POMZA VE GOMALAK İÇEREN SOLVENT BAZLI BOYALAR ÜZERİNE YENİ BİR ARAŞTIRMA

Abstract

Bu çalışmada; inşaat ve kimya sektöründe kullanılmak üzere solvent bazlı boyaya çeşitli katkı maddeleri eklenerek fiziksel özelliklerin geliştirilmesi ve dekoratif amaçlı olarak kullanılması hedeflenmiştir. Yapılan çalışmada viskozite, parlaklık, kapatıcılık, hidrofobiklik ve kuruma süresi gibi farklı fiziksel testler uygulanmıştır. Optimizasyon metodu olarak, Taguchi metodu kullanılmış ve FT-IR cihazı ile moleküler bağ karakterizasyonu incelenmiştir. Burada, gomalağın metal yüzeylerde koruma sağladığı ve pomzanın ise yapışma özelliğini arttırdığı gözlemlenmiştir. Yapılan testler sonucunda kullanılan katkıların, parlaklık, renk uygunluğu ve kuruma süresine olumsuz bir etkisinin olmadığı gözlenmiştir. Referans boyaya kıyasla, hazırlanan boyaların hidrofobikliği ve kapatıcılığı arttırıcı etkisinin olduğu gözlemlenmiştir. Deneylerin FT-IR spektrumları incelendiğinde ise referans boyayla benzer bağ karakterizasyonu olduğu gözlemlenmiştir.

Keywords

• Boya,Solvent,Taguchi,FT-IR

A Novel Survey on Solvent Based-Dyes Containing Shellac and Pumice

Abstract

This study aimed the dyes as decorative usage and improving the physical properties by using solvent based-dye with additives to evaluate in construction and chemical applications. The physical tests as viscosity, hydrophobicity, drying time, gloss effect, hiding power/transparency were applied on surfaces. Taguchi Method was used as an optimization method and characterization of molecular bonds was investigated with FT-IR. Shellac was used for protection of metallic surfaces and pumice increased the adhesive effect of dye. The test results showed that the additives did not affect the glossiness, color availability and drying time as a negative result. When the prepared dyes compared reference dyes, it was seen that hydrophobicity and hiding power/transparency effects were increased. FT-IR spectra showed that the prepared dyes had similar bonds with reference dyes.

Keywords

• Dye,Solvent,Taguchi,FT-IR

References

1. Altinsoy A.R. and Caliskan, S. (2014) Investigation of thermal and physical properties for construction dyes containing different boron chemicals and shellac, Yildiz Technical University, Istanbul.
2. Bayrak, Z. (1996) Applying Taguchi method in the shield of practising quality control, MSc Thesis. Kocaeli University, Kocaeli.
3. Byrappa, K. and Suresh Kumar B.V. (2007) Characterization of zeolites by infrared spectroscopy, Asian Journal of Chemistry, 19(6), 4933-4935.
4. Canıyılmaz, E. (2001) Taguchi method in quality improvement and an application, MSc Thesis. Gazi University, Ankara.
5. Durgun, Z.G. (2010) Çeşitli Kalsiyum Boratların Sentezi Karakterizasyonu ve Alev Geciktirici Etkinliklerinin İncelenmesi, MSc Thesis. Ankara University.
6. http://ec.europa.eu/environment/air/pollutants/stationary/paints/paints_legis.htm, Accessed Date: 12.01.2017.
7. Kalafatoğlu, İ.E. and Örs, S.N. (2003) 21. yüzyılda bor teknolojileri ve uygulamaları, BAÜ Fen Bilimleri Enstitüsü Dergisi, 5(1), 59-71.
8. Kocadagistan, B. and Kocadagistan, E. (2016) Batch and column removal of the dye blue 3R over pumice, Desalination and Water Treatment, 57(58), 28042-28055. doi: 10.1080/19443994.2016.1184186

