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Investigation of the Production of β-Al<sub>2</sub>O<sub>3</sub> Solid Electrolyte from Seydişehir α-Al<sub>2</sub>O<sub>3</sub>

Year 2017, Volume: 21 Issue: 3, 816 - 819, 24.10.2017
https://doi.org/10.19113/sdufbed.31721

Abstract

In this study, we report the production of β˝-Al2O3 solid electrolyte by using Seydişehir α-Al2O3. Alumina has to be low grain-sized to ensure α-β phase transformation. Therefore, grain refining process was applied to high grain sized Seydişehir alumina by jetmill grinding. Seydişehir alumina was calcined at 1200 0C for 2 hours. After calcination, calcined Al2O3 and Na2CO3 were mixed during 2 hours in the mill. The samples were pressed and sintered to obtain β˝-Al2O3. β˝-Al2O3 was obtained after sintering at 1550°C for 1 hour. Due to the formation of β˝-Al2O3, it is observed that dielectric properties increased.

References

  • [1] Erten, R., Emrullahoğlu, C.B., Yazıcı, Z.O., Emrullahoğlu, Ö.F.2004. An investigation on injection molding of Seydişehir alumina. Key Engineering Materials, 264-268(2004), 2523-2526.
  • [2] Tambaş, T., Özgen, S. Seydişehir alüminasının slip döküm parametrelerinin belirlenmesi.2007. İTÜ Dergisi/Mühendislik, 6(2007), 83-94.
  • [3] Subasri, R., Nafe, H.2003. An alternative approach to characterize the equilibrium in a biphasic α-Al2O3/Na-β-Alumina mixture as a function of sodium activity. Electrochimica Acta, 48(2003),3535-3540.
  • [4] Song, H.І., Kim, E.S., Yoon, K.H.1988. Phase transformation and characteristics of beta alumina. Physica B,150 (1988), 148-159.
  • [5] Roth, W.L., Devries, R.C. 1977. Comparison of the thermal stability of β and β˝-alumina high pressures. Journal of Solid State Chemistry, 20 (1977), 111-118.
  • [6] Chengfei, Z, Jinhua, X., Guanghui, J. 2015. Effect of Na2O content on properties of beta alumina solid electrolytes. Materials Science in Semiconductor Processing, 31 (2015), 487- 492.
  • [7] Dunn, S., Kumar, R.V., Fray, D.J.2000. Thermodynamic studies of the ionic conductor Ba β - Al2O3. Solid State Ionics, 128(2000), 141-144.
  • [8] Sartori S, Martocci A, Muffato A, Guglielmi M.2004. Sol-Gel synthesis of Na Beta- Al2O3 powders. Journal of the European Ceramic Society, 24(2004), 911-914.
  • [9] May, G.J.1978. The development of Beta-alumina for use in electro-chemical cells: A Survey. Journal of Power Sources,3(1978), 1-22.
  • [10] Dae-Han, L, Sung-Tae, L., Jin-Sik, K., Sung-Ki, L.2017.Analysis of properties of partially stabilized zirconia-doped Na+-beta-alumina prepared by calcining-cum-sintering process. Materials Research Bulletin, (2017)
  • [11] Jayaraman, V., Periaswami, G., Kutty, T.R.N. 2008. Gel- to- crysallite conversion technique for the syntheses of M-β/β˝-Alumina (M:Li,Na,K,Rb,Ca or Eu).Materials Research Bullettin, 43(2008), 2527-2537.
  • [12] Jones, I.W., Miles, L.J. Production of beta alumina ceramic. United States Patent 1975.
  • [13] Lu, X., Xia, G., Lemmon, J.P., Yang, Z.2010. Advanced materials for sodium-beta alumina batteries: Status, Challenges and Perspective. Journal of Power Sources, 195(2010), 2431-2442.
  • [14] Subasri, R., Mathews, T., Sreedharan, O.M., Raghunatan, V.S.2003. Microwave processing of sodium beta alumina. Solid State Ionics, 158 (2003), 199-204.
  • [15] Chengfei, Z., Jinhua, X., Guanghui, J. 2015. Effect of Na2O content on properties of beta alumina solid electrolytes, Materials Science in Semiconductor Processing, 31 (2015), 487–492.
  • [16] Shqau, K. 2003. Characterization of the electronic conduction parameter of cation conducting solid electrolytes. Bericth Nr.141 Max-Planck-Institut für Metallforschung. Stuttgart University, Stuttgart, Germany, 2003.
Year 2017, Volume: 21 Issue: 3, 816 - 819, 24.10.2017
https://doi.org/10.19113/sdufbed.31721

