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İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot

Year 2017, Volume: 21 Issue: 2, 437 - 443, 15.08.2017

Tuğçe Göver , H. Elif Kormalı Ertürün Ayça Demirel Özel Serkan Erdemir , Esin Canel

Abstract

Bu çalışmada, iyonofor olarak 5,11,17,23-tetra(tert-bütil)-25,26,27,28-tetra(4-propilimidazol asetamit)-kaliks[4]aren bileşiğinin kullanıldığı iyodür-seçici yeni bir polivinil klorür (PVC) membran elektrot hazırlandı. İyodür –seçici membranın hazırlanmasında kullanılan PVC, o-nitrofeniloktileter (o-NPOE; plastikleştirici) ve iyonoforun oranı değiştirilerek, optimum membran bileşimi %2 iyonofor, %29,7 PVC, %68,3 o-NPOE olarak bulundu. pH 4,0'de elektrodun doğrusal çalışma aralığının ve eğiminin sırasıyla 1,0x10-5 – 1,0x10-2 M ve 52,1± 2,6 mV/pI olduğu belirlendi. Önerilen elektrodun oldukça kısa bir cevap süresine (5-10 s) ve 5 ay’dan daha uzun bir ömre sahip olduğu gözlendi. Elektrot diğer anyonlar varlığında I->Salisilat > ClO4- > NO3- > SCN- ≈ Benzoat> NO2- > Br- > Cl- > F- > Sitrat > HCOO- sırasında bir seçicilik gösterdi. Ayrıca, önerilen elektrot, gümüş nitrat ile iyodürün çöktürme titrasyonunda indikatör elektrot olarak başarılı bir şekilde kullanıldı.

Keywords

Kaliks[4]aren İyodür-seçici elektrot; PVC membran; Potansiyometri; Çöktürme titrasyonu

