Preconcentration of Cu2+, Cr3+, Co2+, and Ni2+ by Solid-Phase Extraction Using a Recently Developed Mixed-Mode Sorbent

Year 2024, , 109 - 118, 30.04.2024

Hayriye Aral

https://doi.org/10.53433/yyufbed.1315917

Abstract

The enrichment and simultaneous analysis of Cu2+, Cr3+, Co2+, and Ni2+ by solid-phase extraction method were performed using a stationary phase containing amide functional groups, an aromatic benzene ring, and aliphatic groups in a silica-based structure that we had synthesized for HPLC separations in our previous studies. Solid-phase extraction was performed using a column system and the results obtained were analysed by ICP-OES. Effects of pH, amount of sorbent, amount of eluting solvent, sample volume, flow rates of the eluent and the sample, and interfering ions were evaluated in recovery processes for the metals in the sample solutions. Linear range, detection limit, and relative standard deviation (% RSD) values were calculated for each metal. The linear range (ng/mL) was between 0.01 and 0.25 for all ions, while the limit of detection (ng/mL) was found to be 0.64, 1.7, 0.44, and 0.51 and % RSD was 2.8, 2.4, 2.6, and 2.9 for Cu2+, Cr3+, Co2+, ve Ni2+, respectively.

Keywords

Chromium, Cobalt, Copper, Nickel, Solid-based stationary phase, Solid-phase extraction

Cu2+, Cr3+, Co2+, and Ni2+’nin Son Zamanlarda Geliştirilen Karma Mod Bir Sorbent Kullanılarak Katı Faz Ekstraksiyonu ile Zenginleştirilmesi

Abstract

Daha önceki çalışmalarımızda HPLC ayırmaları için sentezlenen silika tabanlı amid fonksiyonel grupları, benzene halkası ve alifatik gruplar içeren bir sabit baz kullanılarak katı faz ekstraksiyonu yöntemi ile Cu2+, Cr3+, Co2+, ve Ni2+’nin zenginleştirilmesi ve eş zamanlı analizi yapıldı. Katı faz ekstraksiyonu kolon sistemi kullanılarak gerçekleştirilmiş ve elde edilen sonuçlar ICP-OES ile analiz edilmiştir. Örnek çözeltilerdeki metaller için geri kazanım proseslerinde pH, sorbent miktarı, elüsyon çözücü miktarı, numune hacmi, eluent ve numunenin akış hızı ve yabancı iyon etkisi incelendi. Her metal için lineer aralık, dedeksiyon limiti ve bağıl standart sapma değerleri hesaplandı. Dedeksiyon limiti (ng/mL) Cu2+, Cr3+, Co2+, ve Ni2+ için sırasıyla 0.64, 1.7, 0.44 ve 0.51 ve bağıl standart sapma 2.8, 2.4, 2.6 ve 2.9 iken, lineer aralık bütün iyonlar için (ng/mL) 0.01 ve 0.25 aralığındadır.

