Effect of Carbon Fiber Surface Modification on Properties of Carbon Fiber and Carbon Fiber Reinforced Composite Materials
Year 2019,
Volume: 26 Issue: 113, 25 - 32, 26.03.2019
Lütfiye Altay
Mehmet Sarıkanat
Abstract
One of the most important factors affecting the properties of carbon fiber reinforced composite materials is the interface bond strength between the carbon fiber / polymer. Surface treatment and sizing applied to carbon fiber play an important role in improving the interface properties. In this study, carbon fibers are subjected to chemical surface treatment and silane modification before epoxy prepregs are produced. Then, the properties of the composite plates obtained from prepregs were investigated by various characterization methods. The chemical treatment applied to the carbon fiber surface increased the oxygen containing functional groups on the fiber surface to form additional binding sites with epoxy. The silane modification significantly increased the processability of the fibers and fiber/ polymer interface adhesion by forming a protective coating on the fiber surface.
References
- Mallick PK, (2007), Fiber-reinforced composites: materials, manufacturing, and design,CRC press.
- Sharma M, S Gao, E Mäder, H Sharma, LY Wei, J Bijwe, (2014), Carbon fiber surfaces and composite interphases, Composites Science and Technology, 102, 35-50.
- Fujimaki H, F Kodama, R Takabe, K Asano, K Seguchi. Process for the surface treatment of carbon fibers. Google Patents; 1977.
- Nohara LB, G Petraconi Filho, EL Nohara, MU Kleinke, MC Rezende, (2005), Evaluation of carbon fiber surface treated by chemical and cold plasma processes, Materials Research, 8(3), 281-6.
- Zielke U, K Hüttinger, W Hoffman, (1996), Surface-oxidized carbon fibers: I. Surface structure and chemistry, Carbon, 34(8), 983-98.
- Sellitti C, J Koenig, H Ishida, (1990), Surface characterization of graphitized carbon fibers by attenuated total reflection Fourier transform infrared spectroscopy, Carbon, 28(1), 221-8.
- Wu Z, CU Pittman Jr, SD Gardner, (1995), Nitric acid oxidation of carbon fibers and the effects of subsequent treatment in refluxing aqueous NaOH, Carbon, 33(5), 597-605.
- Tiwari S, J Bijwe, S Panier, (2011), Tribological studies on polyetherimide composites based on carbon fabric with optimized oxidation treatment, Wear, 271(9-10), 2252-60.
- Jang J, H Yang, (2000), The effect of surface treatment on the performance improvement of carbon fiber/polybenzoxazine composites, Journal of materials science, 35(9), 2297-303.
- Yang J, J Xiao, J Zeng, L Bian, C Peng, F Yang, (2013), Matrix modification with silane coupling agent for carbon fiber reinforced epoxy composites, Fibers and Polymers, 14(5), 759-66.
- Yue Z, W Jiang, L Wang, S Gardner, C Pittman Jr, (1999), Surface characterization of electrochemically oxidized carbon fibers, Carbon, 37(11), 1785-96.
- Wu Q, M Li, Y Gu, S Wang, L Yao, Z Zhang, (2016), Effect of sizing on interfacial adhesion of commercial high strength carbon fiber‐reinforced resin composites, Polymer Composites, 37(1), 254-61.
- Atas C, Y Akgun, O Dagdelen, BM Icten, M Sarikanat, (2011), An experimental investigation on the low velocity impact response of composite plates repaired by VARIM and hand lay-up processes, Composite Structures, 93(3), 1178-86.
- Sever K, M Sarikanat, Y Seki, G Erkan, ÜH Erdoğan, S Erden, (2012), Surface treatments of jute fabric: The influence of surface characteristics on jute fabrics and mechanical properties of jute/polyester composites, Industrial Crops and Products, 35(1), 22-30.
- Song W, A Gu, G Liang, L Yuan, (2011), Effect of the surface roughness on interfacial properties of carbon fibers reinforced epoxy resin composites, Applied Surface Science, 257(9), 4069-74.
- Han SH, HJ Oh, SS Kim, (2014), Evaluation of fiber surface treatment on the interfacial behavior of carbon fiber-reinforced polypropylene composites, Composites Part B-Engineering, 60, 98-105.
- Kim H-I, W-K Choi, S-J Kang, YS Lee, JH Han, B-J Kim, (2016), Mechanical interfacial adhesion of carbon fibers-reinforced polarized-polypropylene matrix composites: Effects of silane coupling agents, Carbon Lett., 17, 79-84.
- He J, Y Huang, (2007), Effect of silane‐coupling agents on interfacial properties of CF/PI composites, Journal of Applied Polymer Science, 106(4), 2231-7.
- An F, C Lu, Y Li, J Guo, X Lu, H Lu, et al., (2012), Preparation and characterization of carbon nanotube-hybridized carbon fiber to reinforce epoxy composite, Materials & Design, 33, 197-202.
- Jiang S, QF Li, YH Zhao, JW Wang, MQ Kang, (2015), Effect of surface silanization of carbon fiber on mechanical properties of carbon fiber reinforced polyurethane composites, Composites Science and Technology, 110, 87-94.
- Ma QS, YZ Gu, M Li, SK Wang, ZG Zhang, (2016), Effects of surface treating methods of high-strength carbon fibers on interfacial properties of epoxy resin matrix composite, Applied Surface Science, 379, 199-205.
