porous Si3N4/SiC ceramics with rapid nitridation of silicon. J.Eur. Cer. Soc. 35, 3781–3787.
  • [13] Deng, Y., Song, W.; Dong, W., Dai, R., Wang, Z., Zhang, Z., Ding, Z. 2014. White light emission of Eu3+/Ag co-doped Y2Si2O7. J. Rare Earths. 32, 779–786.
  • [14] Sokolnicki, J. 2013. Rare earths (Ce, Eu, Tb) doped Y2Si2O7 phosphors for white LED.2013. J. Lumin. 134, 600–606.
  • [15] Wang, B., Wang, X.J., a De Dood, M.J., Guo, R.M., Wang, L., Vanhoutte, M., Michel, J., Kimerling, L.C., Zhou, Z. 2012. Photoluminescence quantum efficiency and energy transfer of ErRE silicate (RE = Y, Yb) thin films. J. Phys. D. Appl. Phys. 45, 165101-165106.
  • [16] Hreniak,D., Głuchowski, P., Stręk, W., Bettinelli, M., Kozłowska, A., Kozłowski, M. 2006. Preparation and upconversion propertiesofEr3+,Yb3+:Y2Si2O7 nanocrystallites embedded in PVA polymer nanocomposites. Mater. Sci. Poland. 24, 405-412.
  • [17] Diaz, M, Pecharroman, C., Del Monte, F., Sanz, J., Iglesias, J.E., Moya, J.S., Yamagata, C., Mello-Castanho, S.2005. Synthesis, Thermal Evolution, and Luminescence Properties of Yttrium Disilicate Host Matrix.Chem. Mater.17, 1774–1782.
  • [18] Hreniak,D., Strek, W. Opalińska, A., Nyk, M., Wołcyrz, M., Lojkowski, W., Misiewicz, J. 2004.Luminescence Properties of Tb-Doped Yttrium Disilicate Prepared by the Sol–Gel Method J. Sol-Gel Sci. Technol. 32, 195–200.
  • [19] Grzeszkiewicz, K., Marciniak, L., Stręk, W., Hreniak, D. 2016. Downconversion in Y2Si2O7: Pr3+, Yb3+ polymorphs for its possible application as luminescent concentrators in photovoltaic solar-cells. J. Lumin. 177, 172-177.
  • [20] Zhou, P., Yu, X., Yang, L., Yang, S., Gao, W. 2004. Synthesis of Y2Si2O7:Eu nanocrystal and its optical properties. J. Lumin. 124, 241–244.
  • [21] Li, Y., You, B., Zhao, W., Zhang, W., Yin, M. Chinese. 2008. Synthesis and Luminescent Properties of Nano-scale Y2Si2O7:Re3+ (Re=Eu, Tb) Phosphors via Sol-Gel Method. J. Chem. Phys. 21, 376–380.
  • [22] Li, Y., Wei, X., Yin, M., Tao, M. 2011. Energy transfer processes in Ce3+ and Tb3+ co-doped Ln2Si2O7 (Ln = Y, Gd). Opt. Mater. 33, 1239–1242.
  • [23] Thanh, L.X., Phuong, P.T.M. 2012. A Study of Synthesis of Cerium-Doped Yttrium Silicate and Yttrium Disilicate Phosphors by the Ammonia-Added Sol-Gel Method. E-Journal Surf. Sci. Nanotech. 10, 248–251.
  • [24] Sokolnicki,J.2011.Upconversion luminescence from Er3+ in nanocrystalline Y2Si2O7:Er3+ and Y2Si2O7:Yb3+,Er3+ phosphors.Mater.Chem.Phys. 131, 306–312.
  • [25] Marciniak, L., Hreniak, D., Strek, W., Piccinelli, F., Speghini, A.,Bettinelli, M., Miritello, M., Lo Savio, R., Cardile, P., Priolo, F. 2016. Spectroscopic and structural properties of polycrystalline Y2Si2O7 doped with Er3+. J. Lumin. 170, 614–618.
  • [26] Erdem, M., Eryürek, G., Mergen, A., Di Bartolo, B. 2016. Pressure effects on the cooperative emission of Yb3+: Y2Si2O7nano-powders. Ceram.Int. 42, 1501–1506.
  • [27] Erdem, M., Özen, G., Tav, C.; Di Bartolo, B. 2013. Structural and Spectroscopic Properties of δ-Y2Si2O7Nanopowders Activated with Nd3+ Ions. Ceram. Int. 39, 6029–6033.
  • [28] Erdem, M., Sitt, B. 2015. Up conversion based white light emission from sol–gel derived α-Y2Si2O7 nanoparticles activated with Yb3+, Er3+ ions. Opt. Mater. 46, 260–264.
  • [29] Najar, A. Omi, H., Tawara,T. 2014. Scandium effect on the luminescence of Er-Sc silicates prepared from multi-nanolayer films. Nanoscale Res. Lett. 9, 356.
  • [30] Becerro, A., Naranjo, M., Pedrigón, A., Trillo J. 2003. Hydrothermal chemistry of silicates: Low-temperature synthesis of y-yttrium disilicate. J. Am. Ceram. Soc. 86, 1592–1594.
  • [31] Becerro,A.I., Naranjo,M., Alba,M.D., Trillo, J.M. 2003. Structure-directing effect of phyllosilicates on the synthesis of y-Y2Si2O7. Phase transitions in Y2Si2O7. J. Mater. Chem. 13, 1835-1842.
  • [32] Ito, J., Johnson, H. 1968. Synthesis and study of yttrialite. The American Mineralogist, 1968, 53, 1940-1952.
  • [33] Erdem, M., Eryürek, G., Di Bartolo, B. 2015. White light emission from sol–gel derived γ-Y2Si2O7nanoparticles. J. Alloys Compd. 639, 483–487.
  • [34] Marciniak, L.,Hreniak, D., Dobrowolska ,A.,Zych, E. 2010. Size-dependent luminescence in Y2Si2O7nanoparticles doped with Ce3+ ions.Appl. Phys. A Mater. Sci. Process. 99, 871–877.
There are 34 citations in total.

