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Investigation of Hydrochloric Acid Resistance of Ground Pumice Powder Substituted Mortars

Year 2022, Volume: 5 Issue: 2, 160 - 170, 31.12.2022
https://doi.org/10.51764/smutgd.1199413

Abstract

In this study, Hydrochloric (HCI) acid resistance of Ground Pumice Powder (GPP) mortars was investigated. In the preparation of the mortar mixtures, CEMI-42.5/R Portland Cement was used as the binder, and crushed sand with 0-4 mm grain size was used as the aggregate. Mortar samples were produced by substituting GPP as a mineral additive with cement at the rates of 0%, 10%, 20% and 30% by weight. In the investigation of the acid effect, 5% by volume of concentrated HCl acid was used. flow-table test was applied to fresh mortar samples. Mortar samples were kept in the standard curing pool for 7, 28 and 90 days and unit volume weight, water absorption and porosity ratios of the samples that completed their 28th and 90th days were determined. flexure and compression tests were performed on the samples that completed their 7th, 28th and 90th days. The samples, which were kept in the standard curing pool for 28 days, were then subjected to flexure and compression tests at the end of 7, 28 and 90 days in HCl acid curing. In HCl acid, unit volume weight, water absorption and porosity ratios of the samples that completed their 28th and 90th days were determined. As a result, it was observed that the flow-table value, unit weight, flexural and compressive strength decreased, water absorption and porosity ratios increased with the increase of the GPP substitution ratio compared to the reference sample. While the compressive strengths of the samples in the HCl acid solution during the 7-day waiting period increased with the increase in the GPP replacement ratio, a decrease occurred in the 28th and 90-day waiting times.

