Peynir Üretiminde Kalsiyum ve Fosfat İçeriğinin Önemi
Year 2001,
Volume: 15 Issue: 26, 16 - 26, 15.06.2001
Ahmet Ayar
Güldane Yılmaz
Abstract
Süt tuzlarının içeriğindeki kalsiyum ve fosfat, sütün rennet koagülasyonunda, peynirdeki tampon sistemi ve yapısında önemli bir rol sahiptir. Kalsiyum ilavesi sütün peynir mayası ile pıhtılaşmasını hızlandırır. Bu kazanın üzerine olumsuz bir asit yüklenmiş olan kalıntıların nötralizasyonundan dolayıdır. Nötralizasyon mayalanmış ürünlerin lezzetini artırır. Kalsiyumun düşük konsantrasyonlarda ilavesi jel sağlar. Üretilen asit miktarı ve süzme sırasında peynirin suyunun pH’ı peynirin mineral içeriğini belirleyen önemli faktörlerdir. Hem pH hem de erinleyen süt oranı peynir üretiminin minerallerle bir etkisi sahiptir. Süt ve peynirin asidifikasyon esnasında tamponlanmasında kolloidal kalsiyum fosfat önemli bir rolü vardır.
References
- Bringe, N.A. ve Kinsella, J.E. 1986. Use of platelet aggregometer to monitor the chymosin-initiated coagulation of casein micelles. J. Dairy Res. 53, 389.
- Coulon, J.B., Verdier, J., Pradel, P. ve Almena, M. 1998. Effect of lactation stage on the cheese making properties of milk and the quality of Saint Nectaire type cheese. J. Dairy Res. 65, 295-305.
- Çakmakçı, Ş. 1994. Gıda katkı maddesi olarak fosfatlar. Gıda 19, 63-71.
- Dalgleish, D.G. 1983. Coagulation of renneted bovine casein micelles: dependence on temperature, calcium ion concentration and ionic strength. J. Dairy Res. 50, 331-335.
- Dalgleish, D.G. 1987. The enzymatic coagulation of milk. Elsevier Appl. Sci. Publ., London, England.
- Dalgleish, D.G. ve Law, A.J.R. 1989. pH induced dissociation of bovine casein micelles: mineral solubilization and its relation to casein release. J. Dairy Res. 56, 727-730.
- De La Fuente, M.A., Olano, A., Requena, T. ve Juarez, M. 1998. Salt balance and rennet clotting properties of cow's, ewe's and goat's milks preserved with carbon dioxide. J. Food Prot. 61, 66-72.
- Donnelly, W.J. ve Barry, J.G. 1983. Casein compositional studies II. Changes in Irish milk for manufacturing and role of milk proteinase. J. Dairy Res. 50, 433-438.
- Everett, D.W. 1995. Interactions between the casein protein matrix in cheddar cheese and fat globules stabilized with modified membranes. DAI-B 56/2, 6482.
- Fox, P.F. 1970. Influence of aggregation on the susceptibility of casein to proteolysis. J. Dairy Res. 37, 73-180.
- Fox, P.F., Lucey, J.A. ve Cogan, T.M. 1990. Glycolysis and related reactions during cheese manufacture and ripening. CRC Crit. Rev. Food Sci. Nutr. 29, 237-241.
- Fox, P.F. ve McSweeney, P.L.H. 1998. Dairy Chemistry and Biochemistry. Blackie Academic & Professional, An imprint of Thomson Science, London, UK.
- Gannoukou, M., Kehagias, H., ve Katsipes, A. 1989. Effect of various factors on the characteristics and yield of cheese coagulum and strained yoghurt manufactured from various types of milk. Epistimekal Tehnologia Galaktos 5, 28.
- Green, M.L. 1986. Effect of replacing part of the sodium chloride in Cheddar cheese by sodium or potassium phosphates on ripening, flavour and texture. J. Dairy Res. 33, 329-332.
- Grifferty, M.B. ve Fox, P.F. 1988. Milk alkaline proteinase. J. Dairy Res. 55, 609-611.
- Guinee, T.P., O'Callaghan, D.J., Mulholland, E.O., ve Harrington, D. 1996. Milk protein standardisation by ultrafiltration for cheddar cheese manufacture. J. Dairy Res. 63, 281-293.
- Hill, A.R., Bullock, D.H., ve Irvine, D.M. 1985. Composition of cheese whey. Effect of pH and temperature at dipping. J. Can. Inst. Food Sci. Tech. 18:53.
