Research Article
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Year 2019, Volume 1, Issue 1, 11.12.2019

Abstract

References

  • 1. Chen, X., Burda, C. 2008. “The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials” J. Am. Chem. Soc., 130, 5018–5019. DOI: 10.1021/ja711023z
  • 2. Zaleska, A. 2008. “Doped-TiO2: A review” Recent Patents on Engineering 2, 157-164.
  • 3. Martins, A. C., Cazetta, A. L., Pezoti, O., Souza, J. R.B., Zhang, T., Pilau, E. J., Asefa, T., Almeida V. C. 2017. “Sol-gel synthesis of new TiO2/activated carbon photocatalyst and its application for degradation of tetracycline”, Ceram. Intern. 43, 4411–4418. http://dx.doi.org/10.1016/j.ceramint.2016.12.088
  • 4. Leary, R., Westwood A. 2011. “Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis”, Carbon 49, 741–772.
  • 5. Dong, F., Guo, S., Wang, H., Li X., Wu, Z. 2011. “Enhancement of the visible light photocatalytic activity of C-doped TiO2 nanomaterials prepared by a green synthetic approach”, J. Phys. Chem. C 115, 13285–13292. doi.org/10.1021/jp111916q
  • 6. Rahman, M. N. A., Rahim, N. A. A., Kamarudin, W. F. W., Irwan, Z., Amin, A. R. M., Muhammud, A., Muda, S. M., Akhir, N. E. F. M. 2018. “Solar photocatalytic degradation of food dye (Tartrazine) using zinc oxide catalyst” Int. J. Eng. Technol. 7, 222-226.
  • 7. Zazouli, M. A., Ghanbari, F., Yousefi, M., Madihi-Bidgolie, S. 2017. “Photocatalytic degradation of food dye by Fe3O4-TiO2 nanoparticles in presence of peroxymonosulfate: The effect of UV sources” J. Environ. Chem. Eng., 5, 2459-2468.
  • 8. Ranade, M.R., Navrotsky, A., Zhang, H.Z., Banfield, J.F., Elder, S.H., Zaban, A., Borse, P.H., Kulkarni, S.K., Doran, G.S., Whitfield H.J. 2002. “Energetics of nanocrystalline TiO2” PNAS 99, Suppl. 2, 6476-6481.
  • 9. Zhang, H., Banfield, J.F. 2002. “Kinetics of crystallization and crystal growth of nanocrystalline anatase in nanometer-sized amorphous titania” J. Chem. Mater. 14, 4145-4154.
  • 10. Koç Keşir, M., Dilber, G., Sökmen, M., Durmuş, M. 2019. “Use of new quaternized water soluble zinc phthalocyanin derivatives for effective dye sensitization of TiO2”. J. Sol-Gel Sci. Technol. https://doi.org/10.1007/s10971-019-05109-w
  • 11. Sökmen, M., Koc Kesir, M., Alomar, S. Y. 2017. “Phthalocyanine-TiO2 nanocomposites for photocatalytic applications: A review” Am. J. Nanosci. 3, 63-80.

Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes

Year 2019, Volume 1, Issue 1, 11.12.2019

Abstract

Aim of this study is to produce highly active hybrid propolis-TiO2 nanocomposites using sol-gel method and to use it remediation of food industry waste. Propolis solution was prepared in ethanol and added to sol-gel mixture at increasing volume (0.25, 0.50, 0.75, 1.00 mL) to prepare propolis-TiO2 (P-TiO2) hybrid catalyst. Neat TiO2 was also prepared by the same sol-gel technique and its action was compared to propolis doped ones. Catalysts were calcinated at 300 oC to obtain desired anatase form.

After production the catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and FTIR. Sunset Yellow (SY), Allura red (AR) and Tartrazine (TT) were used as model compounds ([C]0=10 mgL-1, catalyst mass=1 gL-1) . Concentration of dyes were monitored by UV-vis spectrometry. P-TiO2 catalyst prepared with 1.00 mL propolis solution was extremely effective for removal of all dyes studies for both 254 nm and 365 nm light exposure. LED light exposure provided lower removal rate (approx.. 25%) but it was still significant for dye removal.