Details

Journal Section Articles
Authors

Murat Erdem

Hümeyra Örücü

Publication Date April 15, 2017
Published in Issue Year 2017 Volume: 21 Issue: 1

Cite

APA Erdem, M., & Örücü, H. (2017). Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21(1), 173-177. https://doi.org/10.19113/sdufbed.05477
AMA Erdem M, Örücü H. Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders. J. Nat. Appl. Sci. April 2017;21(1):173-177. doi:10.19113/sdufbed.05477
Chicago Erdem, Murat, and Hümeyra Örücü. “Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21, no. 1 (April 2017): 173-77. https://doi.org/10.19113/sdufbed.05477.
EndNote Erdem M, Örücü H (April 1, 2017) Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21 1 173–177.
IEEE M. Erdem and H. Örücü, “Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders”, J. Nat. Appl. Sci., vol. 21, no. 1, pp. 173–177, 2017, doi: 10.19113/sdufbed.05477.
ISNAD Erdem, Murat - Örücü, Hümeyra. “Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21/1 (April 2017), 173-177. https://doi.org/10.19113/sdufbed.05477.
JAMA Erdem M, Örücü H. Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders. J. Nat. Appl. Sci. 2017;21:173–177.
MLA Erdem, Murat and Hümeyra Örücü. “Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 21, no. 1, 2017, pp. 173-7, doi:10.19113/sdufbed.05477.
Vancouver Erdem M, Örücü H. Concentration and Cyrstalline Phase Effects on the Spectroscopic Properties of Sol-Gel Synthesized Er3+:Y2Si2O7 Nanopowders. J. Nat. Appl. Sci. 2017;21(1):173-7.

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https://doi.org/10.1063/1.5037184
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