Karbon Lif Yüzey Modifikasyonunun Karbon Lif ve Karbon Lif Takviyeli Kompozit Malzemelerin Özelliklerine Etkilerinin İncelenmesi
Year 2019,
Volume: 26 Issue: 113, 25 - 32, 26.03.2019
Lütfiye Altay
Mehmet Sarıkanat
Abstract
Karbon lif takviyeli kompozit malzemelerin özelliklerini etkileyen en önemli etkenlerden biri karbon lif/polimer arasındaki arayüz bağlanma dayanımıdır. Karbon life uygulanan yüzey modifikasyonları arayüz özelliklerinin iyileşmesinde önemli rol oynamaktadır. Bu çalışmada ilk olarak karbon lifler kimyasal oksidasyon işlemi ve silan modifikasyonundan geçirilerek sonrasında karbon lif takviyeli epoksi tabanlı prepregler üretilmiştir. Daha sonra prepreglerden elde edilen kompozit plakaların özellikleri çeşitli karakterizasyon yöntemleri ile incelenmiştir. Karbon lif yüzeyine uygulanan kimyasal işlem lif yüzeyindeki oksijen içeren fonksiyonel grupları arttırarak epoksi ile ek bağlanma bölgeleri oluşturmuştur. Silan modifikasyonu ise lif yüzeyinde koruyucu bir kaplama oluşturarak lifin işlenebilirliğini ve lif/polimer yapışma özelliğini önemli ölçüde arttırmıştır.
References
- Mallick PK, (2007), Fiber-reinforced composites: materials, manufacturing, and design,CRC press.
- Sharma M, S Gao, E Mäder, H Sharma, LY Wei, J Bijwe, (2014), Carbon fiber surfaces and composite interphases, Composites Science and Technology, 102, 35-50.
- Fujimaki H, F Kodama, R Takabe, K Asano, K Seguchi. Process for the surface treatment of carbon fibers. Google Patents; 1977.
- Nohara LB, G Petraconi Filho, EL Nohara, MU Kleinke, MC Rezende, (2005), Evaluation of carbon fiber surface treated by chemical and cold plasma processes, Materials Research, 8(3), 281-6.
- Zielke U, K Hüttinger, W Hoffman, (1996), Surface-oxidized carbon fibers: I. Surface structure and chemistry, Carbon, 34(8), 983-98.
- Sellitti C, J Koenig, H Ishida, (1990), Surface characterization of graphitized carbon fibers by attenuated total reflection Fourier transform infrared spectroscopy, Carbon, 28(1), 221-8.
- Wu Z, CU Pittman Jr, SD Gardner, (1995), Nitric acid oxidation of carbon fibers and the effects of subsequent treatment in refluxing aqueous NaOH, Carbon, 33(5), 597-605.
- Tiwari S, J Bijwe, S Panier, (2011), Tribological studies on polyetherimide composites based on carbon fabric with optimized oxidation treatment, Wear, 271(9-10), 2252-60.
- Jang J, H Yang, (2000), The effect of surface treatment on the performance improvement of carbon fiber/polybenzoxazine composites, Journal of materials science, 35(9), 2297-303.
- Yang J, J Xiao, J Zeng, L Bian, C Peng, F Yang, (2013), Matrix modification with silane coupling agent for carbon fiber reinforced epoxy composites, Fibers and Polymers, 14(5), 759-66.
- Yue Z, W Jiang, L Wang, S Gardner, C Pittman Jr, (1999), Surface characterization of electrochemically oxidized carbon fibers, Carbon, 37(11), 1785-96.
- Wu Q, M Li, Y Gu, S Wang, L Yao, Z Zhang, (2016), Effect of sizing on interfacial adhesion of commercial high strength carbon fiber‐reinforced resin composites, Polymer Composites, 37(1), 254-61.
- Atas C, Y Akgun, O Dagdelen, BM Icten, M Sarikanat, (2011), An experimental investigation on the low velocity impact response of composite plates repaired by VARIM and hand lay-up processes, Composite Structures, 93(3), 1178-86.
- Sever K, M Sarikanat, Y Seki, G Erkan, ÜH Erdoğan, S Erden, (2012), Surface treatments of jute fabric: The influence of surface characteristics on jute fabrics and mechanical properties of jute/polyester composites, Industrial Crops and Products, 35(1), 22-30.
- Song W, A Gu, G Liang, L Yuan, (2011), Effect of the surface roughness on interfacial properties of carbon fibers reinforced epoxy resin composites, Applied Surface Science, 257(9), 4069-74.
- Han SH, HJ Oh, SS Kim, (2014), Evaluation of fiber surface treatment on the interfacial behavior of carbon fiber-reinforced polypropylene composites, Composites Part B-Engineering, 60, 98-105.
- Kim H-I, W-K Choi, S-J Kang, YS Lee, JH Han, B-J Kim, (2016), Mechanical interfacial adhesion of carbon fibers-reinforced polarized-polypropylene matrix composites: Effects of silane coupling agents, Carbon Lett., 17, 79-84.
- He J, Y Huang, (2007), Effect of silane‐coupling agents on interfacial properties of CF/PI composites, Journal of Applied Polymer Science, 106(4), 2231-7.
- An F, C Lu, Y Li, J Guo, X Lu, H Lu, et al., (2012), Preparation and characterization of carbon nanotube-hybridized carbon fiber to reinforce epoxy composite, Materials & Design, 33, 197-202.
- Jiang S, QF Li, YH Zhao, JW Wang, MQ Kang, (2015), Effect of surface silanization of carbon fiber on mechanical properties of carbon fiber reinforced polyurethane composites, Composites Science and Technology, 110, 87-94.
- Ma QS, YZ Gu, M Li, SK Wang, ZG Zhang, (2016), Effects of surface treating methods of high-strength carbon fibers on interfacial properties of epoxy resin matrix composite, Applied Surface Science, 379, 199-205.