References

  • ACI 515.2R-13, (2013).Guide to Selecting Protective Treatments for Concrete ACI Committee 515, American Concrete Institute.
  • Aiken, TA, Kwasny, J., Sha, W. ve Soutsos, MN (2018). Effect of slag content and activator dosage on the resistance of fly ash geopolymer binders to sulfuric acid attack. Cement and Concrete Research, 111(May), 23-40. https://doi.org/10.1016/j.cemconres.2018.06.011
  • Al-Gahtani, H.J., Abbas, A.G.F., Al-Amoudi, O.S.B. (1998). Concrete mixture design for hot weather: Experimental and statistical analyses, Magazine of Concrete Research, 50, 95-105.
  • ASTM C618, (1998). Standart Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use as a Mineral Admixture in Concrete,Annual Book of ASTM Standarts, No.4.
  • Basheer P., Chidiact, S., Long, A. (1996). Predictive models for deterioration of concrete structures, Construction and Building Materials, vol. 10, no. 1, pp. 27-37.
  • Bertron, A., Duchesne, J., Escadeillas, G.(2005). Attack of cement pastes exposed to organic acids in manure, Cem. Concr. Compos. 27(9), 898-909.
  • Chandra, S. (1988).Hydrochloric acid attack on cement mortar - an analytical study, Cem. Concr. Res. 18 (2), 193-203.
  • De Ceukelaire, L., (1992). The effects of hydrochloric acid on mortar, Cem. Concr. Res. 22 (5) 903-914.
  • Gaurav, C., Abhishek, K., Shobha, R. (2022). Comparative study of metakaolin, pumice powder and silica fume in producing treated sustainable recycled coarse aggregate concrete by adopting two-stage mixing. Cleaner Engineering and Technology, 9, 100528. doi.org/10.1016/j.clet.2022.100528
  • Gutberlet, T., Hilbig, H., Beddoe, R.E. (2015). Acid attack on hydrated cement - effect of mineral acids on the degradation process, Cem. Concr. Res. 74, 35-43.
  • Hossain, K.M.A., Ahmed S., Lachemi M.(2011).Lightweight concrete incorporating pumice based blended cement and aggregate: mechanical and durability characteristics, Constr. Build. Mater. 25, 1186-1195.
  • Ismail, S., Ramli, M. (2013). Engineering properties of treated recycled concrete aggregate (RAC) for structural applications. Construct. Build. Mater. 44, 464-476.
  • Kavas, T., Christogerou, A., Pontikes, Y., Angelopoulos, G. N. (2011). Valorisation of different types of boron-containing wastes for the production of lightweight aggregates," J. Hazard. Mater., vol. 185, no. 2-3, pp. 1381-1389.
  • Kayıhan, M.R., Dündar, B., Çınar, E.(2022).’’ Geri Dönüştürülmüş Asfalt Atığı İle Üretilen Öğütülmüş Pomza Tozu Katkılı Harçların Mühendislik Özelliklerinin Araştırılması’’. Ed. Kardaşlar A., Mike F. Uluslararası Korkut Ata Bilimsel Araştırmalar Konferansı.(424-425).
  • König, J., Petersen, R. R., Iversen, N., Yue, Y.(2018). Suppressing the effect of cullet composition on the formation and properties of foamed glass, Ceram. Int., vol. 44, no. 10, pp. 11143-11150.
  • Kwasny, J., Aiken, TA, Soutsos, MN, McIntosh, JA ve Cleland, DJ (2018). Sulphate and acid resistance of Lithomarge based geopolymer mortars. Construction and Building Materials, 166, 537-553.
  • Liu M. (2011). Incorporating ground glass in self- compacting concrete, Construction and Building Materials, 25, 919-925.
  • Muthu, M., Yang, E.-H. ve Ünlüer, C. (2021). Resistance of graphene oxide-modified cement pastes to hydrochloric acid attack. İnşaat ve Yapı Malzemeleri, 273, 121990. doi:10.1016/j.conbuildmat.2020.
  • Olivier, J.A.H.W., Peters, J.G.J.(2020). Trends in Global CO2 and Total Greenhouse Gas Emissions: 2019 Report, PBL, Netherlands Environ. Assess. Agency Hague, Netherlands.
  • Pravallika B. D., Rao K. V.(2016). The study on strength properties of light weight concrete using light weight aggregate, Int. J. Sci. Res. 5 (6), 1735-1739.
  • Rajeswari S., Sunilaa G. (2015). Experimental study of light weight concrete by partial replacement of coarse aggregate using pumice aggregate, Int. J. Sci. Eng. Res., 50-53.
  • Rashad, A.M. (2019). A short manual on natural pumice as a lightweight aggregate. Journal of Building Engineering, 25, 100802. doi:10.1016/j.jobe.2019.100802
  • Toutanji, H., Deng, Y. (2007). Comparison between organic and inorganic matrices for RC beams strengthened with carbon fiber sheets, Journal of Composites for Construction, vol. 11, no. 5, pp. 507-513.
  • Toutanji, H., Zhao, L., Zhang, Y., (2006). Flexural behavior of reinforced concrete beams externally strengthened with CFRP sheets bonded with an inorganic matrix," Engineering Structures, vol. 28, no. 4, pp. 557-566.
  • TS EN 1008, (2003). Beton-Karma suyu-Numune alma, deneyler ve beton endüstrisindeki işlemlerden geri kazanılan su dahil, suyun, beton karma suyu olarak uygunluğunun tayini kuralları TSE, Ankara Türkiye.
  • TS EN 1015-3, (2000). Kâgir harcı-Deney metotları- Bölüm 3: Taze harç kıvamının tayini TSE, Ankara, Türkiye.
  • TS EN 1170-6, (1999). Ön yapımlı beton mamuller- Cam elyaf takviyeli çimento (ctc) deney metodu-Bölüm 6: Suya daldırma yoluyla su emme ve kuru yoğunluk tayini TSE, Ankara Türkiye.
  • TS EN 196-1.(2016). Çimento deney metotları- Bölüm 1: Dayanım tayini TSE, Ankara Türkiye.
  • TS EN 197-1.(2012). Cement-Stage 1: General cements-component, TSE, Ankara Turkey. Using the orthogonal design method, Construction and Building Materials; 31, 289-293.
  • Yurt, Ü., Dündar, B., & Çınar, E. (2020). Jeopolimer Betonlarda Sülfürik Asit Etkisinin Araştırılması. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, 1548–1561.
  • Zivica, V., Bajza, A., (2001). Acidic attack of cement based materials-a review: Part 1. Principle of acidic attack, Constr. Build. Mater. 15 (8),331-340.
  • Zivica, V.R., Bajza, A., Acidic attack of cement-based materials-a review: Part 2. Factors of rate of acidic attack and protective measures. Constr. Build. Mater.16 (4) (2002) 215-222

Öğütülmüş Pomza Tozlu Harçların Hidroklorik Asit Direncinin İncelenmesi

Year 2022, Volume: 5 Issue: 2, 160 - 170, 31.12.2022
https://doi.org/10.51764/smutgd.1199413