Keywords

Bakır, Katı faz ekstraksiyonu, Kobalt, Krom, Nikel, Silika tabanlı sabit faz

References

• Akhond, M., Absalan, G., Sheikhian, L., Eskandari, M. M., & Sharghi, H. (2006). Di (n-propyl) thiuram disulfide bonded on silica gel as a new sorbent for separation, preconcentration, and measurement of silver ion from aqueous samples. Separation and Purification Technology, 52(1), 53-59. doi:10.1016/j.seppur.2006.03.014
• Akman, S., Ínce, H., & Köklü, Ü. (1992). Determination of some trace elements in sea-water by atomic absorption spectrometry after concentration with modified silicas. Journal of Analytical Atomic Spectrometry, 7(2), 187-189. doi:10.1039/JA9920700187
• Alan, M., Kara, D., & Fisher, A. (2007). Preconcentration of heavy metals and matrix elimination using silica gel chemically modified with 2, 3‐dihydroxybenzaldehyde. Separation Science and Technology, 42(4), 879-895. doi:10.1080/01496390601174182
• Ali, H., Khan, E., & Ilahi, I. (2019). Environmental chemistry and ecotoxicology of hazardous heavy metals: environmental persistence, toxicity, and bioaccumulation. Journal of Chemistry, 2019, 6730305. doi:10.1155/2019/6730305
• Amarasekara, A. S., Owereh, O. S., & Aghara, S. K. (2009). Synthesis of 4-acylpyrazolone Schiff base ligand grafted silica and selectivity in adsorption of lanthanides from aqueous solutions. Journal of Rare Earths, 27(5), 870-874. doi:10.1016/S1002-0721(08)60352-X
• Aral, H., Çelik, K. S., Altındağ, R., & Aral, T. (2017). Synthesis, characterization, and application of a novel multifunctional stationary phase for hydrophilic interaction/reversed phase mixed-mode chromatography. Talanta, 174, 703-714. doi:10.1016/j.talanta.2017.07.014
• Atanassova, D., Stefanova, V., & Russeva, E. (1998). Co-precipitative pre-concentration with sodium diethyldithiocarbamate and ICP-AES determination of Se, Cu, Pb, Zn, Fe, Co, Ni, Mn, Cr and Cd in water. Talanta, 47(5), 1237-1243. doi:10.1016/S0039-9140(98)00211-2
• Aydin, F. A., & Soylak, M. (2007). A novel multi-element coprecipitation technique for separation and enrichment of metal ions in environmental samples. Talanta, 73(1), 134-141. doi:10.1016/j.talanta.2007.03.007
• Baghaei, P. A. M., Mogaddam, M. R. A., Farajzadeh, M. A., Mohebbi, A., & Sorouraddin, S. M. (2023). Application of deep eutectic solvent functionalized cobalt ferrite nanoparticles in dispersive micro solid phase extraction of some heavy metals from aqueous samples prior to ICP-OES. Journal of Food Composition and Analysis, 117, 105125. doi:10.1016/j.jfca.2022.105125
• Behbahani, M., Bide, Y., Salarian, M., Niknezhad, M., Bagheri, S., Bagheri, A., & Nabid, M. R. (2014). The use of tetragonal star-like polyaniline nanostructures for efficient solid phase extraction and trace detection of Pb (II) and Cu (II) in agricultural products, sea foods, and water samples. Food Chemistry, 158, 14-19. doi:10.1016/j.foodchem.2014.02.110
• Betiha, M. A., Moustafa, Y. M., El-Shahat, M. F., & Rafik, E. (2020). Polyvinylpyrrolidone-Aminopropyl-SBA-15 schiff Base hybrid for efficient removal of divalent heavy metal cations from wastewater. Journal of Hazardous Materials, 397, 122675. doi:10.1016/j.jhazmat.2020.122675
• Chui, Y. M., Chang, X. J., Zhu, X. B., Luo, H. X., Hu, Z., Zou, X. J., He, Q. (2007). Chemically modified silica gel with p-dimethylaminobenzaldehyde for selective solid-phase extraction and preconcentration of Cr(III), Cu(II), Ni(II), Pb(II) and Zn(II) by ICP-OES. Microchemical Journal, 87(1), 20-26. doi:10.1016/j.microc.2007.04.004
• Cui, Y., Chang, X., Zhu, X., Luo, H., Hu, Z., Zou, X., & He, Q. (2007). Chemically modified silica gel with p-dimethylaminobenzaldehyde for selective solid-phase extraction and preconcentration of Cr (III), Cu (II), Ni (II), Pb (II) and Zn (II) by ICP-OES. Microchemical Journal, 87(1), 20-26. doi:10.1016/j.microc.2007.04.004
