Research Article
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Year 2023, , 81 - 85, 28.12.2023
https://doi.org/10.46810/tdfd.1376717

Abstract

Ethical Statement

Çalışmamızın etik kurul beyanına gerek yoktur.

Supporting Institution

Fırat Üniversitesi

Project Number

FF.22.14

References

  • Soleymani Eil Bakhtiari S, Bakhsheshi-Rad HR, Karbasi S, Tavakoli M, Razzaghi M, Ismail AF, et al. Polymethyl Methacrylate-Based Bone Cements Containing Carbon Nanotubes and Graphene Oxide: An Overview of Physical, Mechanical, and Biological Properties. Polymers. 2020;12(7):1469.
  • Castillo-Aguirre A, Maldonado M. Preparation of Methacrylate-Based Polymers Modified with Chiral Resorcinarenes and Their Evaluation as Sorbents in Norepinephrine Microextraction. Polymers. 2019;11(9):1428.
  • Dabrowski ML, Stubenrauch C. Methacrylate-Based Polymer Foams with Controllable Pore Sizes and Controllable Polydispersities via Foamed Emulsion Templating. Advanced Engineering Materials. 2021;23(3):2001013.
  • Sengwa RJ, Choudhary S. Dielectric properties and fluctuating relaxation processes of poly(methyl methacrylate) based polymeric nanocomposite electrolytes. Journal of Physics and Chemistry of Solids. 2014;75(6):765-74.
  • Deka N, Bera A, Roy D, De P. Methyl Methacrylate-Based Copolymers: Recent Developments in the Areas of Transparent and Stretchable Active Matrices. ACS Omega. 2022;7(42):36929-44.
  • Roig A, Ramis X, De la Flor S, Serra À. Dual-cured thermosets from glycydil methacrylate obtained by epoxy-amine reaction and methacrylate homopolymerization. Reactive and Functional Polymers. 2021;159:104822.
  • Biryan F, Çalışkan E, Koran K. Kinetic analysis and dielectric properties of tyrosine-based tripeptide side groups carrying novel methacrylate polymers. Journal of Polymer Research. 2022;29(10):415.
  • Singh N, Agarwal P, Porwal J, Porwal SK. Evaluation of block copolymer and homopolymer of stearyl methacrylate as multifunctional additives for lubricating oil. Polymer Bulletin. 2023.
  • Arslan Z, Kiliclar HC, Yagci Y. Visible Light Induced Degradation of Poly(methyl methacrylate-co-methyl α-chloro acrylate) Copolymer at Ambient Temperature. Macromolecular Rapid Communications. 2023;44(9):2300066.
  • Baruah U, Dutta PP, Mohan B, Baruah SD, Saikia PJ. Thermal degradation study of poly(ethylene-co-methyl methacrylate) nanospheres synthesized via miniemulsion polymerization. Journal of Thermal Analysis and Calorimetry. 2023;148(13):6085-95.
  • Atiyah H, Hussein RD, Rashid MM, Powell J, Voisey KT. Thermal degradation and ablation energy of poly (methyl methacrylate). AIP Conference Proceedings. 2023;2806(1).
  • Hu Z, Cai T, Chi C. Thermoresponsive oligo(ethylene glycol)-methacrylate-based polymers and microgels. Soft Matter. 2010;6(10):2115-23.
  • Biryan F, Çelik H, Çalışkan E, Koran K. Molecular design of ferrocene-based novel polymer using click chemistry via chemoselective polymerization and investigation of electrical properties as organic Schottky diode. European Polymer Journal. 2023;197:112321.
  • Fonseca AC, Lima MS, Sousa AF, Silvestre AJ, Coelho JFJ, Serra AC. Cinnamic acid derivatives as promising building blocks for advanced polymers: synthesis, properties and applications. Polymer Chemistry. 2019;10(14):1696-723.
  • Ruwizhi N, Aderibigbe BA. Cinnamic Acid Derivatives and Their Biological Efficacy. International Journal of Molecular Sciences. 2020;21(16):5712.

Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative

Year 2023, , 81 - 85, 28.12.2023
https://doi.org/10.46810/tdfd.1376717

Abstract

The study investigates the thermal, kinetic, and dielectric properties of a novel methacrylate polymer synthesized from a naphthol-containing cinnamic acid derivative. Notably, the glass transition temperature (Tg) of the polymer, a crucial parameter for amorphous polymers, was found to be significantly higher than traditional methacrylate polymers, owing to the presence of the naphthol group within the polymer structure. The research also delves into the thermal stability and activation energy of the polymer using thermal analysis techniques. Additionally, the dielectric properties of the homopolymer were explored with a focus on the temperature-dependent changes in the dielectric constant and its behavior with varying frequencies.

