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The Effect of Amphoteric Polymers on Dyestuff Consumption

Year 2024, Volume: 34 Issue: 2, 110 - 116
https://doi.org/10.32710/tekstilvekonfeksiyon.1066549

Abstract

In recent years, the importance and use of wet-white tanning technology have increased due to the increase in environmental and health concerns. On the other hand, this technology still has problems related with fixation of dyestuff and fatliquoring agents during wet-end processes. In this study, the effect of the use of different commercial amphoteric retanning agents in different ratios on dyestuff consumption was investigated. For this purpose, amphoteric polymers were used at the beginning of dyeing process of syntan tanned leathers and the concentrations of remaining dyestuff after the process have been measured using UV-Vis Spectrophotometer for each trial. From the results it was concluded that the use of amphoteric polymers in retanning of wet-white tanned leathers significantly decreased the remaining dyestuff in the floats. Also, the physical and mechanical properties of the final leather were not adversely affected up to the use of 6 wt% the amphoteric polymer.

Thanks

This paper was an outcome of a bachelor thesis entitled “Investigations on the Effect of Amphoteric Polymers Used in Retanning Process on Dyestuff Consumption” published in 2021 at Ege University, Faculty of Engineering, Leather Engineering Department, İzmir-Turkey. The results have been partially presented in IAFLI 2021- VI. International Leather Enginnering Congress on 25-26 November, İzmir-Turkey, as oral communication. The authors wish to thank “Kepler Deri Teknolojisi San. ve Tic. A.Ş., İstanbul, TURKEY” and ACADEMICHEM Kimya ARGE San. Tic. Ltd. Şti. for their support to the study by donation some of the necessary chemicals.

References

  • Jin L, Wang Y, Zhu D, Xu Q. 2011. Effect of an Amphoteric Acrylic Retanning Agent on the Physical Properties of the Resultant Leather. Advanced Materials Research 284-286, 1925-1928.
  • Xu W, Chai X, Zhao G, Li J, Wang X. 2019. Preparation of Reactive Amphoteric Polyurethane with Multialdehyde Groups and Its Use as a Retanning Agent for Chrome-free Tanned Leather. Journal of Aplied Polymer Science 136, 47940.
  • Kılıcarislan Ozkan C. 2018. Investigation of Possible Use of Starch as Tanning Agent in Leather Industry (Doctoral dissertation), Retrieved from T.C. Council of Higher Education Thesis Center. (498550)
  • Kılıcarislan Ozkan C, Ozgunay H, Akat H. 2019. Possible Use of Corn Starch as Tanning Agent in Leather Industry: Controlled (Gradual) Degradation by H2O2. International Journal of Biological Macromolecules 122, 610-618.
  • Shi J, Zhang R, Mi Z, Lyu S, Ma. J. 2020. Engineering a Sustainable Chrome-Free Leather Processing Based on Novel Lightfast Wet-White Tanning System Towards Eco-Leather Manufacture. Journal of Cleaner Production 282, 124504.
  • Dilek Y. 2017. Improving the Properties of Wet-White Tanned Leather (Master’s Thesis). Retrieved from T.C. Council of Higher Education Thesis Center. (479732)
  • Hao D, Wang X, Liu X, Zhu X, Sun S, Li J, Yue O. 2020. A Novel Eco-friendly Imidazole Ionic Liquids Based Amphoteric Polymers for High Performance Fatliquoring in Chromium-Free Tanned Leather Production. Journal of Hazardous Materials 399, 123048.
  • Canudas M, Menna N, Torreles A, de Pablo J, Morera JM. Modified Polyacrylates as a New Leather Rettanning Agents. IULTCS Congress 25-28 June 2019. Dresden, Germany.
  • Jia L, Ma J, Gao D, Lyu B, Zhang J. 2016. Application of an Amphoteric Polymer for Leather Pickling to Obtain a Less Total Dissolved Solids Residual Process. Journal of Cleaner Production 139, 788-795.
  • Liu X, Yue O, Wang X, Hou M, Zheng M, Jiang H. 2020. Preparation and Application of a Novel Biomass-Based Amphoteric Retanning Agent with the Function of Reducing Free Formaldehyde in Leather. Journal of Cleaner Production 265, 121796.
  • TS EN ISO 3380. Leather - Physical and mechanical tests - Determination of shrinkage temperature up to 100 °C. Turkish Standard Institution, 15p.
  • TS EN ISO 3376. Leather - Physical and mechanical tests – Determination of tensile strength and percentage elongation. Turkish Standard Institution, 18p.
  • TS EN ISO 3377-2. Leather - Physical and mechanical tests - Determination of tear load - Part 2: Double edge tear. Turkish Standard Institution, 11p.
  • Omur S. 2015. Determinaton of Light Fastness Property of Leathers Tanned with Different Vegetable Tannins and Investigating the Possibility of Increasing the Light Fastness (Doctoral dissertation). Retrieved from T.C. Council of Higher Education Thesis Center. (409979)
Year 2024, Volume: 34 Issue: 2, 110 - 116
https://doi.org/10.32710/tekstilvekonfeksiyon.1066549