• Dakova, I., Vasileva, P., Karadjova, I., Karadjov, M., & Slaveykova, V. (2011). Solid phase extraction and diffusive gradients in thin films techniques for determination of total and labile concentrations of Cd (II), Cu (II), Ni (II) and Pb (II) in Black Sea water. International Journal of Environmental and Analytical Chemistry, 91(1), 62-73. doi:10.1080/03067310903195011
• El-Ashgar, N. M., El-Nahhal, I. M., Chehimi, M. M., Babonneau, F., & Livage, J. (2009). Preparation of ethylenediaminetriacetic acid silica-gel immobilised ligand system and its application for trace metal analysis in aqueous samples. International Journal of Environmental and Analytical Chemistry, 89(14), 1057-1069. doi:10.1080/03067310902717278
• Fan, Z., Hu, B., & Jiang, Z. (2005). Speciation analysis of vanadium in natural water samples by electrothermal vaporization inductively coupled plasma optical emission spectrometry after separation/preconcentration with thenoyltrifluoroacetone immobilized on microcrystalline naphthalene. Spectrochimica Acta Part B: Atomic Spectroscopy, 60(1), 65-71. doi:10.1016/j.sab.2004.10.004
• Fan, J., Wu, C., Wei, Y., Peng, C., & Peng, P. (2007). Preparation of xylenol orange functionalized silica gel as a selective solid phase extractor and its application for preconcentration—separation of mercury from waters. Journal of Hazardous Materials, 145(1-2), 323-330. doi:10.1016/j.jhazmat.2006.11.025
• Farajzadeh, M. A., Bahram, M., Zorita, S., & Mehr, B. G. (2009). Optimization and application of homogeneous liquid–liquid extraction in preconcentration of copper (II) in a ternary solvent system. Journal of Hazardous Materials, 161(2-3), 1535-1543. doi:10.1016/j.jhazmat.2008.05.041
• Ghaedi, M., Rezakhani, M., Khodadoust, S., Niknam, K., & Soylak, M. (2012). The solid phase extraction of some metal ions using palladium nanoparticles attached to silica gel chemically bonded by silica-bonded N-propylmorpholine as new sorbent prior to their determination by flame atomic absorption spectroscopy. The Scientific World Journal, 2012, 764195. doi:10.1100/2012/764195
• Ghaedi, M., Montazerozohori, M., Hekmati, A., & Roosta, M. (2013). Solid phase extraction of heavy metals on chemically modified silica-gel with 2-(3-silylpropylimino) methyl)-5-bromophenol in food samples. International Journal of Environmental Analytical Chemistry, 93(8), 843-857. doi:10.1080/03067319.2012.690148
• Goswami, A., & Singh, A. K. (2002a). 1, 8-Dihydroxyanthraquinone anchored on silica gel: synthesis and application as solid phase extractant for lead (II), zinc (II) and cadmium (II) prior to their determination by flame atomic absorption spectrometry. Talanta, 58(4), 669-678. doi:10.1016/S0039-9140(02)00374-0
• Goswami, A., & Singh, A. K. (2002b). Silica gel functionalized with resacetophenone: synthesis of a new chelating matrix and its application as metal ion collector for their flame atomic absorption spectrometric determination. Analytica Chimica Acta, 454(2), 229-240. doi:10.1016/S0003-2670(01)01552-5
• Gübbük, I. H., Hatay, I., Coşkun, A., & Ersöz, M. (2009). Immobilization of oxime derivative on silica gel for the preparation of new adsorbent. Journal of Hazardous Materials, 172(2-3), 1532-1537. doi:10.1016/j.jhazmat.2009.08.024
• Jamali, M. R., Assadi, Y., Shemirani, F., & Salavati-Niasari, M. (2007). Application of thiophene-2-carbaldehyde-modified mesoporous silica as a new sorbent for separation and preconcentration of palladium prior to inductively coupled plasma atomic emission spectrometric determination. Talanta, 71(4), 1524-1529. doi:10.1016/j.talanta.2006.07.034
