İzonitrosoasetofenon ve Fenilglioksim Tek Kristallerinde Tuzaklanmış İminoksi Radikallerinin Elektron Spin Rezonansı
Abstract
Gama ışınlarıyla ışınlanan izonitrosoasetofenon ve fenilglioksim tek kristallerinde tuzaklanan iminoksi radikallerinin Elektron Spin Rezonansı (ESR) ile çalışılmıştır. Bu kristallerde tuzaklanan iminoksi radikalleri izomerik iminoksi radikalleri olduğu anlaşılmış, her iki kristalde de site yarılmaları gözlenmiştir. Her radikal için 14 N ve proton aşırı ince yapı(aş. i. y. ) ve g tensörlerinin esas eksen değerleri; radikaldeki çiftlenmemiş elektron yoğunluk dağılımı, azot üzerindeki spin yoğunluğunun s ve p karekterleri ile CNO bağ açıları hesaplanmıştır.
Electron Spin Resonance Of Iminoxy Radicals Trapped Isonitrosoacetophenone And Phenylglioxime Single Crystals
Abstract
The Electron Spin Resonance(ESR) of iminoxy radicals trapped in gamma-irradiated isonitroseacetophenone and phenylglioxime single crystals have been studied. It has been understood that iminoxy radicals trapped in these crystals is isomeric iminoxy radicals. In addition site splitings have been observed for both of crystals for every radicals, principal components of the g and hyperfine tensors of 14N and proton; distribution spin density of unpaired electron in radicals; s and p charecters of spin density on the nitrogen, and CNO bond angle have been calculated.
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Details
| Other ID | JA58YC66BG |
|---|---|
| Journal Section | Research Articles |
| Authors | |
| Publication Date | June 1, 2000 |
| Submission Date | June 1, 2000 |
| Published in Issue | Year 2000 Volume: 1 Issue: 16 |
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Journal Owner: On behalf of Selçuk University Faculty of Science, Rector Prof. Dr. Metin AKSOY
Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.
It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
In 1984, its name was changed to "S.Ü. Fen-Edeb. Fak. Fen Dergisi" and it was published under this name as of the 5th issue.
When the Faculty of Letters and Sciences was separated into the Faculty of Science and the Faculty of Letters with the decision of the Council of Ministers numbered 2008/4344 published in the Official Gazette dated 3 December 2008 and numbered 27073, it has been published as "Selcuk University Journal of Science Faculty" since 2009.
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