Bor Katkılı Elmas Elektrot ile Naftalin’in Voltametrik Davranışı: Kare Dalga Anodik Sıyırma Voltametrisi ile Miktar Tayini

Year 2017, Volume: 21 Issue: 3, 948 - 955, 28.04.2017

Abdulkadir Levent

https://doi.org/10.19113/sdufbed.20660

Cited By: 1

Abstract

Bu çalışmada, Naftalin bor katkılı elmas elektrot yüzeyindeki elektrokimyasal özellikleri, değişik çözelti ortamları ve geniş bir pH aralığında incelenmiştir. İlk olarak çalışma elektrotun performansını etkileyen değişkenler (destek elektrolitinin seçimi, elektrot temizleme yöntemi, iyon şiddeti ve pH, biriktirme/ölçüm çözeltisinin bileşimi, biriktirme gerilimi/süresi, voltametrik dalga formu değişkenleri); voltametri ve/ya da sıyırma voltametrisi teknikleri kullanılarak ayrıntılı olarak araştırılmıştır. Daha sonra önerilen yöntemlerin elde edilen optimum koşullarda Naftalin için doğrusallık (0.9-4.5 µM), saptama sınırı (LOD; 0.225 µM) ve kesinlik (% BSS 2.26) açısından validasyonu gerçekleştirilmiştir. Geliştirilen KD-ASV yöntemi, çeşme suyunda naftalinin analizi için standart katma yöntemi kullanılarak başarılı bir şekilde uygulanmıştır.

Keywords

PAH, Naftalin; Voltametri; Bor katkılı elmas elektrot

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