Abstract
Gama ışınları ile ışınlanan o-tolilaminoglioksim ve p-metilizonitroseasetofenon tek kristalleri ile anilinofenilglioksim, p-tolidinofenilglioksim, p-anisidinofenilglioksim, naftilaminofenilglioksim polikris-tallerinin oda sıcaklığında alınmış olan ESR spektrumları incelendi. Bu kristallerde tuzaklanan radikallerde çiftlenmemiş elektron spin yoğunluk dağılımları ve CNO bağ açıları hesaplandı. Polikristal oksim bileşiklerinde tuzaklanan radikallerin iminoksi radikalleri olduğu sonucuna varıldı.
Abstract
The electron spin resonance(ESR) spectra of gamma-irradiated o-tolylaminogliyoxime and p-methylisonitroseacethephenone single crystals, and anilinophenylglyoxime, ptolydinophenylglyoxime, naphthylaminophenylglyoxime polycrystals have been examined. Experiment were performed at room temperature. Observed triplet and dublet lines due to 14N and proton respectivly have been determined the spectra of single crystals. Spin density distiribition of unpaired electron and CNO bond angle have been calculated for the mentioned crystals. It has been understood that radicals trapped in polycrystals oxime compound is iminoxy radicals.
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Details
| Other ID | JA58YD37CU |
|---|---|
| Journal Section | Research Articles |
| Authors | |
| Publication Date | June 1, 2000 |
| Submission Date | June 1, 2000 |
| Published in Issue | Year 2000 Volume: 1 Issue: 16 |
Cite
Journal Owner: On behalf of Selçuk University Faculty of Science, Rector Prof. Dr. Metin AKSOY
Selcuk University Journal of Science Faculty accepts articles in Turkish and English with original results in basic sciences and other applied sciences. The journal may also include compilations containing current innovations.
It was first published in 1981 as "S.Ü. Fen-Edebiyat Fakültesi Dergisi" and was published under this name until 1984 (Number 1-4).
In 1984, its name was changed to "S.Ü. Fen-Edeb. Fak. Fen Dergisi" and it was published under this name as of the 5th issue.
When the Faculty of Letters and Sciences was separated into the Faculty of Science and the Faculty of Letters with the decision of the Council of Ministers numbered 2008/4344 published in the Official Gazette dated 3 December 2008 and numbered 27073, it has been published as "Selcuk University Journal of Science Faculty" since 2009.
It has been scanned in DergiPark since 2016.
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