- Holt, C., Kemenade, M.L.J.M., Nelson, L.S., Sawyer, L., Harries, J.E., Bailey, R.T., ve Hukins, D.W.L. 1989. Composition and structure of micellar calcium phosphate. J. Dairy Res. 56, 411-414.
- Kindstedt, P.S. ve Kosikowski, F.V. 1988. Calcium, phosphorus and sodium concentrations in Cheddar cheese. J. Dairy Sci. 71, 285-288.
- Lawrence, R.C., Creamer, L.K., ve Gilles, J. 1983. The relationship between cheese texture and flavour. N.Z. Dairy Sci. Tech. 18, 175.
- Lawrence, R.C., Heap, H.A., ve Gilles, J. 1984. A controlled approach to cheese technology. J. Dairy Sci. 67, 1632-1636.
- Lawrence, R.C., Creamer, L.K., Gilles, J. 1987. Texture Development During Cheese Ripening, Symposium: Cheese Ripening Technology. J. Dairy Sci. 70, 1748-1760.
- Lucey, J.A. 1990. Physico-chemical aspects of Cheddar cheese. 2nd Moorepark Cheese Symposium, Fermoy, Ireland.
- Lucey, J.A. 1992. Acid-base buffering and rennet coagulation properties of milk systems. Thesis. University College Cork, Irish Republic.
- Luyten, H., Vliet, T.V., ve Walstra, P. 1991. Characterization of the consistency of Gouda cheese; rheological properties. Neth. Milk Dairy J. 45, 3.
- Macheboeuf, D., Coulon, J.B., ve D’Hour, P. 1993. Effect of breed, protein genetic variants and feeding on cow’s milk coagulation properties. J. Dairy Res. 60, 43-54.
- Marshall, R.J., Hatfield, D.S., ve Green, M.L.L. 1982. Assessment of two instruments for continuous measurement of the curd firming of renneted milk. J. Dairy Res. 49, 127-131.
- McMahon, D.J., Brown, R.J., Richardson, G.H., ve Ernstrom, C.A. 1984. Effects of calcium, phosphate and bulk culture media on milk coagulation properties. J. Dairy Sci. 67, 930-935.
- Metzger, L.E., Barbano, D.M., ve Kindstedt, P.S. 2000. Effect of milk preacidification on low fat mozzarella cheese: I. Composition and yield. J. Dairy Sci. 83, 648-658.
- Metzger, L.E., Barbano, D.M., ve Kindstedt, P.S. 2001. Effect of milk preacidification on low fat mozzarella cheese: II. Post-melt chewiness and whiteness. J. Dairy Sci. 84, 1357-1366.
- Morris, H.A., Holt, C., Brooker, B.E., Banks, J.M., ve Manson, W. 1988. Inorganic constituents of cheese: analysis of juice from one-month-old Cheddar cheese and the use of light and electron microscopy to characterise the crystalline phases. J. Dairy Res. 55, 255-259.
- Okashi, T., Nagai, S., Yamauchi, K., Haga, S., Fukuda, H., Fujino, H. 1988. Effects of reconstituted milk prepared from high-temperature heated dried skim milk. Japanese J. Dairy and Food Sci. 37, 143-150.
- Oysun, G. 1987. Süt Kimyası ve Biyokimyası. Ondokuz Mayıs Üniversitesi Yayınları Yayın No:18, Samsun.
- Patel, R.S. ve Reuter, H. 1986. Effect of sodium, calcium and phosphate on properties of rennet coagulated milk. Lebensm. Wiss. Tech. 19, 288-295.
- Pyne, G.T. 1955. The chemistry of casein: a review of the literature. Dairy Sci. Abs. 17, 531-534.
- Storry, J.E. ve Ford, G.D. 1982. Some factors affecting the post-clot development of coagulum strength in renneted milk. J. Dairy Res. 48, 467-472.
- Üçüncü, M. 1984. Beyaz Peynir Yapımında Kullanılan Yardımcı Maddeler. İstanbul Ticaret Odası Yayın No:14, İstanbul.
- Üçüncü, M. 1992. Süt Teknolojisi II. E.Ü. Müh. Fak. Yayın No: 88, İzmir.
- Van Hooydonk, A.C.M., Hagedoorn, H.G. ve Boerrigter, H. 1986. pH-induced physico-chemical changes of casein micelles in milk and their effect on renneting. I. Effects of acidification on physico-chemical properties. Neth. Milk Dairy J. 40, 369.
- Walstra, P. 1990. On the stability of casein micelles. J. Dairy Sci. 73, 1965-1969.
