OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION

Okey-onyesolu Chinenye Faith; Ude Callistus Nonso; Onukwuli Okechukwu Dominic; Okoye Chukwunonso Chukwuzuloke

OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION

Abstract

Biosorption potentials of activated carbons from pentaclethra Macrophylla (PMAC) seed shells for the removal of Pb(II) from aqueous solution were investigated. The physicochemical properties of pentaclethra Macrophylla (PMAC) seed shells were characterized through ASTM standards for adsorbents tests. The functional groups of the pentaclethra Macrophylla (PMAC) were investigated using Fourier transform infrared (FTIR) spectroscopy, morphology measured with scanning electron microscopy (SEM),oxides investigated by X-ray fluorescence (XRF) and diffraction pattern observed by x-ray diffraction (XRD). Influence of key parameters such as contact time, pH of Pb(II) solution, temperature of Pb(II) solution, adsorbent dosage, adsorbent particle size and initial concentration of Pb(II)solution were studied by batch mode. These process parameters were optimized using response surface methodology (RSM) and analysis of variance (ANOVA). The significance of the different process parameters and their combined effects on the adsorption efficiency were established through a full factorial central composite design. The results obtained are in good agreement with published data for other activated carbons as well as various international standards for water treatment. An optimal yield of 94.83% was obtained with optimal conditions of solution temperature, 30oC; contact time, 120minutes; adsorbent dosage, 1.50 g; and pH, 7. The optimization was performed using the numerical method of the Design Expert version 8.7.1.0 by State Ease U.S.A. This investigation has shown that Pentaclethra Macrophylla (PMAC) seed shells from Nigeria can be used for industries as activated carbon for waste water treatment.

Keywords

References

[1] Nabi, S. A., Bushra, R. A., Al-Othman, Z. A., & Naushad, M. (2011). Synthesis, characterization and analytical applications of a new composite cation exchange material acetonitrile stannic (IV) selenite: adsorption behavior of toxic metal ions in nonionic surfactant medium. Separation Science Technology, 46, 847-857.
[2] Karatas, M. (2011). Removal of Pb(II) from water by natural zeolite tuff: Kinetics and thermodynamics. Journal of Hazardous Materials, 199-200, 383-389.
[3] Okoye, A. I., Ejikeme, P. M., & Onukwuli, O. D. (2010). Lead removal from waste water using fluted pumpkin seed shell activated carbon: Adfsorption modelling and kinetics. International Journal of Environmental Technology, 7 (4), 793-800.
[4] Pauliulis, D. (2015). Adsorptive removal of Pb2+ ions from aqueous solutions by peat. Polish Journal of Environmental Studies , 24 (3), 1213-1218.
[5] Akar, S. T., Arslan, S., Alp, T., Arslan, D., Akar, T. (2012). Biosorption potential of the waste biomaterial obtained from Cucumis melo for the removal of Pb2+ ions from aqueous media: Equilibrium, Kinetic, thermodynamic and mechanism analysis. Chemical Engineering Journal, 185-186, 82-90.
[6] Girald, L., Moreno-Pirajan, J. C. (2008). Pb2+ adsorption from aqueous solution on activated carbons obtained from lignocellulosic residues. Brazilian Journal of Chemical Engineering, 25(1), 143-151.
[7] Ramana, D. K. V., Reddy, D. H. K., Yu, J. S. , Seshiah, K. (2012). Pigeon peas hulls waste as potential adsorbent for removal of Pb(II) and NI(II) from waste. Chemical Engineering Journal, 197, 24-33.
[8] Kavak, D., Demir, M., Bassagel, B., Anagum, A. S. (2013). Factorial experimental design for optimizing the removal of lead ions from aqueous solutions by cation exchange resin. Desaliation and Water Treatment, 51, 1712-1719.

