Investigation of Inhibition Performance of Phenytoin for Mild Steel Protection in HCl Solution: Electrochemical and Quantum Theoretical Approaches

Year 2022, Volume: 11 Issue: 4, 70 - 78, 28.12.2022

Hüseyin Nazlıgül , Emre Güllü , Mehmet Erman Mert , Başak Doğru Mert

https://doi.org/10.46810/tdfd.1180712

Cited By: 2

Abstract

In this study, the application potential of the expired "Epdantoin" drug which includes phenytoin (EP) as the corrosion inhibitor was investigated. For this purpose, the electrochemical impedance spectroscopy measurements and polarization curves were obtained for 168 hours immersion period in 0.5 M HCl in the absence and presence of various concentration of EP. The experimental results were compared with quantum theoretical parameters in order to present adsorption behavior of EP. The adsorption equilibrium constant and Gibbs free energy were calculated as 5000 M-1 and -31,05 kj mol-1, respectively. The calculated HOMO and LUMO values were -6.67 eV and -0.72 eV, respectively. Results indicated that EP is a convenient candidate of corrosion inhibitor for mild steel in HCl medium.

Keywords

Corrosion, Density functional theory, Mild steel, Phenytoin

References

• Akbarzadeh S, Ramezanzadeh M, Ramezanzadeh B, Bahlakeh G. A green assisted route for the fabrication of a high-efficiency self-healing anti-corrosion coating through graphene oxide nanoplatform reduction by Tamarindus indiaca extract. Journal of Hazardous Materials. 2020;390:122147.
• Lgaz H, Salghi R, Masroor S, Kim SH, Kwon C, Kim SY, et al. Assessing corrosion inhibition characteristics of hydrazone derivatives on mild steel in HCl: Insights from electronic-scale DFT and atomic-scale molecular dynamics. Journal of Molecular Liquids. 2020;308:112998.
• Zhang J, Li W, Zuo X, Chen Y, Luo W, Zhang Y, et al. Combining experiment and theory researches to insight into anti-corrosion nature of a novel thiazole derivatives. Journal of the Taiwan Institute of Chemical Engineers. 2021;122:190–200.
• Zhang J, Li W, Zuo X, Chen Y, Luo W, Zhang Y, et al. Combining experiment and theory researches to insight into anti-corrosion nature of a novel thiazole derivatives. Journal of the Taiwan Institute of Chemical Engineers. 2021;122:190–200.
• Sorkh Kaman Zadeh A, Shahidi Zandi M, Kazemipour M. Corrosion protection of carbon steel in acidic media by expired bupropion drug; experimental and theoretical study. Journal of the Indian Chemical Society. 2022;99(7):100522.
• Azzaoui K, Mejdoubi E, Jodeh S, Lamhamdi A, Rodriguez-Castellón E, Algarra M, et al. Eco friendly green inhibitor Gum Arabic (GA) for the corrosion control of mild steel in hydrochloric acid medium. Corrosion Science. 2017;129:70–81.
• Shamnamol GK, Sreelakshmi KP, Ajith G, Jacob JM. Effective utilization of drugs as green corrosion inhibitor – A review. In Puducherry, India; 2020 [cited 2022 Sep 22]. p. 070006. Available from: http://aip.scitation.org/doi/abs/10.1063/5.0005931
• Nayak P, Kumari P P, Rao SA. Electrochemical approach to interfacial adsorption and inhibitory performance of (2E)-2- [(IH-Imidazole 2yl) methylidene] Hydrazine1-carbothioamide for corrosion mitigation. Chemical Data Collections. 2022;38:100826.
• Srivastava M, Tiwari P, Srivastava SK, Prakash R, Ji G. Electrochemical investigation of Irbesartan drug molecules as an inhibitor of mild steel corrosion in 1 M HCl and 0.5 M H 2 SO 4 solutions. Journal of Molecular Liquids. 2017;236:184–97.
