Araştırma Makalesi
BibTex RIS Kaynak Göster

Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2)

Yıl 2020, Cilt: 10 Sayı: 3, 1886 - 1898, 01.09.2020
https://doi.org/10.21597/jist.725624

Öz

Polymers of Intrinsic Microporosity (PIMs) are documented as suitable materials for organic adsorption applications. Intrinsic porous structure along with a solution-processability behaviour make them attractive for the adsorption of organic contaminants from water. In this research, PIM-2 powder was synthesised and the exploitation of PIM-2 for aniline removal was studied using a batch adsorption process. The effect of several variables were explored including initial aniline concentration, adsorption time and temperature. Adsorption reached the equilibrium after five hours and experimental adsorption capacity (qe, exp) was found as 79.7 mg g-1 for aniline at pH 6 and 298K. Isotherm (Langmuir, Freundlich and Liu) and kinetic models (pseudo first order and pseudo second order) and elovich model were applied using non-linear regression analysis. In addition, various errors analysis approaches were used to determine the most appropriate isotherm and kinetic models. Pseudo second order model and Liu isotherm fitted well for aniline adsorption. Maximum adsorption capacity (qm) were computed as 82.4 mg g-1 for aniline at pH 6 and 298 K based on the Liu adsorption model. Thermodynamic studies revealed that the adsorption process was physical, spontaneous and exothermic.

