Electrochemical Determination of Copper(II) Ions Based on a Semicarbazone Derivative Molecule

Muhammed Elik; Abdulkadir Akyasan; Ayşegül Nazlı Özcan; Meliha Burcu Gürdere

Electrochemical Determination of Copper(II) Ions Based on a Semicarbazone Derivative Molecule

Abstract

In this study, a new potentiometric sensor selective for copper(II) ions was developed. A semicarbazone derivative molecule synthesized as an ionophore was used in the composition of the new sensor. The proposed polymer membrane sensor had a wide linear operating range of 1.0×10-5–1.0×10-1 M, a low detection limit of 4.2×10-6 M, and a near-Nernstian response. The new copper(II)-selective sensor had a wide pH range, fast response time, good selectivity and good reproducibility. The sensor, whose potentiometric performance characteristics were successfully completed, was able to determine copper(II) ions in water samples with very high recoveries.

Keywords

Heavy metals , Potentiometry , Sensor , Ion-selective electrode , Copper(II)

References

[1] Das, S., Sultana, K. W., Ndhlala, A. R., Mondal, M., & Chandra, I. (2023). Heavy metal pollution in the environment and its impact on health: exploring green technology for remediation. Environmental health Insights, 17, 1-10.
[2] Tapiero, H., Townsend, D. Á., & Tew, K. D. (2003). Trace elements in human physiology and pathology. Copper. Biomedicine & Pharmacotherapy, 57(9), 386-398.
[3] Wang, P., Yuan, Y., Xu, K., Zhong, H., Yang, Y., Jin, S. Yang, K., & Qi, X. (2021). Biological applications of copper-containing materials. Bioactive Materials, 6(4), 916-927.
[4] Ochoa-Herrera, V., León, G., Banihani, Q., Field, J. A., & Sierra-Alvarez, R. (2011). Toxicity of copper (II) ions to microorganisms in biological wastewater treatment systems. Science of the Total Environment, 412, 380-385.
[5] Özbek, O., Gürdere, M. B., Berkel, C., & Isildak, Ö. (2022). Electroanalytical determination of copper (II) ions using a polymer membrane sensor. Journal of Electrochemical Science and Technology, 14(1), 66-74.
[6] Özbek, O., & Ölcenoglu, A. (2023). The use of bis–thiadiazole and bis–oxadiazol derivatives as ionophores: a novel copper (II)–selective potentiometric electrodes. Microchemical Journal, 190, 108679.
[7] Isildak, Ö., & Özbek, O. (2021). Application of potentiometric sensors in real samples. Critical Reviews in Analytical Chemistry, 51(3), 218-231.
[8] Bratov, A., Abramova, N., & Ipatov, A. (2010). Recent trends in potentiometric sensor arrays—A review. Analytica Chimica Acta, 678(2), 149-159.
[9] Yin, T., & Qin, W. (2013). Applications of nanomaterials in potentiometric sensors. TrAC Trends in Analytical Chemistry, 51, 79-86.
[10] Mostafa, I. M., Meng, C., Dong, Z., Lou, B., & Xu, G. (2022). Potentiometric sensors for the determination of pharmaceutical drugs. Analytical Sciences, 38(1), 23-37.

