Year 2019, Volume 45 , Issue 2, Pages 116 - 125 2019-10-30

Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi
Synthesis of Schiff Base Ligand Complex Compound and Investigation of Multiple Nuclear Fe(III)/Fe(II)/Fe(III) Metal Complex

Gülcan FERİÇOK [1] , Ziya Erdem KOÇ [2]


Bu çalışmada çıkış maddesi olarak 5-aminoisoftalik asit (5-Aminobenzen-1,3-dikarboksilik asit) kullanıldı. 5-Aminobenzen-1,3-dikarboksilik asit ile ferrosenkarboksialdehitin kondenzasyon reaksiyonundan [[(3,5-dikarboksifenil)imino]karbonil]ferrosen elde edildi. Sonra literatürden faydalanılarak salisilaldehit ve etilendiamin ile kondenzasyon reaksiyonu ile dört dişli salen ligandı elde edildi. Daha sonra susuz FeCl3 ile kompleksi elde edildi ve sonuç ürün NH4OH ile dimerleştirilerek Schiff bazı içerikli ligand kompleksimiz olan [Fe(salen)2O] elde edildi. Daha önce sentezlediğimiz Schiff bazı ligand kompleksine [Fe(salen)2O] ligand kompleksini ilave ederek -COOH gruplarının kullanılması ile çift oksijen köprülü multinükleer kompleksler elde edildi. Sonuç olarak, elde edilen ligandların ve komplekslerin FT-IR, 1H NMR, elementel analizi ve manyetik süsseptibilite ölçümleri ile yapıları aydınlatıldı.

In this study, 5-aminoisophthalic acid (5-aminobenzene-1,3-dicarboxylic acid) was used as the starting material. The condensation reaction of 5-aminobenzene-1,3-dicarboxylic acid and ferrosecarboxyaldehyde gave [[(3,5-dicarboxyphenyl)imino]carbonyl]ferrocene. Then the four-saline ligand was obtained by condensation reaction with salicylaldehyde and ethylenediamine using the literature. Then the complex with anhydrous FeCl3 was obtained and the resulting product was dimerized with NH4OH to obtain Schiff base-containing ligand complex [Fe(salen)2O]. By using the [Fe(salen)2O] ligand complex with the Schiff base ligand complex we synthesized previously, multinuclear complexes with double oxygen bridges were obtained by using the -COOH groups. As a result, FT-IR, elemental analysis, 1H NMR and magnetic susceptibility of ligands and complexes were investigated. 

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Primary Language tr
Subjects Science
Journal Section Articles
Authors

Author: Gülcan FERİÇOK
Institution: SELÇUK ÜNİVERSİTESİ
Country: Turkey


Author: Ziya Erdem KOÇ (Primary Author)
Institution: SELÇUK ÜNİVERSİTESİ
Country: Turkey


Dates

Publication Date : October 30, 2019

Bibtex @research article { sufefd578129, journal = {Selçuk Üniversitesi Fen Fakültesi Fen Dergisi}, issn = {}, eissn = {2458-9411}, address = {Selçuk Üniversitesi Fen Fakültesi Biyoloji Bölümü 3. Kat No: 324, Selçuklu, 42250, KONYA}, publisher = {Selcuk University}, year = {2019}, volume = {45}, pages = {116 - 125}, doi = {10.35238/sufefd.578129}, title = {Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi}, key = {cite}, author = {FERİÇOK, Gülcan and KOÇ, Ziya Erdem} }
APA FERİÇOK, G , KOÇ, Z . (2019). Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi , 45 (2) , 116-125 . DOI: 10.35238/sufefd.578129
MLA FERİÇOK, G , KOÇ, Z . "Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi". Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 45 (2019 ): 116-125 <https://dergipark.org.tr/en/pub/sufefd/issue/49939/578129>
Chicago FERİÇOK, G , KOÇ, Z . "Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi". Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 45 (2019 ): 116-125
RIS TY - JOUR T1 - Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi AU - Gülcan FERİÇOK , Ziya Erdem KOÇ Y1 - 2019 PY - 2019 N1 - doi: 10.35238/sufefd.578129 DO - 10.35238/sufefd.578129 T2 - Selçuk Üniversitesi Fen Fakültesi Fen Dergisi JF - Journal JO - JOR SP - 116 EP - 125 VL - 45 IS - 2 SN - -2458-9411 M3 - doi: 10.35238/sufefd.578129 UR - https://doi.org/10.35238/sufefd.578129 Y2 - 2019 ER -
EndNote %0 Selçuk Üniversitesi Fen Fakültesi Fen Dergisi Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi %A Gülcan FERİÇOK , Ziya Erdem KOÇ %T Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi %D 2019 %J Selçuk Üniversitesi Fen Fakültesi Fen Dergisi %P -2458-9411 %V 45 %N 2 %R doi: 10.35238/sufefd.578129 %U 10.35238/sufefd.578129
ISNAD FERİÇOK, Gülcan , KOÇ, Ziya Erdem . "Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi". Selçuk Üniversitesi Fen Fakültesi Fen Dergisi 45 / 2 (October 2019): 116-125 . https://doi.org/10.35238/sufefd.578129
AMA FERİÇOK G , KOÇ Z . Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi. sufefd. 2019; 45(2): 116-125.
Vancouver FERİÇOK G , KOÇ Z . Schiff Bazı Ligand Kompleks Bileşiğinin Sentezi ve Multinükleer Fe(III)/Fe(II)/Fe(III) Geçiş Metal Kompleksinin İncelenmesi. Selçuk Üniversitesi Fen Fakültesi Fen Dergisi. 2019; 45(2): 125-116.