• Alamry KA, Aslam R, Khan A, Hussein MA, Tashkandi NY. Evaluation of corrosion inhibition performance of thiazolidine-2,4-diones and its amino derivative: Gravimetric, electrochemical, spectroscopic, and surface morphological studies. Process Safety and Environmental Protection. 2022;159:178–97.
• Rodrigues FA de S, Gonçalves YMH, Horta BAC, Santos I da S, Silva BV, D’Elia E. Experimental and theoretical studies of isonitrosoacetanilides derivatives as corrosion inhibitors for mild steel in 1 mol L−1 HCl. Journal of Molecular Structure. 2021;1245:131256.
• Salcı A, Yüksel H, Solmaz R. Experimental studies on the corrosion inhibition performance of 2-(2-aminophenyl)benzimidazole for mild steel protection in HCl solution. Journal of the Taiwan Institute of Chemical Engineers. 2022;134:104349.
• Oubaaqa M, Ouakki M, Rbaa M, Abousalem AS, Maatallah M, Benhiba F, et al. Insight into the corrosion inhibition of new amino-acids as efficient inhibitors for mild steel in HCl solution: Experimental studies and theoretical calculations. Journal of Molecular Liquids. 2021;334:116520.
• Rahal C, Masmoudi M, Abdelhedi R, Sabot R, Jeannin M, Bouaziz M, et al. Olive leaf extract as natural corrosion inhibitor for pure copper in 0.5 M NaCl solution: A study by voltammetry around OCP. Journal of Electroanalytical Chemistry. 2016;769:53–61.
• Sharma S, Kumar A. Recent advances in metallic corrosion inhibition: A review. Journal of Molecular Liquids. 2021;322:114862.
• Gholamhosseinzadeh MR, Aghaie H, Zandi MS, Giahi M. Rosuvastatin drug as a green and effective inhibitor for corrosion of mild steel in HCl and H2SO4 solutions. Journal of Materials Research and Technology. 2019;8(6):5314–24.
• Abd El-Lateef HM, Sayed AR, Shalabi K. Studying the effect of two isomer forms thiazole and thiadiazine on the inhibition of acidic chloride-induced steel corrosion: Empirical and Computer simulation explorations. Journal of Molecular Liquids. 2022;356:119044.
• Sundaram RG, Vengatesh G, Sundaravadivelu M. Surface morphological and quantum chemical studies of some expired drug molecules as potential corrosion inhibitors for mild steel in chloride medium. Surfaces and Interfaces. 2021;22:100841.
• Wen J, Zhang X, Chen J, Liu T, Zhou Y, Li L. Synthesis of 1, 4, 7-triazaheptane derivative and its corrosion inhibition for mild steel in the hydrochloric medium. Journal of Industrial and Engineering Chemistry. 2022;107:333–45.
• Şahin EA, Dursun YA, Tunç M, Geçibesler İH, Solmaz R. Bakırın asidik ortamdaki korozyonuna hurma (Phoenix dactylifera) çekirdeğinin inhibisyon etkisinin incelenmesi. Turkish Journal of Nature Science. 2021;10(2):258-264.
• Arrousse N, Salim R, Kaddouri Y, zarrouk A, Zahri D, Hajjaji FE, et al. The inhibition behavior of two pyrimidine-pyrazole derivatives against corrosion in hydrochloric solution: Experimental, surface analysis and in silico approach studies. Arabian Journal of Chemistry. 2020;13(7):5949–65.
• Top MN, Özbey S, Soruşbay B, Gülsoy HÖ. Investigation of microstructural, mechanical and corrosion properties of Cu-10Sn bronze parts produced by selective laser melting. Turkish Journal of Nature Science. 2022;11(2):76-81.
• Khadraoui A, Khelifa A, Hachama K, Mehdaoui R. Thymus algeriensis extract as a new eco-friendly corrosion inhibitor for 2024 aluminium alloy in 1M HCl medium. Journal of Molecular Liquids. 2016;214:293–7.