Abstract

References

  • Jin L, Wang Y, Zhu D, Xu Q. 2011. Effect of an Amphoteric Acrylic Retanning Agent on the Physical Properties of the Resultant Leather. Advanced Materials Research 284-286, 1925-1928.
  • Xu W, Chai X, Zhao G, Li J, Wang X. 2019. Preparation of Reactive Amphoteric Polyurethane with Multialdehyde Groups and Its Use as a Retanning Agent for Chrome-free Tanned Leather. Journal of Aplied Polymer Science 136, 47940.
  • Kılıcarislan Ozkan C. 2018. Investigation of Possible Use of Starch as Tanning Agent in Leather Industry (Doctoral dissertation), Retrieved from T.C. Council of Higher Education Thesis Center. (498550)
  • Kılıcarislan Ozkan C, Ozgunay H, Akat H. 2019. Possible Use of Corn Starch as Tanning Agent in Leather Industry: Controlled (Gradual) Degradation by H2O2. International Journal of Biological Macromolecules 122, 610-618.
  • Shi J, Zhang R, Mi Z, Lyu S, Ma. J. 2020. Engineering a Sustainable Chrome-Free Leather Processing Based on Novel Lightfast Wet-White Tanning System Towards Eco-Leather Manufacture. Journal of Cleaner Production 282, 124504.
  • Dilek Y. 2017. Improving the Properties of Wet-White Tanned Leather (Master’s Thesis). Retrieved from T.C. Council of Higher Education Thesis Center. (479732)
  • Hao D, Wang X, Liu X, Zhu X, Sun S, Li J, Yue O. 2020. A Novel Eco-friendly Imidazole Ionic Liquids Based Amphoteric Polymers for High Performance Fatliquoring in Chromium-Free Tanned Leather Production. Journal of Hazardous Materials 399, 123048.
  • Canudas M, Menna N, Torreles A, de Pablo J, Morera JM. Modified Polyacrylates as a New Leather Rettanning Agents. IULTCS Congress 25-28 June 2019. Dresden, Germany.
  • Jia L, Ma J, Gao D, Lyu B, Zhang J. 2016. Application of an Amphoteric Polymer for Leather Pickling to Obtain a Less Total Dissolved Solids Residual Process. Journal of Cleaner Production 139, 788-795.
  • Liu X, Yue O, Wang X, Hou M, Zheng M, Jiang H. 2020. Preparation and Application of a Novel Biomass-Based Amphoteric Retanning Agent with the Function of Reducing Free Formaldehyde in Leather. Journal of Cleaner Production 265, 121796.
  • TS EN ISO 3380. Leather - Physical and mechanical tests - Determination of shrinkage temperature up to 100 °C. Turkish Standard Institution, 15p.
  • TS EN ISO 3376. Leather - Physical and mechanical tests – Determination of tensile strength and percentage elongation. Turkish Standard Institution, 18p.
  • TS EN ISO 3377-2. Leather - Physical and mechanical tests - Determination of tear load - Part 2: Double edge tear. Turkish Standard Institution, 11p.
  • Omur S. 2015. Determinaton of Light Fastness Property of Leathers Tanned with Different Vegetable Tannins and Investigating the Possibility of Increasing the Light Fastness (Doctoral dissertation). Retrieved from T.C. Council of Higher Education Thesis Center. (409979)
There are 14 citations in total.

Details

Primary Language English
Subjects Wearable Materials
Journal Section Articles
Authors

Müge Deveci This is me 0000-0001-6152-1203

Onur Yilmaz 0000-0002-0992-5937

Early Pub Date July 1, 2024
Publication Date
Submission Date February 1, 2022
Acceptance Date March 24, 2023
Published in Issue Year 2024 Volume: 34 Issue: 2

Cite

APA Deveci, M., & Yilmaz, O. (2024). The Effect of Amphoteric Polymers on Dyestuff Consumption. Textile and Apparel, 34(2), 110-116. https://doi.org/10.32710/tekstilvekonfeksiyon.1066549

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