9. Kowalczyk, K., Łuczka, K., Grzmil, B. and Spychaj, T. (2013) Anticorrosive 2K polyurethane paints based on nano and microphosphates with high dispersing additive content, Progress in Organic Coatings, 76, 1088–1094. doi: 10.1016/j.porgcoat.2013.03.003
10. Kucuk, M. and Kocakerim, M. (2005) Optimization of dissolution of ulexite in water saturated with sulphur dioxide, Chemical Engineering and Processing, 44(9), 1005-1011. doi: 10.1016/j.cep.2004.11.006
11. Kul, A.R., Benek, V., Selçuk, A. and Onursal, N. (2017) Using natural stone pumice in Van region on adsorption of some textile dyes, 4 (2), 525-536. doi: 10.18596/jotcsa.292662
12. Kymalainen, H.R. and Sjöberg, A.M. (2008) Flax and hemp fibres as raw materials for thermal insulations, Building and Environment, 43, 1261-1270. doi: 10.1016/j.buildenv.2007.03.006
13. Law, C., Pathirana, S.C., Li, X., Anderson, A.Y., Barnes, P.R.F., Listorti, A., Ghaddar, T.H. and O′Regan, B.C. (2010) Water-based electrolytes for dye-sensitized solar cells, Advanced Materials, 22(40), 4505-4509. doi: 10.1002/adma.201001703
14. Mergen, A., Demirhan, M.H. and Bilen, M. (2003) Processing of boric acid from borax by a wet chemical method, Advanced Powder Technology, 14, 279-293. doi: 10.1163/15685520360685947
15. Moreno, M., Lampard, C., Williams, N., Lago, E., Emmett, S., Goikoetxea, M. and Barandiaran, M.J. (2015) Eco-paints from bio-based fatty acid derivative latexes, Progress in Organic Coatings, 81, 101–106. doi: 10.1016/j.porgcoat.2015.01.001
16. Nakajima, A., Hashimoto, K. and Watanabe, T. (2001) Recent studies on super-hydrophobic films, Monatshefte fur Chemie, 132, 31-41.
17. Ozturk Akbal, F., Akdemir, N. and Nur Onar, A. (2000) FT-IR spectroscopic detection of pesticide after sorption onto modified pumice, Talanta, 53(1), 131-135.
18. Ozturk, A.B. (2015) Investigation of thermal and physical properties for construction dyes containing different boron chemicals and shellac, MSc Thesis. Yildiz Technical University, Istanbul.
19. Panyakaew, S. and Fotios, S. (2011) New thermal insulation boards made from coconut husk and bagasse, Energy Buildings, 43, 1732-1739. doi: 10.1016/j.enbuild.2011.03.015
20. Pizzi, A. and Mittal, K.L. (2003) Handbook of Adhesive Technology, Second Edition, Revised and Expanded, USA.
21. Seclaman, E., Sallo, A., Elenes, F., Crasmareanu, C., Wikete, C., Timofei, S. and Simon, Z. (2002) Hydrophobicity, protolytic equilibrium and chromatographic behaviour of some monoazoic dyes, Dyes and Pigments, 55, 69–77.
22. Singaravel, B. and Selvaraj, T. (2016) Application of Taguchi method for optimization of parameters in turning operation, Journal for Manufacturing Science and Production, 16(3), 1-5.
23. Stoye, D. and Freitag, W. (1998) Paints, coatings and solvents, Second Edition, Wiley-VCH.
24. Vankantia, V.K and Ganta, V.J. (2014) Optimization of Process parameters in drilling of GFRP composite using Taguchi method, Journal of Materials Research and Technology, 3(1), 35-41. doi: 10.1016/j.jmrt.2013.10.007
25. Varhegyi, G., Szabo, P., Till, F. and Zelei, B. (1998) TG, TG-MS and FTIR characterization of high-yield biomass charcoals, Energy Fuels, 12, 969-974. doi: 10.1021/ef9800359
26. Veliev, E.V., Öztürk, T., Veli, S. and Fatullayev, A.G. (2006) Application of Diffusion Model for Adsorption of Azo Reactive Dye on Pumice, Polish Journal of Environmental Studies, 15 (2), 347-353.
27. Woods, W.G. (1994) An introduction to boron: history, sources, uses, and chemistry, Environmental Health Perspectives, 102, 5-11. doi: 10.1289/ehp.94102s75