Kızılçam kozalağından elde edilen biyokömürün absorban olarak kullanımı: Sulu çözeltiden kongo kırmızısı giderimi

Abstract

Anyonik bir boyar madde olan Kongo Kırmızısı (KR) günümüzde endüstrinin birçok alanında kullanılmaktadır. Anyonik ve katyonik boyar maddelerin temizlenmeden su kaynakları ile temas etmesi ciddi çevre sorunlarına yol açmaktadır. Bu çalışmada ülkemizde geniş yayılış gösteren kızılçam (Pinus brutia Ten.) kozalağı biyokömür (PBKB) haline getirilmiş ve sulu çözeltilerden KR gideriminde kullanılmıştır. Elde edilen sonuçlarda, PBKB ile KR gideriminin Langmuir adsorpsiyon izotermine uygun olduğu (R2=0.975) ve maksimum adsorpsiyon kapasitesi değerinin 14.124 mg/g olduğu bulunmuştur. Yapılan kinetik ve termodinamik hesaplamalar sonucunda adsorpsiyon sürecinin endotermik olduğu ve pseudo-second-order (PSO) üzerinden yürüdüğü sonucuna ulaşılmıştır. PBKB, KR ile temas etmeden önce ve temas ettikten sonra SEM-EDS ve FT-IR cihazlarıyla karakterize edilmiştir. Temas etmeden önce SEM-EDS karakterizasyonu yapıldığında C elementinin ağırlık yüzdesi (%57.450), atomik yüzdesi (%66.540) ve O elementinin ağırlık yüzdesi (%34.310), atomik yüzdesi (%29.830) olarak hesaplamıştır. Sonrasında ise C elementinin ağırlık yüzdesi (%67.230), atomik yüzdesi (%75.400) ve O elementinin ağırlık yüzdesi (%26.110), atomik yüzdesi (%21.990) olarak hesaplanmıştır.

Keywords

• Kızılçam kozalağı
• Kongo kırmızısı
• Adsorpsiyon
• Langmuir

Utilization as absorban of biochar made from red pine cones: Removal of Congo Red from aqueous solutions

Abstract

Congo Red, an anionic dyestuff, is used in many areas of industry today. Contact of anionic and cationic dyestuffs with water sources without cleaning causes serious environmental problems. In this study, red pine (Pinus brutia Ten.) cones, which can be found in many parts of the world, were turned into biochar (PBKB) and used for KR removal from aqueous solutions. In the results obtained, it was found that the removal of CR by PBKB was in accordance with the Langmuir adsorption isotherm (R2=0.975) and the maximum adsorption capacity value was 14.124 mg/g. As a result of the kinetic and thermodynamic calculations, it was concluded that the adsorption process is endothermic and proceeds over pseudo-second-order (PSO). PBKB was characterized by SEM-EDS and FT-IR devices before and after contact with the CR. When SEM-EDS characterization was performed before contact, it was calculated as the weight percentage (57.450%) and atomic percentage (66.540%) of element C and the weight percentage (34.310%) and atomic percentage (29.830%) of element O. Afterwards, the weight percentage (67.230%) and atomic percentage (75.400%) of element C and the weight percentage (26.110%) and atomic percentage (21.990%) of element O were calculated.

Keywords

• Red pine cone
• Congo red
• Adsorption
• Langmuir

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