Abstract

References

  • [1] Erten, R., Emrullahoğlu, C.B., Yazıcı, Z.O., Emrullahoğlu, Ö.F.2004. An investigation on injection molding of Seydişehir alumina. Key Engineering Materials, 264-268(2004), 2523-2526.
  • [2] Tambaş, T., Özgen, S. Seydişehir alüminasının slip döküm parametrelerinin belirlenmesi.2007. İTÜ Dergisi/Mühendislik, 6(2007), 83-94.
  • [3] Subasri, R., Nafe, H.2003. An alternative approach to characterize the equilibrium in a biphasic α-Al2O3/Na-β-Alumina mixture as a function of sodium activity. Electrochimica Acta, 48(2003),3535-3540.
  • [4] Song, H.І., Kim, E.S., Yoon, K.H.1988. Phase transformation and characteristics of beta alumina. Physica B,150 (1988), 148-159.
  • [5] Roth, W.L., Devries, R.C. 1977. Comparison of the thermal stability of β and β˝-alumina high pressures. Journal of Solid State Chemistry, 20 (1977), 111-118.
  • [6] Chengfei, Z, Jinhua, X., Guanghui, J. 2015. Effect of Na2O content on properties of beta alumina solid electrolytes. Materials Science in Semiconductor Processing, 31 (2015), 487- 492.
  • [7] Dunn, S., Kumar, R.V., Fray, D.J.2000. Thermodynamic studies of the ionic conductor Ba β - Al2O3. Solid State Ionics, 128(2000), 141-144.
  • [8] Sartori S, Martocci A, Muffato A, Guglielmi M.2004. Sol-Gel synthesis of Na Beta- Al2O3 powders. Journal of the European Ceramic Society, 24(2004), 911-914.
  • [9] May, G.J.1978. The development of Beta-alumina for use in electro-chemical cells: A Survey. Journal of Power Sources,3(1978), 1-22.
  • [10] Dae-Han, L, Sung-Tae, L., Jin-Sik, K., Sung-Ki, L.2017.Analysis of properties of partially stabilized zirconia-doped Na+-beta-alumina prepared by calcining-cum-sintering process. Materials Research Bulletin, (2017)
  • [11] Jayaraman, V., Periaswami, G., Kutty, T.R.N. 2008. Gel- to- crysallite conversion technique for the syntheses of M-β/β˝-Alumina (M:Li,Na,K,Rb,Ca or Eu).Materials Research Bullettin, 43(2008), 2527-2537.
  • [12] Jones, I.W., Miles, L.J. Production of beta alumina ceramic. United States Patent 1975.
  • [13] Lu, X., Xia, G., Lemmon, J.P., Yang, Z.2010. Advanced materials for sodium-beta alumina batteries: Status, Challenges and Perspective. Journal of Power Sources, 195(2010), 2431-2442.
  • [14] Subasri, R., Mathews, T., Sreedharan, O.M., Raghunatan, V.S.2003. Microwave processing of sodium beta alumina. Solid State Ionics, 158 (2003), 199-204.
  • [15] Chengfei, Z., Jinhua, X., Guanghui, J. 2015. Effect of Na2O content on properties of beta alumina solid electrolytes, Materials Science in Semiconductor Processing, 31 (2015), 487–492.
  • [16] Shqau, K. 2003. Characterization of the electronic conduction parameter of cation conducting solid electrolytes. Bericth Nr.141 Max-Planck-Institut für Metallforschung. Stuttgart University, Stuttgart, Germany, 2003.
There are 16 citations in total.

Details

Journal Section Articles
Authors

Zeynep Taşlıçukur Öztürk

Selin Engürlü This is me

Nilgun Kuşkonmaz This is me

Publication Date October 24, 2017
Published in Issue Year 2017 Volume: 21 Issue: 3

Cite

APA Taşlıçukur Öztürk, Z., Engürlü, S., & Kuşkonmaz, N. (2017). Investigation of the Production of β-Al2O3 Solid Electrolyte from Seydişehir α-Al2O3. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21(3), 816-819. https://doi.org/10.19113/sdufbed.31721
AMA Taşlıçukur Öztürk Z, Engürlü S, Kuşkonmaz N. Investigation of the Production of β-Al2O3 Solid Electrolyte from Seydişehir α-Al2O3. J. Nat. Appl. Sci. December 2017;21(3):816-819. doi:10.19113/sdufbed.31721
Chicago Taşlıçukur Öztürk, Zeynep, Selin Engürlü, and Nilgun Kuşkonmaz. “/Sub>”;. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21, no. 3 (December 2017): 816-19. https://doi.org/10.19113/sdufbed.31721.
EndNote Taşlıçukur Öztürk Z, Engürlü S, Kuşkonmaz N (December 1, 2017) Investigation of the Production of β-Al2O3 Solid Electrolyte from Seydişehir α-Al2O3. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21 3 816–819.
IEEE Z. Taşlıçukur Öztürk, S. Engürlü, and N. Kuşkonmaz, “/sub>”;, J. Nat. Appl. Sci., vol. 21, no. 3, pp. 816–819, 2017, doi: 10.19113/sdufbed.31721.
ISNAD Taşlıçukur Öztürk, Zeynep et al. “/Sub>”;. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21/3 (December 2017), 816-819. https://doi.org/10.19113/sdufbed.31721.
JAMA Taşlıçukur Öztürk Z, Engürlü S, Kuşkonmaz N. Investigation of the Production of β-Al2O3 Solid Electrolyte from Seydişehir α-Al2O3. J. Nat. Appl. Sci. 2017;21:816–819.
MLA Taşlıçukur Öztürk, Zeynep et al. “/Sub>”;. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 21, no. 3, 2017, pp. 816-9, doi:10.19113/sdufbed.31721.
Vancouver Taşlıçukur Öztürk Z, Engürlü S, Kuşkonmaz N. Investigation of the Production of β-Al2O3 Solid Electrolyte from Seydişehir α-Al2O3. J. Nat. Appl. Sci. 2017;21(3):816-9.

Cited By


TiO2 ile Sol Jel Kaplanmış Seydişehir Alüminanın Sinterlenme Davranışının İncelenmesi
International Journal of Advances in Engineering and Pure Sciences
Zeynep TAŞLIÇUKUR ÖZTÜRK
https://doi.org/10.7240/jeps.631637

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