• Jang, S. H., Min, B. G., Jeong, Y. G., Lyoo, W. S., & Lee, S. C. (2008). Removal of lead ions in aqueous solution by hydroxyapatite/polyurethane composite foams. Journal of Hazardous Materials, 152(3), 1285-1292. doi:10.1016/j.jhazmat.2007.08.003
• Javanbakht, M., Rudbaraki, H., Sohrabi, M. R., Attaran, A. M., & Badiei, A. (2010). Separation, pre-concentration and determination of trace amounts of lead (II) ions in environmental samples using two functionalised nanoporous silica gels containing a dipyridyl sub-unit. International Journal of Environmental and Analytical Chemistry, 90(13), 1014-1024. doi:10.1080/03067310903045471
• Khan, W. A., Arain, M. B., & Soylak, M. (2020). Nanomaterials-based solid phase extraction and solid phase microextraction for heavy metals food toxicity. Food and Chemical Toxicology, 145, 111704. doi:10.1016/j.fct.2020.111704
• Liska, I. (1993). On-line versus off-line solid-phase extraction in the determination of organic contaminants in water: advantages and limitations. Journal of Chromatography A, 655(2), 163-176. doi:10.1016/0021-9673(93)83220-M
• Liu, R., & Liang, P. (2008). Determination of trace lead in water samples by graphite furnace atomic absorption spectrometry after preconcentration with nanometer titanium dioxide immobilized on silica gel. Journal of Hazardous Materials, 152(1), 166-171. doi:10.1016/j.jhazmat.2007.06.081
• Liu, H., Zhang, M., Guo, Y., & Qiu, H. (2016). Solid-phase extraction of flavonoids in honey samples using carbamate-embedded triacontyl-modified silica sorbent. Food Chemistry, 204, 56-61. doi:10.1016/j.foodchem.2016.02.102
• Liu, H., Yu, H., Jin, P., Jiang, M., Zhu, G., Duan, Y., ..., & Qiu, H. (2020). Preparation of mesoporous silica materials functionalized with various amino-ligands and investigation of adsorption performances on aromatic acids. Chemical Engineering Journal, 379, 122405. doi:10.1016/j.cej.2019.122405
• Ngeontae, W., Aeungmaitrepirom, W., & Tuntulani, T. (2007). Chemically modified silica gel with aminothioamidoanthraquinone for solid phase extraction and preconcentration of Pb (II), Cu (II), Ni (II), Co (II) and Cd (II). Talanta, 71(3), 1075-1082. doi:10.1016/j.talanta.2006.05.094
• Nguyen, T. H. D., Huynh, T. T. T., Dang, M. H. D., Nguyen, L. H. T., Doan, T. L. H., Nguyen, T. P., ..., & Tran, P. H. (2022). Ionic liquid-immobilized silica gel as a new sorbent for solid-phase extraction of heavy metal ions in water samples. RSC Advances, 12(31), 19741-19750. doi:10.1039/D2RA02980D
• Sadeghi, S., & Sheikhzadeh, E. (2009). Solid phase extraction using silica gel modified with murexide for preconcentration of uranium (VI) ions from water samples. Journal of Hazardous Materials, 163(2-3), 861-868. doi:10.1016/j.jhazmat.2008.07.053
• Sharma, R. K., Pandey, A., Gulati, S., & Adholeya, A. (2012). An optimized procedure for preconcentration, determination and on-line recovery of palladium using highly selective diphenyldiketone-monothiosemicarbazone modified silica gel. Journal of Hazardous Materials, 209, 285-292. doi:10.1016/j.jhazmat.2012.01.022
• Vergara-Barberan, M., Lerma-García, M. J., Simó-Alfonso, E. F., & Herrero-Martínez, J. M. (2017). Polymeric sorbents modified with gold and silver nanoparticles for solid-phase extraction of proteins followed by MALDI-TOF analysis. Microchimica Acta, 184, 1683-1690. doi:10.1007/s00604-017-2168-5
• Yan, H., Xu, Y., Lu, Y., & Xing, W. (2017). Reduced graphene oxide-based solid-phase extraction for the enrichment and detection of microRNA. Analytical Chemistry, 89(19), 10137-10140. doi:10.1021/acs.analchem.7b03138
• Zou, X., Cui, Y., Chang, X., Zhu, X., Hu, Z., & Yang, D. (2009). Silica gel surface modified with sulfanilamide for selective solid-phase extraction of Cu (II), Zn (II) and Ni (II). International Journal of Environmental and Analytical Chemistry, 89(14), 1043-1055. doi:10.1080/03067310902995148