Abstract

Bu çalışmada, Öğütülmüş Pomza Tozlu (ÖPT) harçların Hidroklorik (HCI) asit direnci araştırılmıştır. Harç karışımlarının hazırlanmasında bağlayıcı olarak CEMI-42.5/R Portland Çimentosu, agrega olarak ise 0-4 mm tane boyutunda kırma kum kullanılmıştır. Mineral katkı olarak ÖPT, çimento ile ağırlıkça %0, %10, %20 ve %30 oranlarında ikame edilerek harç numuneleri üretilmiştir. Asit etkisinin araştırılmasında hacimce %5 derişikteki HCl asit kullanılmıştır. Taze haldeki harç numunelerine yayılma deneyi uygulanmıştır. Harç numuneleri 7, 28 ve 90 gün boyunca standart kür havuzunda bekletilmiş ve 28 ve 90. gününü dolduran numunelerin birim hacim ağırlık, su emme ve porozite oranları belirlenmiştir. 7, 28 ve 90. gününü dolduran numunelere eğilme ve basınç deneyleri yapılmıştır. Standart kür havuzunda 28 gün bekletilen numuneler daha sonra, HCI asit küründe 7, 28 ve 90 gün sonunda eğilme ve basınç deneyleri yapılmıştır. HCl asitte, 28 ve 90. gününü dolduran numunelerin birim hacim ağırlık, su emme ve porozite oranları belirlenmiştir. Sonuç olarak, ÖPT ikame oranının artmasıyla referans numuneye göre yayılma değerinde, birim hacim ağırlık, eğilme ve basınç dayanımında azalma, su emme ve porozite oranları ise artış gözlemlenmiştir. HCI asit çözeltisinde 7 gün bekleme süresinde numunelerin basınç dayanımları ÖPT ikame oranının artmasıyla artış gerçekleşirken, 28. ve 90 günlük bekleme sürelerinde azalış meydana gelmiştir.

