Fosforesans Pigmentli Vitrifiye Sırları ile Enerji Tasarruflu Yüzeyler

Year 2020, Volume: 12 Issue: 1, 118 - 124, 31.01.2020

Nazım Kunduracı , Zahide Bayer Öztürk Gülfem Binal

https://doi.org/10.29137/umagd.599028

Abstract

Malzemeler için enerji tasarrufu sağlayan yüzey uygulanması çok
önemlidir ve son yıllarda kapsamlı bir şekilde araştırılmıştır. Bu çalışmada, fosforesans
pigment uygulaması vitrifiye sırlarında kullanılmıştır. Fosforesans
pigmentlerin ve sırların kullanımı yüksek kalite sağlamakta ve aynı zamanda
müşterinin dikkatini çekmektedir. Bu çalışmada, üretilen fosforesans pigment,
belirli oranlarda vitrifiye sır fritine eklenmiştir. Vitrifiye bünyeler
sırlandıktan sonra bileşimler endüstriyel fırınlarda pişirilmiştir. Standart
vitrifiye sırına kıyasla homojen ve uzun ömürlü yüzeyler elde edilmiştir.
Pigment kristalinitesi ve mikroyapısı sırasıyla X-ışını difraksiyonu (XRD) ve
taramalı elektron mikroskobu (SEM-EDS) ile değerlendirilmiştir. Sonuçlar %10
pigment ilavesi ile yeni fosforesans sır numunelerinin tatmin edici bir ışıma
gücü sergilediğini göstermektedir. İlk kez vitrifiye bir ürün fotolüminesans
sır ile dekorlanmıştır.

Keywords

Vitrifiye, sır, fosforesans

The energy saving surfaces for the sanitary-ware glaze by means of the phosphorescent pigment

Abstract

Application
of the energy saving surfaces for materials is very important and researched
extensively in recent years. In this study, application of phosphorescent
pigment is used in sanitary-ware. The usage of phosphorescent pigments and
glazes supplies high quality and also attracts customer’s attention. In this
study, produced phosphorescent pigment added into sanitary-ware glaze frit at
certain ratios. After applying glazes on sanitary bodies, the compositions were
fired in industrial kiln. In comparison with the standard sanitary-ware glaze,
the homogenous and long lasting ability surface performed. The crystallinity of
pigment and microstructure were evaluated by X-ray diffraction (XRD) and
scanning electron microscope (SEM-EDS), respectively. The results highlighted
the new sanitary-ware glaze samples with phosphorescent showed satisfactory
phosphorescence ability can be achieved with 10%wt. pigment addition. It is
important to note that it is the first time sanitaryware was decorated with
photoluminescent glaze.

Keywords

Sanitary-ware, Glaze, Phosphorescence

References

• Referans 1. Bernaconi, A., Marinoni, N., Pavese, A., Francescon, F., & Young, K. (2014). Feldspar and firing cycle effects on the evolution of sanitary-ware vitreous body. Ceram. Int., 40, 6389-6398.
• Referans 2. Clabau, F., Rocquefelte, X., Jobic, S., Deniard, P., Whangbo, M.H., Garcia, A., & Mercier, T.L. (2007) On the phoshorescence mechanism in SrAl2O4:Eu2+and its codoped derivates. Solid State Sci., 9, 608-612.
• Referans 3. Dumitrache, R.L., & Teoreanu, I. (2006). Melting behaviour of feldspar porcelain glazes. U.P.B. Sci. Bull., 68(3), 16.
• Referans 4. Eppler, R.A., & Eppler, D.R. (2000). Glazes and glass coatings. Westerville, Ohio: Am. Cer. Soc.
• Referans 5. German, R.M. (1985) Liquid Phase Sintering. New York: Plenum Press.
• Referans 6. Hupa, L., Bergman, R., Fröberg, L., Vane-Tempest, S., Hupa, M., Kronberg, T., Pesonen-Leinonen, E., & Sjöberg, A.M. (2005). Chemical resistance and cleanability of glazed surfaces. J.Su.Sc., 584, 113-118.
• Referans 7. Kaya, S.Y., & Karasu, B. (2012). Process parameters determination of phosphorescent pigment added, frit-based wall tiles vetrosa decorations. Ceram. Int., 38, 2757-2766.
• Referans 8. Kaya, S.Y., & Karasu, B. (2012) Ceramics and glass with phosphorescent ability. Ceram. Tech., 34, 94-99.
• Referans 9. Kaya, S.Y., Karasu, B., & Karacaoglu, E. (2009) General review of application of phosphorescence pigments in ceramic industry. In: Proceedings of SERES’09 I. International, Ceramic, Glass, Porcelain Enamel, Glaze and Pigment Congress, Eskisehir, Turkey, p. 608-616.
• Refernas 10. Kaya, S.Y., Karasu, B., & Karacaoglu, E. (2010) Phosphorescence pigment applications in glasses, In: Proceedings of the Camgeran Glass Symposium, Eskisehir, Turkey, p. 41-44.
• Refernas 11. Qing, X., Wen, C., Feng, Z., & Run-Zhang, Y. (2002). A novel infrared radiant glaze exhibiting antibacterial and antifungal functions. J Wuham Univ Technol., 17, 11-12.
• Refernas 12. Reed, J.S. (1993). Introduction to principles of ceramic processing, second ed., New York: Wiley, p. 395-474.
• Referans 13. Ruiz, O., Sanmiguel, F., Gargori, C., Galindo, F., & Monrós, G. (2008). Study of the photocatalytic degradability of ceramic glazes. In: Proceedings of Qualicer, Castellon, Spain. p. 15-31.
• Referans 14. Staneva, N., & Kasabov, I. (1996) The ınfluence of electrolytes of the casting properties of porcelain slips. Interceram., 45, 12-14.
• Referans 15. Xiao, L., Xiao, Q., Liu, Y., Ai, P., Li, Y., & Wang, H. (2010). A transparent surface-crystallized Eu2+, Dy3+ co-doped strontium aluminate long-lasting phosphorescent glass-ceramic. J.All.Com., 495, 72-75.