GLASS FORMATION IN Li2O‐Pr2O3‐B2O3 SYSTEM

Year 2008, Volume: 23 Issue: 1, 51 - 54, 01.03.2008

Sh. A. Hamıdova F. A. Novruzova S. M. Agapashayeva

Abstract

By methods of physical‐chemical analysis (DTA, X‐ray diffraction, IR‐spectroscopy) phase‐ and glass formation in Li2O‐Pr2O3 B2O3 system was researched in zone, which is enriched with boric anhydride. According to the results of three quasi binary sections: Li2O⋅3B2O3− Pr2O3⋅3B2O3; Li2O⋅2B2O3-Pr2O3⋅3B2O3; Li2O⋅2B2O3Pr2O3⋅B2O3, as well as materials about glass formation in binary Li2O−B2O3‐ and Pr2O3−B2O3 systems the zone of glass formation and glass transition diagram of Li2O‐Pr2O3‐B2O3 was defined.

Keywords

Class formation, physical‐chemical analysis, Li2O‐Pr2O3‐B2O3 system

References

• Levin, E.M, 1966, Phys. Chem. Glass. 7, 90‐93.
• Hamidova Sh.A.; 2005,  The properties of glass formation in triple borate systems of Lithium and REE (Nd, Eu), Azerb. Chemistry journal, №1. p.147‐149.
• Hamidova Sh.A., 1995,  Glass formation in Li2O‐B2O3‐Dy2O3. Materials of scientific technical conference on inorganic and physical chemistry, dedicated to 60th anniversary of the Institute,Baku, p.21.
• Hamidova Sh.A. and    Kuli‐zade E.S., 2004, Glass formation in systems    Li2O‐Eu2O3 (V2O3)‐B2O   Dep.VINITI. № 3758‐1889, 1989,  p.1‐14.
• Hamidova    Sh.A. and Kuli‐zade E.S., 2003, Glass formation in systems Li2O‐B2O3‐Nd2O3 Thesis of abstracts of scientific conference dedicated to 95th anniversary of Academician M.F.Nagiyev. Baku, p.125
• Hamidova Sh.A., Novruzova F.A., and Aliyev I.I., 2006, Melting character of triple compound and triangulation in system Li2O⋅B2O3‐Pr2O3‐B2O3. Journal of Chemical Problems, №2, p.344‐346.
• Hamidova Sh.A. and Novruzova F.A., 2007,    Glass formation in system   Li2O‐Gd2O3‐B2O3, Azerb.Chemcial Journal,  №3, 52‐54.
• Poycon, K., 1969, IR‐spectra of adsorption of inorganic substances. M.:Mir. p.109.
• Shegolova,M.D., and  Berkovskiy E.Y., 1980, Chemical technology.,  №1, p.17‐19.