- Walstra, P. ve Jenness, R. 1984. Dairy Chemistry and Physics. John Wiley & Sons, New York, NY.
- Wolfschoon-Pombo, A.F. 1997. Influence of calcium chloride addition to milk on the cheese yield. Int. Dairy J. 7, 249-254.
Importance of Calcium and Phosphate in Cheese Manufacture
Year 2001,
Volume: 15 Issue: 26, 16 - 26, 15.06.2001
Ahmet Ayar
Güldane Yılmaz
Abstract
The milk salts, calcium and phosphate have an important role in the rennet coagulation of milk and in the structure and buffering of cheese. Addition of calcium reduces the rennet coagulation time of milk that is due to the neutralization of negatively charged residues on casein. Addition of low concentrations of calcium also increases gel firmness. The rate of acid production and the pH of the whey at draining are the critical factors that affect the mineral content of cheese. Both pH and the proportion of dissolved milk salts have important effects on cheese texture. An important role is detected for colloidal calcium phosphate in buffering during the acidification of milk and cheese.
References
- Bringe, N.A. ve Kinsella, J.E. 1986. Use of platelet aggregometer to monitor the chymosin-initiated coagulation of casein micelles. J. Dairy Res. 53, 389.
- Coulon, J.B., Verdier, J., Pradel, P. ve Almena, M. 1998. Effect of lactation stage on the cheese making properties of milk and the quality of Saint Nectaire type cheese. J. Dairy Res. 65, 295-305.
- Çakmakçı, Ş. 1994. Gıda katkı maddesi olarak fosfatlar. Gıda 19, 63-71.
- Dalgleish, D.G. 1983. Coagulation of renneted bovine casein micelles: dependence on temperature, calcium ion concentration and ionic strength. J. Dairy Res. 50, 331-335.
- Dalgleish, D.G. 1987. The enzymatic coagulation of milk. Elsevier Appl. Sci. Publ., London, England.
- Dalgleish, D.G. ve Law, A.J.R. 1989. pH induced dissociation of bovine casein micelles: mineral solubilization and its relation to casein release. J. Dairy Res. 56, 727-730.
- De La Fuente, M.A., Olano, A., Requena, T. ve Juarez, M. 1998. Salt balance and rennet clotting properties of cow's, ewe's and goat's milks preserved with carbon dioxide. J. Food Prot. 61, 66-72.
- Donnelly, W.J. ve Barry, J.G. 1983. Casein compositional studies II. Changes in Irish milk for manufacturing and role of milk proteinase. J. Dairy Res. 50, 433-438.
- Everett, D.W. 1995. Interactions between the casein protein matrix in cheddar cheese and fat globules stabilized with modified membranes. DAI-B 56/2, 6482.
- Fox, P.F. 1970. Influence of aggregation on the susceptibility of casein to proteolysis. J. Dairy Res. 37, 73-180.
- Fox, P.F., Lucey, J.A. ve Cogan, T.M. 1990. Glycolysis and related reactions during cheese manufacture and ripening. CRC Crit. Rev. Food Sci. Nutr. 29, 237-241.
- Fox, P.F. ve McSweeney, P.L.H. 1998. Dairy Chemistry and Biochemistry. Blackie Academic & Professional, An imprint of Thomson Science, London, UK.
- Gannoukou, M., Kehagias, H., ve Katsipes, A. 1989. Effect of various factors on the characteristics and yield of cheese coagulum and strained yoghurt manufactured from various types of milk. Epistimekal Tehnologia Galaktos 5, 28.
- Green, M.L. 1986. Effect of replacing part of the sodium chloride in Cheddar cheese by sodium or potassium phosphates on ripening, flavour and texture. J. Dairy Res. 33, 329-332.
- Grifferty, M.B. ve Fox, P.F. 1988. Milk alkaline proteinase. J. Dairy Res. 55, 609-611.
- Guinee, T.P., O'Callaghan, D.J., Mulholland, E.O., ve Harrington, D. 1996. Milk protein standardisation by ultrafiltration for cheddar cheese manufacture. J. Dairy Res. 63, 281-293.
- Hill, A.R., Bullock, D.H., ve Irvine, D.M. 1985. Composition of cheese whey. Effect of pH and temperature at dipping. J. Can. Inst. Food Sci. Tech. 18:53.
- Holt, C., Kemenade, M.L.J.M., Nelson, L.S., Sawyer, L., Harries, J.E., Bailey, R.T., ve Hukins, D.W.L. 1989. Composition and structure of micellar calcium phosphate. J. Dairy Res. 56, 411-414.