References

  • [1] Greenwood, N. N., Earnsltaw, A. 1984. Chemistry of the Elements. Pergamon, Oxford, 933s.
  • [2] Benvidi, A., Ghanbarzadeh, M. T., Mazloum-Ardakani, M., Vafazadeh, R. 2011. Iodide-Selective Polymeric Membrane Electrode Based on Copper (II) Bis (N-2-bromophenylsalicyldenaminato) Complex. Chinese Chemical Letters, 22: 9(2011), 1087–1090.
  • [3] Singh, A. K., Mehtab, S. 2008. Polymeric Membrane Sensors Based on Cd(II) Schiff Base Complexes for Selective Iodide Determination in Environmental and Medicinal Samples. Talanta, 74(2008), 806–814.
  • [4] Amini, M. K., Ghaedi, M., Rafi, A., Habibi, M. H., Zohory, M. M. 2003. Iodide Selective Electrodes Based on Bis(2-mercaptobenzomercaptobenzothiazolato) Mercury(II) and Bis(4-chlorothiophenolato) Mercury(II) Carriers. Sensors, 3(2003), 509-523.
  • [5] Bermejo-Barrera P., Aboal-Somoza M., Bermejo-Barrera A., Cervera M.L., de la Guardia M. 2001. Microwave-assisted distillation of iodine for the indirect atomic absorption spectrometric determination of iodide in milk samples. J Anal Atom Spectrom., 16(2001), 382-389.
  • [6] Mesko MF, Mello PA, Bizzi CA, Dressler VL, Knapp G, Flores EM. 2010. Iodine determination in food by inductively coupled plasma mass spectrometry after digestion by microwave-induced combustion. Anal Bioanal Chem., 398(2010), 1125-1131.
  • [7] Hou X, Dahlgaard H, Rietz B, Jacobsen U, Nielsen SP, Aarkrog A. 1999. Determination of Chemical Species of Iodine in Seawater by Radiochemical Neutron Activation Analysis Combined with IonExchange Preseparation. Anal Chem., 71(1999), 2745-2750.
  • [8] Khazan, M., Azizi, F., Hedayati, M. 2013. A Review on Iodine Determination Methods in Salt and Biological Samples. Scimetr, 1(2013), 1, e14092.
  • [9] Jeong, D. C., Lee, H. K., Jeon, S. 2006. Polymeric Iodide-ion Selective Electrodes Based on Urea Derivative as an Ionophore. Bulletin of the Korean Chemical Society, 27(2006),12, 1985-1988.
  • [10] Lizondo-Sabater, J., Mart´ınez-Máñez, R., Sancenón, F., Segu´ı, M.-J., Soto, J. 2002. Cobalt(II) and Nickel(II) Complexes of a Cyclam Derivative as Carriers in Iodide-selective Electrodes. Analytica Chimica Acta, 459(2002), 229–234.
  • [11] Poursaberi, T., Hosseinia, M., Taghizadeha, M., Pirelahia, H., Shamsipurb ,M., Ganjalia, M. R. 2002. A Selective Membrane Electrode for Iodide Ion Based on a Thiopyrilium Ion Derivative as a New Ionophore. Microchemical Journal, 72(2002), 77-83.
  • [12] Zare, H. R., Memarzadeh, F., Gorji, A., Ardakani, M. M. 2005. Iodide- Selective Membrane Electrode Based on Salophen Complex of Cobalt (III). Journal of the Brazilian Chemical Society, 16(2005), 571-577.
  • [13] Erden, S. 2002. Rodanür ve Perklorat İyon-Seçici Elektrot Geliştirilmesi. Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi, 2s, Ankara.
  • [14] Atwood, J. L., Steed, J. W. 1997. Supramolecular Chemistry of Anions. Wiley-VCH, New York, 148s.
  • [15] Shamsipur, M., Soleymanpour, A., Akhond, M., Sharghi, H., Naseri, M. A. 2001. Iodide-Selective Carbon Paste Electrodes Based on Recently Synthesized Schiff Base Complexes of Fe(III). Analytica Chimica Acta, 450(2001), 37-44.
  • [16] Mortazavi, K., Ghaedi, M., Montazerozohori, M., Andikaey, Z. 2011. Iodide–Selective Electrodes Based on Bis(Trans- Cinnamaldehyde)1,3-Propanediimine Mercury (II) Chloride [BCPHgCl2] and Bis(Trans-Cinnamaldehyde)-1,3- Propandiimine Cadmium(II) Chloride [BCPCdCl2] Carriers: Influence of Multiwalled Carbon Nanotubes on the Response Performance. International Journal of Electrochemical Science, 6(2011), 4250-4263.
  • [17] Akın, İ., Erdemir, S., Yılmaz, M., Ersöz, M. 2012. Calix[4]arene Derivative Bearing Imidazole Groups as Carrier for the Transport of Palladium by Using Bulk Liquid Membrane. Journal of Hazardous Materials, 223– 224(2012), 24– 30.
  • [18] Anonim, 1994. IUPAC Recommendations. Analytical Chemistry Division Commission on Electroanalytical Chemistry. Recommendations for Nomenclature of Ion-Selective Electrodes. Pure and Applied Chemistry, 2527-2536.
  • [19] Zolotov, Y. A. 1997. Macrocyclic Compounds in Analytical Chemistry. John Wiley and Sons Ltd., USA, 448s.
  • [20] Schaller, U., Bakker, E., Spichiger, U. E., Pretsch, E. 1994. Ionic Additives for Ion-Selective Electrodes Based on Electrically Charged Carriers. Analytical Chemistry, 66(1994), 3, 391-398.
  • [21] Demirel, A., Doğan, A., Canel, E., Memon, S., Yilmaz, M., Kiliç, E. 2004. Hydrogen Ion-Selective Poly(Vinyl Chloride) Membrane Electrode Based on a p-tert-butylcalix[4]arene-oxacrown-4. Talanta, 62(2004), 123-129.
  • [22] Buck, R. P., Lindner, E. 1994. Recommendations for Nomenclature of Ion-Selective Electrodes. Pure and Applied Chemistry, 66(1994), 2527.
  • [23] Ayanoğlu, M. N., Kormalı, Ertürün, H. E., Demirel, Özel, A., Şahin, Ö., Yılmaz, M., Kılıç, E. 2015. Salicylate Ion-Selective Electrode Based on a Calix[4]arene as Ionophore. Electroanalysis, 27(2015), 1-10.
  • [24] Daunert, S., Wallace, S., Florido, A., Bachas, L. G. 1991. Anion-Selective Electrodes Based on Elektropolymerized Porphyrin Films. Analytical Chemistry, 63(1991), 1676-1679.

