Investigation of the Effect of Cyclodextrin and Crosslinking Agent on Enhancement of Water and Oil Repellency Properties of TencelTM Fabrics

Year 2024, Volume: 29 Issue: 2, 463 - 478, 30.08.2024

Deniz Ildız , Buket Arık

https://doi.org/10.17482/uumfd.1422601

Abstract

In this study, it was intended to enhance the water and oil repellency properties of TencelTM fibres that are in naturally hydrophilic character to expand their usage possibilities. For this aim, TencelTM fabrics were treated by floroalkyloligosiloxan (Dynasylan F 8815), cyclodextrin, crosslinking agent and catalyst. By preparing seven different treatment recipes, fabric application processes were carried out in one or in two stages. Then, the properties of the samples like water and oil repellency values, durability of the treatments after washing, bursting strength, stiffness and yellowness were determined and compared. Moreover, the microscopic images of the samples were evaluated and chemical structure of the fabric surfaces were characterized. The most withstanding outcome was obtained by the two stages application of floroalkyloligosiloxan, cyclodextrin, crosslinking agent and catalyst altogether to TencelTM fabric surfaces.

Keywords

Tencel, Cyclodextrin, Crosslinking agent, Water repellency, Oil repellency, Washing durability

TENCELTM KUMAŞLARIN SU VE YAĞ İTİCİLİK ÖZELLİKLERİNİN İYİLEŞTİRİLMESİNDE SİKLODEKSTRİN VE ÇAPRAZ BAĞLAYICI ETKİSİNİN İNCELENMESİ

Abstract

Bu çalışmada, normalde hidrofil olan TencelTM liflerinin kullanım olanaklarını genişletmek için su ve yağ iticilik özelliklerinin iyileştirilmesi amaçlanmıştır. Bu amaçla, TencelTM kumaşlara floroalkiloligosiloksan (Dynasylan F 8815), siklodekstrin, çapraz bağlayıcı ve katalizör kullanılarak işlem yapılmıştır. Yedi farklı işlem reçetesi hazırlanarak tek aşamalı veya iki aşamalı olarak kumaşlara uygulanmıştır. Daha sonra numunelerin su ve yağ iticilik değerleri, yıkama sonrası işlemlerin kalıcılığı, patlama mukavemetleri, tutum sertleşmesi ve sararma gibi özellikleri belirlenmiş ve kıyaslanmıştır. Ayrıca numunelerin mikroskobik görünümleri incelenmiş ve kumaş yüzeylerinin kimyasal yapısı karakterize edilmiştir. En başarılı sonuç, floroalkiloligosiloksan, siklodekstrin, çapraz bağlayıcı ve katalizörün TencelTM kumaş yüzeylerine birlikte uygulandığı iki aşamalı işlemle elde edilmiştir.

Keywords

Tencel, Siklodekstrin, Çapraz bağlayıcı, Su iticilik, Yağ iticilik, Yıkama dayanımı

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