References

  • 1. Chen, X., Burda, C. 2008. “The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials” J. Am. Chem. Soc., 130, 5018–5019. DOI: 10.1021/ja711023z
  • 2. Zaleska, A. 2008. “Doped-TiO2: A review” Recent Patents on Engineering 2, 157-164.
  • 3. Martins, A. C., Cazetta, A. L., Pezoti, O., Souza, J. R.B., Zhang, T., Pilau, E. J., Asefa, T., Almeida V. C. 2017. “Sol-gel synthesis of new TiO2/activated carbon photocatalyst and its application for degradation of tetracycline”, Ceram. Intern. 43, 4411–4418. http://dx.doi.org/10.1016/j.ceramint.2016.12.088
  • 4. Leary, R., Westwood A. 2011. “Carbonaceous nanomaterials for the enhancement of TiO2 photocatalysis”, Carbon 49, 741–772.
  • 5. Dong, F., Guo, S., Wang, H., Li X., Wu, Z. 2011. “Enhancement of the visible light photocatalytic activity of C-doped TiO2 nanomaterials prepared by a green synthetic approach”, J. Phys. Chem. C 115, 13285–13292. doi.org/10.1021/jp111916q
  • 6. Rahman, M. N. A., Rahim, N. A. A., Kamarudin, W. F. W., Irwan, Z., Amin, A. R. M., Muhammud, A., Muda, S. M., Akhir, N. E. F. M. 2018. “Solar photocatalytic degradation of food dye (Tartrazine) using zinc oxide catalyst” Int. J. Eng. Technol. 7, 222-226.
  • 7. Zazouli, M. A., Ghanbari, F., Yousefi, M., Madihi-Bidgolie, S. 2017. “Photocatalytic degradation of food dye by Fe3O4-TiO2 nanoparticles in presence of peroxymonosulfate: The effect of UV sources” J. Environ. Chem. Eng., 5, 2459-2468.
  • 8. Ranade, M.R., Navrotsky, A., Zhang, H.Z., Banfield, J.F., Elder, S.H., Zaban, A., Borse, P.H., Kulkarni, S.K., Doran, G.S., Whitfield H.J. 2002. “Energetics of nanocrystalline TiO2” PNAS 99, Suppl. 2, 6476-6481.
  • 9. Zhang, H., Banfield, J.F. 2002. “Kinetics of crystallization and crystal growth of nanocrystalline anatase in nanometer-sized amorphous titania” J. Chem. Mater. 14, 4145-4154.
  • 10. Koç Keşir, M., Dilber, G., Sökmen, M., Durmuş, M. 2019. “Use of new quaternized water soluble zinc phthalocyanin derivatives for effective dye sensitization of TiO2”. J. Sol-Gel Sci. Technol. https://doi.org/10.1007/s10971-019-05109-w
  • 11. Sökmen, M., Koc Kesir, M., Alomar, S. Y. 2017. “Phthalocyanine-TiO2 nanocomposites for photocatalytic applications: A review” Am. J. Nanosci. 3, 63-80.

Details

Primary Language English
Subjects Chemistry, Analytical
Journal Section Research Articles
Authors

Melek KOÇ KEŞİR This is me
Karadeniz Technical University
Türkiye


Münevver SÖKMEN> (Primary Author)
Konya Food and Agriculture University
Türkiye

Supporting Institution TÜBİTAK
Project Number 1649B031600549
Thanks Thanks to TÜBİTAK for financial support.
Publication Date December 11, 2019
Application Date November 6, 2019
Acceptance Date November 25, 2019
Published in Issue Year 2019, Volume 1, Issue 1

Cite

Bibtex @research article { turkjac643719, journal = {Turkish Journal of Analytical Chemistry}, eissn = {2687-6698}, address = {Karadeniz Teknik Üniversitesi, Fen Fakültesi, Kimya Bölümü, Oda No: 111, 61080 Trabzon}, publisher = {Miraç OCAK}, year = {2019}, volume = {1}, number = {1}, pages = { - }, title = {Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes}, key = {cite}, author = {Koç Keşir, Melek and Sökmen, Münevver} }
APA Koç Keşir, M. & Sökmen, M. (2019). Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes . Turkish Journal of Analytical Chemistry , 1 (1) , . Retrieved from https://dergipark.org.tr/en/pub/turkjac/issue/50574/643719
MLA Koç Keşir, M. , Sökmen, M. "Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes" . Turkish Journal of Analytical Chemistry 1 (2019 ): <https://dergipark.org.tr/en/pub/turkjac/issue/50574/643719>
Chicago Koç Keşir, M. , Sökmen, M. "Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes". Turkish Journal of Analytical Chemistry 1 (2019 ):
RIS TY - JOUR T1 - Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes AU - MelekKoç Keşir, MünevverSökmen Y1 - 2019 PY - 2019 N1 - DO - T2 - Turkish Journal of Analytical Chemistry JF - Journal JO - JOR SP - EP - VL - 1 IS - 1 SN - -2687-6698 M3 - UR - Y2 - 2019 ER -
EndNote %0 Turkish Journal of Analytical Chemistry Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes %A Melek Koç Keşir , Münevver Sökmen %T Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes %D 2019 %J Turkish Journal of Analytical Chemistry %P -2687-6698 %V 1 %N 1 %R %U
ISNAD Koç Keşir, Melek , Sökmen, Münevver . "Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes". Turkish Journal of Analytical Chemistry 1 / 1 (December 2019): - .
AMA Koç Keşir M. , Sökmen M. Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes. TurkJAC. 2019; 1(1): -.
Vancouver Koç Keşir M. , Sökmen M. Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes. Turkish Journal of Analytical Chemistry. 2019; 1(1): -.
IEEE M. Koç Keşir and M. Sökmen , "Production of propolis/TiO2 (P-TiO2) nano composites for degradation of food dyes", Turkish Journal of Analytical Chemistry, vol. 1, no. 1, Dec. 2019