Year 2017, Volume: 21 Issue: 2, 437 - 443, 15.08.2017

Tuğçe Göver , H. Elif Kormalı Ertürün Ayça Demirel Özel Serkan Erdemir , Esin Canel

Abstract

References

  • [1] Greenwood, N. N., Earnsltaw, A. 1984. Chemistry of the Elements. Pergamon, Oxford, 933s.
  • [2] Benvidi, A., Ghanbarzadeh, M. T., Mazloum-Ardakani, M., Vafazadeh, R. 2011. Iodide-Selective Polymeric Membrane Electrode Based on Copper (II) Bis (N-2-bromophenylsalicyldenaminato) Complex. Chinese Chemical Letters, 22: 9(2011), 1087–1090.
  • [3] Singh, A. K., Mehtab, S. 2008. Polymeric Membrane Sensors Based on Cd(II) Schiff Base Complexes for Selective Iodide Determination in Environmental and Medicinal Samples. Talanta, 74(2008), 806–814.
  • [4] Amini, M. K., Ghaedi, M., Rafi, A., Habibi, M. H., Zohory, M. M. 2003. Iodide Selective Electrodes Based on Bis(2-mercaptobenzomercaptobenzothiazolato) Mercury(II) and Bis(4-chlorothiophenolato) Mercury(II) Carriers. Sensors, 3(2003), 509-523.
  • [5] Bermejo-Barrera P., Aboal-Somoza M., Bermejo-Barrera A., Cervera M.L., de la Guardia M. 2001. Microwave-assisted distillation of iodine for the indirect atomic absorption spectrometric determination of iodide in milk samples. J Anal Atom Spectrom., 16(2001), 382-389.
  • [6] Mesko MF, Mello PA, Bizzi CA, Dressler VL, Knapp G, Flores EM. 2010. Iodine determination in food by inductively coupled plasma mass spectrometry after digestion by microwave-induced combustion. Anal Bioanal Chem., 398(2010), 1125-1131.
  • [7] Hou X, Dahlgaard H, Rietz B, Jacobsen U, Nielsen SP, Aarkrog A. 1999. Determination of Chemical Species of Iodine in Seawater by Radiochemical Neutron Activation Analysis Combined with IonExchange Preseparation. Anal Chem., 71(1999), 2745-2750.
  • [8] Khazan, M., Azizi, F., Hedayati, M. 2013. A Review on Iodine Determination Methods in Salt and Biological Samples. Scimetr, 1(2013), 1, e14092.
  • [9] Jeong, D. C., Lee, H. K., Jeon, S. 2006. Polymeric Iodide-ion Selective Electrodes Based on Urea Derivative as an Ionophore. Bulletin of the Korean Chemical Society, 27(2006),12, 1985-1988.
  • [10] Lizondo-Sabater, J., Mart´ınez-Máñez, R., Sancenón, F., Segu´ı, M.-J., Soto, J. 2002. Cobalt(II) and Nickel(II) Complexes of a Cyclam Derivative as Carriers in Iodide-selective Electrodes. Analytica Chimica Acta, 459(2002), 229–234.
  • [11] Poursaberi, T., Hosseinia, M., Taghizadeha, M., Pirelahia, H., Shamsipurb ,M., Ganjalia, M. R. 2002. A Selective Membrane Electrode for Iodide Ion Based on a Thiopyrilium Ion Derivative as a New Ionophore. Microchemical Journal, 72(2002), 77-83.
  • [12] Zare, H. R., Memarzadeh, F., Gorji, A., Ardakani, M. M. 2005. Iodide- Selective Membrane Electrode Based on Salophen Complex of Cobalt (III). Journal of the Brazilian Chemical Society, 16(2005), 571-577.
  • [13] Erden, S. 2002. Rodanür ve Perklorat İyon-Seçici Elektrot Geliştirilmesi. Ankara Üniversitesi, Fen Bilimleri Enstitüsü, Doktora Tezi, 2s, Ankara.
  • [14] Atwood, J. L., Steed, J. W. 1997. Supramolecular Chemistry of Anions. Wiley-VCH, New York, 148s.
  • [15] Shamsipur, M., Soleymanpour, A., Akhond, M., Sharghi, H., Naseri, M. A. 2001. Iodide-Selective Carbon Paste Electrodes Based on Recently Synthesized Schiff Base Complexes of Fe(III). Analytica Chimica Acta, 450(2001), 37-44.
  • [16] Mortazavi, K., Ghaedi, M., Montazerozohori, M., Andikaey, Z. 2011. Iodide–Selective Electrodes Based on Bis(Trans- Cinnamaldehyde)1,3-Propanediimine Mercury (II) Chloride [BCPHgCl2] and Bis(Trans-Cinnamaldehyde)-1,3- Propandiimine Cadmium(II) Chloride [BCPCdCl2] Carriers: Influence of Multiwalled Carbon Nanotubes on the Response Performance. International Journal of Electrochemical Science, 6(2011), 4250-4263.
  • [17] Akın, İ., Erdemir, S., Yılmaz, M., Ersöz, M. 2012. Calix[4]arene Derivative Bearing Imidazole Groups as Carrier for the Transport of Palladium by Using Bulk Liquid Membrane. Journal of Hazardous Materials, 223– 224(2012), 24– 30.
  • [18] Anonim, 1994. IUPAC Recommendations. Analytical Chemistry Division Commission on Electroanalytical Chemistry. Recommendations for Nomenclature of Ion-Selective Electrodes. Pure and Applied Chemistry, 2527-2536.
  • [19] Zolotov, Y. A. 1997. Macrocyclic Compounds in Analytical Chemistry. John Wiley and Sons Ltd., USA, 448s.
  • [20] Schaller, U., Bakker, E., Spichiger, U. E., Pretsch, E. 1994. Ionic Additives for Ion-Selective Electrodes Based on Electrically Charged Carriers. Analytical Chemistry, 66(1994), 3, 391-398.
  • [21] Demirel, A., Doğan, A., Canel, E., Memon, S., Yilmaz, M., Kiliç, E. 2004. Hydrogen Ion-Selective Poly(Vinyl Chloride) Membrane Electrode Based on a p-tert-butylcalix[4]arene-oxacrown-4. Talanta, 62(2004), 123-129.
  • [22] Buck, R. P., Lindner, E. 1994. Recommendations for Nomenclature of Ion-Selective Electrodes. Pure and Applied Chemistry, 66(1994), 2527.
  • [23] Ayanoğlu, M. N., Kormalı, Ertürün, H. E., Demirel, Özel, A., Şahin, Ö., Yılmaz, M., Kılıç, E. 2015. Salicylate Ion-Selective Electrode Based on a Calix[4]arene as Ionophore. Electroanalysis, 27(2015), 1-10.
  • [24] Daunert, S., Wallace, S., Florido, A., Bachas, L. G. 1991. Anion-Selective Electrodes Based on Elektropolymerized Porphyrin Films. Analytical Chemistry, 63(1991), 1676-1679.
There are 24 citations in total.