Project Number

FF.22.14

References

  • Soleymani Eil Bakhtiari S, Bakhsheshi-Rad HR, Karbasi S, Tavakoli M, Razzaghi M, Ismail AF, et al. Polymethyl Methacrylate-Based Bone Cements Containing Carbon Nanotubes and Graphene Oxide: An Overview of Physical, Mechanical, and Biological Properties. Polymers. 2020;12(7):1469.
  • Castillo-Aguirre A, Maldonado M. Preparation of Methacrylate-Based Polymers Modified with Chiral Resorcinarenes and Their Evaluation as Sorbents in Norepinephrine Microextraction. Polymers. 2019;11(9):1428.
  • Dabrowski ML, Stubenrauch C. Methacrylate-Based Polymer Foams with Controllable Pore Sizes and Controllable Polydispersities via Foamed Emulsion Templating. Advanced Engineering Materials. 2021;23(3):2001013.
  • Sengwa RJ, Choudhary S. Dielectric properties and fluctuating relaxation processes of poly(methyl methacrylate) based polymeric nanocomposite electrolytes. Journal of Physics and Chemistry of Solids. 2014;75(6):765-74.
  • Deka N, Bera A, Roy D, De P. Methyl Methacrylate-Based Copolymers: Recent Developments in the Areas of Transparent and Stretchable Active Matrices. ACS Omega. 2022;7(42):36929-44.
  • Roig A, Ramis X, De la Flor S, Serra À. Dual-cured thermosets from glycydil methacrylate obtained by epoxy-amine reaction and methacrylate homopolymerization. Reactive and Functional Polymers. 2021;159:104822.
  • Biryan F, Çalışkan E, Koran K. Kinetic analysis and dielectric properties of tyrosine-based tripeptide side groups carrying novel methacrylate polymers. Journal of Polymer Research. 2022;29(10):415.
  • Singh N, Agarwal P, Porwal J, Porwal SK. Evaluation of block copolymer and homopolymer of stearyl methacrylate as multifunctional additives for lubricating oil. Polymer Bulletin. 2023.
  • Arslan Z, Kiliclar HC, Yagci Y. Visible Light Induced Degradation of Poly(methyl methacrylate-co-methyl α-chloro acrylate) Copolymer at Ambient Temperature. Macromolecular Rapid Communications. 2023;44(9):2300066.
  • Baruah U, Dutta PP, Mohan B, Baruah SD, Saikia PJ. Thermal degradation study of poly(ethylene-co-methyl methacrylate) nanospheres synthesized via miniemulsion polymerization. Journal of Thermal Analysis and Calorimetry. 2023;148(13):6085-95.
  • Atiyah H, Hussein RD, Rashid MM, Powell J, Voisey KT. Thermal degradation and ablation energy of poly (methyl methacrylate). AIP Conference Proceedings. 2023;2806(1).
  • Hu Z, Cai T, Chi C. Thermoresponsive oligo(ethylene glycol)-methacrylate-based polymers and microgels. Soft Matter. 2010;6(10):2115-23.
  • Biryan F, Çelik H, Çalışkan E, Koran K. Molecular design of ferrocene-based novel polymer using click chemistry via chemoselective polymerization and investigation of electrical properties as organic Schottky diode. European Polymer Journal. 2023;197:112321.
  • Fonseca AC, Lima MS, Sousa AF, Silvestre AJ, Coelho JFJ, Serra AC. Cinnamic acid derivatives as promising building blocks for advanced polymers: synthesis, properties and applications. Polymer Chemistry. 2019;10(14):1696-723.
  • Ruwizhi N, Aderibigbe BA. Cinnamic Acid Derivatives and Their Biological Efficacy. International Journal of Molecular Sciences. 2020;21(16):5712.
There are 15 citations in total.

Details

Primary Language English
Subjects Physical Chemistry (Other)
Journal Section Articles
Authors

Eray Çalışkan 0000-0003-2399-4100

Fatih Biryan 0000-0001-9198-3329

Kenan Koran 0000-0002-2218-7211

Project Number FF.22.14
Early Pub Date December 28, 2023
Publication Date December 28, 2023
Submission Date October 16, 2023
Acceptance Date November 30, 2023
Published in Issue Year 2023

Cite

APA Çalışkan, E., Biryan, F., & Koran, K. (2023). Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative. Türk Doğa Ve Fen Dergisi, 12(4), 81-85. https://doi.org/10.46810/tdfd.1376717
AMA Çalışkan E, Biryan F, Koran K. Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative. TDFD. December 2023;12(4):81-85. doi:10.46810/tdfd.1376717
Chicago Çalışkan, Eray, Fatih Biryan, and Kenan Koran. “Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative”. Türk Doğa Ve Fen Dergisi 12, no. 4 (December 2023): 81-85. https://doi.org/10.46810/tdfd.1376717.
EndNote Çalışkan E, Biryan F, Koran K (December 1, 2023) Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative. Türk Doğa ve Fen Dergisi 12 4 81–85.
IEEE E. Çalışkan, F. Biryan, and K. Koran, “Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative”, TDFD, vol. 12, no. 4, pp. 81–85, 2023, doi: 10.46810/tdfd.1376717.
ISNAD Çalışkan, Eray et al. “Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative”. Türk Doğa ve Fen Dergisi 12/4 (December 2023), 81-85. https://doi.org/10.46810/tdfd.1376717.
JAMA Çalışkan E, Biryan F, Koran K. Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative. TDFD. 2023;12:81–85.
MLA Çalışkan, Eray et al. “Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative”. Türk Doğa Ve Fen Dergisi, vol. 12, no. 4, 2023, pp. 81-85, doi:10.46810/tdfd.1376717.
Vancouver Çalışkan E, Biryan F, Koran K. Investigation of the Thermal, Kinetic, and Dielectric Properties of a Novel Methacrylate Polymer Derived from Naphthol-Containing Cinnamic Acid Derivative. TDFD. 2023;12(4):81-5.