- Kindstedt, P.S. ve Kosikowski, F.V. 1988. Calcium, phosphorus and sodium concentrations in Cheddar cheese. J. Dairy Sci. 71, 285-288.
- Lawrence, R.C., Creamer, L.K., ve Gilles, J. 1983. The relationship between cheese texture and flavour. N.Z. Dairy Sci. Tech. 18, 175.
- Lawrence, R.C., Heap, H.A., ve Gilles, J. 1984. A controlled approach to cheese technology. J. Dairy Sci. 67, 1632-1636.
- Lawrence, R.C., Creamer, L.K., Gilles, J. 1987. Texture Development During Cheese Ripening, Symposium: Cheese Ripening Technology. J. Dairy Sci. 70, 1748-1760.
- Lucey, J.A. 1990. Physico-chemical aspects of Cheddar cheese. 2nd Moorepark Cheese Symposium, Fermoy, Ireland.
- Lucey, J.A. 1992. Acid-base buffering and rennet coagulation properties of milk systems. Thesis. University College Cork, Irish Republic.
- Luyten, H., Vliet, T.V., ve Walstra, P. 1991. Characterization of the consistency of Gouda cheese; rheological properties. Neth. Milk Dairy J. 45, 3.
- Macheboeuf, D., Coulon, J.B., ve D’Hour, P. 1993. Effect of breed, protein genetic variants and feeding on cow’s milk coagulation properties. J. Dairy Res. 60, 43-54.
- Marshall, R.J., Hatfield, D.S., ve Green, M.L.L. 1982. Assessment of two instruments for continuous measurement of the curd firming of renneted milk. J. Dairy Res. 49, 127-131.
- McMahon, D.J., Brown, R.J., Richardson, G.H., ve Ernstrom, C.A. 1984. Effects of calcium, phosphate and bulk culture media on milk coagulation properties. J. Dairy Sci. 67, 930-935.
- Metzger, L.E., Barbano, D.M., ve Kindstedt, P.S. 2000. Effect of milk preacidification on low fat mozzarella cheese: I. Composition and yield. J. Dairy Sci. 83, 648-658.
- Metzger, L.E., Barbano, D.M., ve Kindstedt, P.S. 2001. Effect of milk preacidification on low fat mozzarella cheese: II. Post-melt chewiness and whiteness. J. Dairy Sci. 84, 1357-1366.
- Morris, H.A., Holt, C., Brooker, B.E., Banks, J.M., ve Manson, W. 1988. Inorganic constituents of cheese: analysis of juice from one-month-old Cheddar cheese and the use of light and electron microscopy to characterise the crystalline phases. J. Dairy Res. 55, 255-259.
- Okashi, T., Nagai, S., Yamauchi, K., Haga, S., Fukuda, H., Fujino, H. 1988. Effects of reconstituted milk prepared from high-temperature heated dried skim milk. Japanese J. Dairy and Food Sci. 37, 143-150.
- Oysun, G. 1987. Süt Kimyası ve Biyokimyası. Ondokuz Mayıs Üniversitesi Yayınları Yayın No:18, Samsun.
- Patel, R.S. ve Reuter, H. 1986. Effect of sodium, calcium and phosphate on properties of rennet coagulated milk. Lebensm. Wiss. Tech. 19, 288-295.
- Pyne, G.T. 1955. The chemistry of casein: a review of the literature. Dairy Sci. Abs. 17, 531-534.
- Storry, J.E. ve Ford, G.D. 1982. Some factors affecting the post-clot development of coagulum strength in renneted milk. J. Dairy Res. 48, 467-472.
- Üçüncü, M. 1984. Beyaz Peynir Yapımında Kullanılan Yardımcı Maddeler. İstanbul Ticaret Odası Yayın No:14, İstanbul.
- Üçüncü, M. 1992. Süt Teknolojisi II. E.Ü. Müh. Fak. Yayın No: 88, İzmir.
- Van Hooydonk, A.C.M., Hagedoorn, H.G. ve Boerrigter, H. 1986. pH-induced physico-chemical changes of casein micelles in milk and their effect on renneting. I. Effects of acidification on physico-chemical properties. Neth. Milk Dairy J. 40, 369.
- Walstra, P. 1990. On the stability of casein micelles. J. Dairy Sci. 73, 1965-1969.
- Walstra, P. ve Jenness, R. 1984. Dairy Chemistry and Physics. John Wiley & Sons, New York, NY.
- Wolfschoon-Pombo, A.F. 1997. Influence of calcium chloride addition to milk on the cheese yield. Int. Dairy J. 7, 249-254.