[11] Özbek, O., Gezegen, H., Cetin, A., & Isildak, Ö. (2022). A potentiometric sensor for the determination of Pb (II) ions in different environmental samples. ChemistrySelect, 7(33), e202202494.
[12] Mohamed, M. E. B., Frag, E. Y., & El Brawy, M. H. (2021). Rapid potentiometric sensor for determination of Cu (II) ions in food samples. Microchemical Journal, 164, 106065.
[13] Asif, M., & Alghamdi, S. (2021). Chemical and Biological potentials of semicarbazide and thiosemicarbazide derivatives and their metals complexes. Advanced Journal of Chemistry, Section B, 3(3), 243-270.
[14] Liu, R., Cui, J., Ding, T., Liu, Y., & Liang, H. (2022). Research progress on the biological activities of metal complexes bearing polycyclic aromatic hydrazones. Molecules, 27(23), 8393.
[15] More, M. S., Joshi, P. G., Mishra, Y. K., & Khanna, P. K. (2019). Metal complexes driven from Schiff bases and semicarbazones for biomedical and allied applications: a review. Materials Today Chemistry, 14, 100195.
[16] Doğan, M., Koçyiğit, Ü. M., Gürdere, M. B., Ceylan, M., & Budak, Y. (2022). Synthesis and biological evaluation of thiosemicarbazone derivatives. Medical Oncology, 39(10), 157.
[17] Özbek, O., Ugur, Ö. B., Ören, S., Gürdere, M. B., & Kocabas, S. (2024). New solid state contact potentiometric sensor based on a thiosemicarbazone derivative molecule for determination of copper (II) ions in environmental samples. Polyhedron, 252, 116878.
[18] Altunoluk, O. C., Özbek, O., Kalay, E., Tokalı, F. S., & Aslan, O. N. (2024). Surface characterization of barium (II)-selective potentiometric sensor based on a newly synthesized thiosemicarbazone derivative molecule. Electroanalysis, 36(7), e202300407.
[19] Ören, S., Özbek, O., & Isildak, Ö. (2024). The use of thiazole derivative molecules as sensor materials: Potentiometric determination of Cu (II) ions. Vietnam Journal of Chemistry. 62, 486-492.
[20] Buck, R. P., & Lindner, E. (1994). Recommendations for nomenclature of ionselective electrodes (IUPAC Recommendations 1994). Pure and Applied Chemistry, 66(12), 2527-2536.
[21] Umezawa, Y., Buhlmann, P., Umezawa, K., Tohda, K., & Amemiya, S. (2000). Potentiometric Selectivity Coefficients of Ion-Selective Electrodes. Part I. Inorganic Cations. Pure Appl. Chem, 72, 1851-2082.
[22] Özbek, O., Altunoluk, O. C., & Isildak, Ö. (2024). Surface characterization and electroanalytical applications of the newly developed copper (II)-selective potentiometric sensor. Analytical Sciences, 40(1), 141-149.
[23] Ganjali, M. R., Ghafarloo, A., Faridbod, F., & Norouzi, P. (2012). Copper-selective PVC membrane sensor. International Journal of Electrochemical Science, 7(4), 3706-3716.
[24] Çay, Ç., Yolcu, M., & Sayın, S. (2024). All-Solid-State PVC-Membrane Cu (II)-Selective Potentiometric Microsensor Based on a Novel Calix [4] arene Derivative. Erzincan University Journal of Science and Technology, 17(2), 460-473.
[25] Aslan, N., Koçak, Z., Kormalı Ertürün, H., & Şen, N. (2023). Analysis of Copper (II) Ions in Human Blood Using a New Solid-Contact PVC Membrane Potentiometric Sensor Based on a N, N′-Bis (salicylidene)-1, 3-diaminopropane Schiff Base. Analytical and Bioanalytical Chemistry Research, 10(2), 193-204.
[26] Özbek, O., & Isildak, Ö. (2022). Potentiometric determination of copper (II) ions based on a porphyrin derivative. Journal of the Chinese Chemical Society, 69(7), 1060-1069.

Details

Primary Language

English

Subjects

Sensor Technology

Journal Section

Research Article

Authors

Muhammed Elik
0009-0005-4192-6576
Türkiye

Abdulkadir Akyasan
0009-0000-6474-6483
Türkiye

Ayşegül Nazlı Özcan
0009-0008-4716-5263
Türkiye

Meliha Burcu Gürdere ^*
0000-0003-4285-5528
Türkiye

Publication Date

December 27, 2024

Submission Date

December 21, 2024

Acceptance Date

December 27, 2024

Published in Issue

Year 2024 Volume: 1 Number: 1

IZ

https://izlik.org/JA89EP36TR

APA

Elik, M., Akyasan, A., Özcan, A. N., & Gürdere, M. B. (2024). Electrochemical Determination of Copper(II) Ions Based on a Semicarbazone Derivative Molecule. Turkish Journal of Sensors and Biosensors, 1(1), 37-44. https://izlik.org/JA89EP36TR

31746

The content of the Turkish Journal of Sensors and Biosensors is published under the Creative Commons Attribution - NonCommercial 4.0 International (CC BY-NC 4.0).