References

  • ACI 515.2R-13, (2013).Guide to Selecting Protective Treatments for Concrete ACI Committee 515, American Concrete Institute.
  • Aiken, TA, Kwasny, J., Sha, W. ve Soutsos, MN (2018). Effect of slag content and activator dosage on the resistance of fly ash geopolymer binders to sulfuric acid attack. Cement and Concrete Research, 111(May), 23-40. https://doi.org/10.1016/j.cemconres.2018.06.011
  • Al-Gahtani, H.J., Abbas, A.G.F., Al-Amoudi, O.S.B. (1998). Concrete mixture design for hot weather: Experimental and statistical analyses, Magazine of Concrete Research, 50, 95-105.
  • ASTM C618, (1998). Standart Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use as a Mineral Admixture in Concrete,Annual Book of ASTM Standarts, No.4.
  • Basheer P., Chidiact, S., Long, A. (1996). Predictive models for deterioration of concrete structures, Construction and Building Materials, vol. 10, no. 1, pp. 27-37.
  • Bertron, A., Duchesne, J., Escadeillas, G.(2005). Attack of cement pastes exposed to organic acids in manure, Cem. Concr. Compos. 27(9), 898-909.
  • Chandra, S. (1988).Hydrochloric acid attack on cement mortar - an analytical study, Cem. Concr. Res. 18 (2), 193-203.
  • De Ceukelaire, L., (1992). The effects of hydrochloric acid on mortar, Cem. Concr. Res. 22 (5) 903-914.
  • Gaurav, C., Abhishek, K., Shobha, R. (2022). Comparative study of metakaolin, pumice powder and silica fume in producing treated sustainable recycled coarse aggregate concrete by adopting two-stage mixing. Cleaner Engineering and Technology, 9, 100528. doi.org/10.1016/j.clet.2022.100528
  • Gutberlet, T., Hilbig, H., Beddoe, R.E. (2015). Acid attack on hydrated cement - effect of mineral acids on the degradation process, Cem. Concr. Res. 74, 35-43.
  • Hossain, K.M.A., Ahmed S., Lachemi M.(2011).Lightweight concrete incorporating pumice based blended cement and aggregate: mechanical and durability characteristics, Constr. Build. Mater. 25, 1186-1195.
  • Ismail, S., Ramli, M. (2013). Engineering properties of treated recycled concrete aggregate (RAC) for structural applications. Construct. Build. Mater. 44, 464-476.
  • Kavas, T., Christogerou, A., Pontikes, Y., Angelopoulos, G. N. (2011). Valorisation of different types of boron-containing wastes for the production of lightweight aggregates," J. Hazard. Mater., vol. 185, no. 2-3, pp. 1381-1389.
  • Kayıhan, M.R., Dündar, B., Çınar, E.(2022).’’ Geri Dönüştürülmüş Asfalt Atığı İle Üretilen Öğütülmüş Pomza Tozu Katkılı Harçların Mühendislik Özelliklerinin Araştırılması’’. Ed. Kardaşlar A., Mike F. Uluslararası Korkut Ata Bilimsel Araştırmalar Konferansı.(424-425).
  • König, J., Petersen, R. R., Iversen, N., Yue, Y.(2018). Suppressing the effect of cullet composition on the formation and properties of foamed glass, Ceram. Int., vol. 44, no. 10, pp. 11143-11150.
  • Kwasny, J., Aiken, TA, Soutsos, MN, McIntosh, JA ve Cleland, DJ (2018). Sulphate and acid resistance of Lithomarge based geopolymer mortars. Construction and Building Materials, 166, 537-553.
  • Liu M. (2011). Incorporating ground glass in self- compacting concrete, Construction and Building Materials, 25, 919-925.
  • Muthu, M., Yang, E.-H. ve Ünlüer, C. (2021). Resistance of graphene oxide-modified cement pastes to hydrochloric acid attack. İnşaat ve Yapı Malzemeleri, 273, 121990. doi:10.1016/j.conbuildmat.2020.
  • Olivier, J.A.H.W., Peters, J.G.J.(2020). Trends in Global CO2 and Total Greenhouse Gas Emissions: 2019 Report, PBL, Netherlands Environ. Assess. Agency Hague, Netherlands.
  • Pravallika B. D., Rao K. V.(2016). The study on strength properties of light weight concrete using light weight aggregate, Int. J. Sci. Res. 5 (6), 1735-1739.
  • Rajeswari S., Sunilaa G. (2015). Experimental study of light weight concrete by partial replacement of coarse aggregate using pumice aggregate, Int. J. Sci. Eng. Res., 50-53.
  • Rashad, A.M. (2019). A short manual on natural pumice as a lightweight aggregate. Journal of Building Engineering, 25, 100802. doi:10.1016/j.jobe.2019.100802
  • Toutanji, H., Deng, Y. (2007). Comparison between organic and inorganic matrices for RC beams strengthened with carbon fiber sheets, Journal of Composites for Construction, vol. 11, no. 5, pp. 507-513.
  • Toutanji, H., Zhao, L., Zhang, Y., (2006). Flexural behavior of reinforced concrete beams externally strengthened with CFRP sheets bonded with an inorganic matrix," Engineering Structures, vol. 28, no. 4, pp. 557-566.
  • TS EN 1008, (2003). Beton-Karma suyu-Numune alma, deneyler ve beton endüstrisindeki işlemlerden geri kazanılan su dahil, suyun, beton karma suyu olarak uygunluğunun tayini kuralları TSE, Ankara Türkiye.
  • TS EN 1015-3, (2000). Kâgir harcı-Deney metotları- Bölüm 3: Taze harç kıvamının tayini TSE, Ankara, Türkiye.
  • TS EN 1170-6, (1999). Ön yapımlı beton mamuller- Cam elyaf takviyeli çimento (ctc) deney metodu-Bölüm 6: Suya daldırma yoluyla su emme ve kuru yoğunluk tayini TSE, Ankara Türkiye.
  • TS EN 196-1.(2016). Çimento deney metotları- Bölüm 1: Dayanım tayini TSE, Ankara Türkiye.
  • TS EN 197-1.(2012). Cement-Stage 1: General cements-component, TSE, Ankara Turkey. Using the orthogonal design method, Construction and Building Materials; 31, 289-293.
  • Yurt, Ü., Dündar, B., & Çınar, E. (2020). Jeopolimer Betonlarda Sülfürik Asit Etkisinin Araştırılması. Düzce Üniversitesi Bilim ve Teknoloji Dergisi, 1548–1561.
  • Zivica, V., Bajza, A., (2001). Acidic attack of cement based materials-a review: Part 1. Principle of acidic attack, Constr. Build. Mater. 15 (8),331-340.
  • Zivica, V.R., Bajza, A., Acidic attack of cement-based materials-a review: Part 2. Factors of rate of acidic attack and protective measures. Constr. Build. Mater.16 (4) (2002) 215-222
There are 32 citations in total.

Details

Primary Language Turkish
Journal Section Articles
Authors

Meryem Rumeysa Kayıhan 0000-0002-7244-3551

Behcet Dündar 0000-0003-0724-9469

Emriye Çınar Resuloğulları 0000-0002-9435-2968

Publication Date December 31, 2022
Submission Date November 4, 2022
Acceptance Date November 21, 2022
Published in Issue Year 2022 Volume: 5 Issue: 2

Cite

APA Kayıhan, M. R., Dündar, B., & Çınar Resuloğulları, E. (2022). Öğütülmüş Pomza Tozlu Harçların Hidroklorik Asit Direncinin İncelenmesi. Sürdürülebilir Mühendislik Uygulamaları Ve Teknolojik Gelişmeler Dergisi, 5(2), 160-170. https://doi.org/10.51764/smutgd.1199413

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