Details

Journal Section Articles
Authors

Tuğçe Göver

H. Elif Kormalı Ertürün This is me

Ayça Demirel Özel This is me

Serkan Erdemir

Esin Canel

Publication Date August 15, 2017
Published in Issue Year 2017 Volume: 21 Issue: 2

Cite

APA Göver, T., Kormalı Ertürün, H. E., Demirel Özel, A., Erdemir, S., et al. (2017). İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, 21(2), 437-443. https://doi.org/10.19113/sdufbed.83711
AMA Göver T, Kormalı Ertürün HE, Demirel Özel A, Erdemir S, Canel E. İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot. J. Nat. Appl. Sci. August 2017;21(2):437-443. doi:10.19113/sdufbed.83711
Chicago Göver, Tuğçe, H. Elif Kormalı Ertürün, Ayça Demirel Özel, Serkan Erdemir, and Esin Canel. “İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21, no. 2 (August 2017): 437-43. https://doi.org/10.19113/sdufbed.83711.
EndNote Göver T, Kormalı Ertürün HE, Demirel Özel A, Erdemir S, Canel E (August 1, 2017) İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21 2 437–443.
IEEE T. Göver, H. E. Kormalı Ertürün, A. Demirel Özel, S. Erdemir, and E. Canel, “İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot”, J. Nat. Appl. Sci., vol. 21, no. 2, pp. 437–443, 2017, doi: 10.19113/sdufbed.83711.
ISNAD Göver, Tuğçe et al. “İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi 21/2 (August 2017), 437-443. https://doi.org/10.19113/sdufbed.83711.
JAMA Göver T, Kormalı Ertürün HE, Demirel Özel A, Erdemir S, Canel E. İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot. J. Nat. Appl. Sci. 2017;21:437–443.
MLA Göver, Tuğçe et al. “İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot”. Süleyman Demirel Üniversitesi Fen Bilimleri Enstitüsü Dergisi, vol. 21, no. 2, 2017, pp. 437-43, doi:10.19113/sdufbed.83711.
Vancouver Göver T, Kormalı Ertürün HE, Demirel Özel A, Erdemir S, Canel E. İyonofor Olarak Bir Kaliks[4]aren Türevinin Kullanıldığı İyodür-Seçici PVC Membran Elektrot. J. Nat. Appl. Sci. 2017;21(2):437-43.
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