[9] Kavak, D. (2017). Removal of Iron, Copper and Zinc Mixture From Aqueous Solution By Cross Flow Nanofiltration. Fresenius Environmental Bulletin, 25(1a), 1101-1107.
[10] Shi, B. Y., Li, G. H., Wang, D. S., Feng, C. H., Tang, H. X. (2007). Removal of direct dyes by coagulation: the performance of preformed polymeric aluminum species. Journal of Hazardous Material, 143, 567-574.
[11] Ahmad, M. A., Alrozi, R. (2011). Removal of malachite green dye from aqueous solution using rambutan peel-based activated carbon: equilibrium, kinetic and thermodynamic studies. Chemical Engineering Journal, 171, 510 – 516.
[12] Uluozlu, O. D., Sari, A., Tuzen, M., Soylak, M. (2008). Biosorption of Pb(II) and Cr(III) from aqueous solution by lichen (Parmelinatlliaceae) biomass. Bioresources Technology, 99, 2972 – 2980.
[13] Al-Asheh, S., Banat, F., Al-Omari, R., Duvnjak, Z. (2000). Predictions of binary sorption isotherms for the sorption of heavy metals by pine bark using single isotherm data. Chemosphere, 41, 659-665.
[14] Bailey, S. E, Olin, T. I., Bricka, R. m, Adrian, D. D. (1999). A review of potentially low cost sorbents for heavy metals. Water Resources, 33, 2464-2479.
[15] Chilaka, F. C., Anosike, E. O., Egbuna, P. C. (1993). Purification and properties of polyphenol oxidase from oil bean (P. macrophyllaBenth) seeds. Journal Science Food Agriculture, 61(1), 125-127.
[16] Agbogidi, M. O. (2010). Response of African oil bean (PentaclethramacrophyllaBenth) seeds to soils contaminated with spent lubrication oil. African Journal of Environmental Science and Technology, 4(5), 492- 494.
[17] Nwabanne, J. T., Igbokwe, P. K. (2012) Comparative study of lead (II) removal from aqueous solution using different adsorbents. International Journal of Engineering Research and Applications, 2(4), 1830-1838.
[18] Ahmad M. A., Alrozi R.,(2011) Removal of malachite green dye from aqueous solution using rambutan peel-based activated carbon: Equilibrium, kinetic and thermodynamic studies. Chemical Engineering Journal, 171, 510– 516.
[19] Kara S, Aydiner C, Demirbas E, Kobya M, Dizge N., (2007) Modeling the effects of adsorbent dose and particle size on the adsorption of reactive textile dyes by fly ash. Desalination, 212, 282–293.
[20] Lee H.V., Yunus R, Juan J.C, Taufiq-Yap Y.H, (2011). Process optimization design for jatropha-based biodesel production using response surface methodology. Fuel Processing Technology, 92, 2420–2428.

Details

Primary Language

English

Subjects

-

Journal Section

Research Article

Authors

Okey-onyesolu Chinenye Faith This is me
Nigeria

Ude Callistus Nonso This is me
Nigeria

Onukwuli Okechukwu Dominic This is me
Nigeria

Okoye Chukwunonso Chukwuzuloke This is me
Nigeria

Publication Date

June 1, 2017

Submission Date

November 3, 2016

Acceptance Date

February 19, 2017

Published in Issue

Year 2017 Volume: 35 Number: 2

IZ

https://izlik.org/JA68UL32RY

Cite

RIS / Bibtex

APA

Faith, O.- onyesolu C., Nonso, U. C., Dominic, O. O., & Chukwuzuloke, O. C. (2017). OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION. Sigma Journal of Engineering and Natural Sciences, 35(2), 213-226. https://izlik.org/JA68UL32RY

AMA

1.Faith O onyesolu C, Nonso UC, Dominic OO, Chukwuzuloke OC. OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION. SIGMA. 2017;35(2):213-226. https://izlik.org/JA68UL32RY

Chicago

Faith, Okey-onyesolu Chinenye, Ude Callistus Nonso, Onukwuli Okechukwu Dominic, and Okoye Chukwunonso Chukwuzuloke. 2017. “OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION”. Sigma Journal of Engineering and Natural Sciences 35 (2): 213-26. https://izlik.org/JA68UL32RY.

EndNote

Faith O- onyesolu C, Nonso UC, Dominic OO, Chukwuzuloke OC (June 1, 2017) OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION. Sigma Journal of Engineering and Natural Sciences 35 2 213–226.

IEEE

[1]O.- onyesolu C. Faith, U. C. Nonso, O. O. Dominic, and O. C. Chukwuzuloke, “OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION”, SIGMA, vol. 35, no. 2, pp. 213–226, June 2017, [Online]. Available: https://izlik.org/JA68UL32RY

ISNAD

Faith, Okey-onyesolu Chinenye - Nonso, Ude Callistus - Dominic, Onukwuli Okechukwu - Chukwuzuloke, Okoye Chukwunonso. “OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION”. Sigma Journal of Engineering and Natural Sciences 35/2 (June 1, 2017): 213-226. https://izlik.org/JA68UL32RY.

JAMA

1.Faith O- onyesolu C, Nonso UC, Dominic OO, Chukwuzuloke OC. OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION. SIGMA. 2017;35:213–226.

MLA

Faith, Okey-onyesolu Chinenye, et al. “OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION”. Sigma Journal of Engineering and Natural Sciences, vol. 35, no. 2, June 2017, pp. 213-26, https://izlik.org/JA68UL32RY.

Vancouver

1.Okey-onyesolu Chinenye Faith, Ude Callistus Nonso, Onukwuli Okechukwu Dominic, Okoye Chukwunonso Chukwuzuloke. OPTIMIZATION AND CHARACTERIZATION OF ADSORPTIVE BEHAVIOR OF PENTACLETHRA MACROPHYLLA ACTIVATED CARBON ON AQUEOUS SOLUTION. SIGMA [Internet]. 2017 Jun. 1;35(2):213-26. Available from: https://izlik.org/JA68UL32RY