Kaynakça

  • Ahmadi M, Mohammadian M, Khosravi-Nikou MR, Baghban A, 2019. Experimental, Kinetic, and Thermodynamic Studies of Adsorptive Desulfurization and Denitrogenation of Model Fuels Using Novel Mesoporous Materials. Journal of Hazardous Materials, 374: 129-139.
  • An F, Feng X, Gao B, 2010. Adsorption Property and Mechanism of Composite Adsorbent PMMA/SiO2 for Aniline. Journal of Hazardous Materials, 178 (1): 499-504.
  • Budd PM, Ghanem BS, Makhseed S, McKeown NB, Msayib KJ, Tattershall CE, 2004. Polymers of Intrinsic Microporosity (PIMs): Robust, Solution-Processable, Organic Nanoporous Materials. Chemical Communications, (2): 230-231.
  • Budd PM, McKeown NB, Fritsch D, 2005. Free Volume and Intrinsic Microporosity in Polymers. Journal of Materials Chemistry, 15 (20): 1977-1986.
  • Budd PM, McKeown NB, Ghanem BS, Msayib KJ, Fritsch D, Starannikova L, Belov N, Sanfirova O, Yampolskii Y, Shantarovich V, 2008. Gas Permeation Parameters and Other Physicochemical Properties of a Polymer of Intrinsic Microporosity: Polybenzodioxane PIM-1. Journal of Membrane Science, 325 (2): 851-860.
  • Foo KY, Hameed BH, 2010. Insights into the Modeling of Adsorption Isotherm Systems. Chemical Engineering Journal, 156 (1): 2-10.
  • Freundlich H, 1906. Over the Adsorption in Solution. Journal of Physical Chemistry, 57: 385-471.
  • Fuoco A, Satilmis B, Uyar T, Monteleone M, Esposito E, Muzzi C, Tocci E, Longo M, De Santo MP, Lanč M, Friess K, Vopička O, Izák P, Jansen JC, 2020. Comparison of Pure and Mixed Gas Permeation of the Highly Fluorinated Polymer of Intrinsic Microporosity PIM-2 under Dry and Humid Conditions: Experiment and Modelling. Journal of Membrane Science, 594: 117460.
  • Gan Y, Chen G, Sang Y, Zhou F, Man R, Huang J, 2019. Oxygen-Rich Hyper-Cross-Linked Polymers with Hierarchical Porosity for Aniline Adsorption. Chemical Engineering Journal, 368: 29-36.
  • Gao D-W, Hu Q, Pan H, Jiang J, Wang P, 2015. High-Capacity Adsorption of Aniline Using Surface Modification of Lignocellulose-Biomass Jute Fibers. Bioresource Technology, 193: 507-512.
  • Gheewala SH, Annachhatre AP, 1997. Biodegradation of Aniline. Water Science and Technology, 36 (10): 53-63.
  • Ghosal PS, Gupta AK, 2017. Determination of Thermodynamic Parameters from Langmuir Isotherm Constant-Revisited. Journal of Molecular Liquids, 225: 137-146.
  • Günay A, Arslankaya E, Tosun İ, 2007. Lead Removal from Aqueous Solution by Natural and Pretreated Clinoptilolite: Adsorption Equilibrium and Kinetics. Journal of Hazardous Materials, 146 (1): 362-371.
  • Guo F, Wang Y, Chen X, Chen M, He W, Chen Z, 2019. Supermacroporous Polydivinylbenzene Cryogels with High Surface Area: Synthesis by Solvothermal Postcrosslinking and Their Adsorption Behaviors for Carbon Dioxide and Aniline. Journal of Applied Polymer Science, 136 (27): 47716.
  • Guo H, Yang F, Chai X, Jiao Z, Li C, 2012. Synthesis of Novel Calix[6]-1,4-Crown-Based Netty Polymer and Its Excellent Adsorption Capabilities for Aniline Derivatives. Iranian Polymer Journal, 21 (7): 451-456.
  • Harrache Z, Abbas M, Aksil T, Trari M, 2019. Thermodynamic and Kinetics Studies on Adsorption of Indigo Carmine from Aqueous Solution by Activated Carbon. Microchemical Journal, 144: 180-189.
  • Ho YS, McKay G, 1999. Pseudo-Second Order Model for Sorption Processes. Process Biochemistry, 34 (5): 451-465.
  • Hu Q, Gao D-W, Pan H, Hao L, Wang P, 2014. Equilibrium and Kinetics of Aniline Adsorption onto Crosslinked Sawdust-Cyclodextrin Polymers. Rsc Advances, 4 (75): 40071-40077.
  • Huang Y, Xu Y, He Q, Cao Y, Du B, 2014. Rapid Removal of Aniline from Contaminated Water by a Novel Polymeric Adsorbent. Water Environment Research, 86 (1): 20-27.
  • Igberase E, Ofomaja A, Osifo PO, 2019. Enhanced Heavy Metal Ions Adsorption by 4‑Aminobenzoic Acid Grafted on Chitosan/Epichlorohydrin Composite: Kinetics, Isotherms, Thermodynamics and Desorption Studies. International Journal of Biological Macromolecules, 123: 664-676.
  • Khan EA, Shahjahan, Khan TA, 2018. Adsorption of Methyl Red on Activated Carbon Derived from Custard Apple (Annona Squamosa) Fruit Shell: Equilibrium Isotherm and Kinetic Studies. Journal of Molecular Liquids, 249: 1195-1211.
  • Kuang W, Liu Y-N, Huang J, 2017. Phenol-Modified Hyper-Cross-Linked Resins with Almost All Micro/Mesopores and Their Adsorption to Aniline. Journal of Colloid and Interface Science, 487: 31-37.
  • Lagergren S, 1898. About the Theory of So Called Adsorption of Soluble Substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24 (4): 1-39.
  • Langmuir I, 1916. The Constitution and Fundamental Properties of Solids and Liquids. Part I. Solids. Journal of the American Chemical Society, 38 (11): 2221-2295.
  • Lima ÉC, Adebayo MA, Machado FM, 2015. Carbon Nanomaterials as Adsorbents for Environmental and Biological Applications.Carbon Nanostructures. Springer, pp. 33-71, Brazil.
  • Lima EC, Hosseini-Bandegharaei A, Moreno-Piraján JC, Anastopoulos I, 2019. A Critical Review of the Estimation of the Thermodynamic Parameters on Adsorption Equilibria. Wrong Use of Equilibrium Constant in the Van't Hoof Equation for Calculation of Thermodynamic Parameters of Adsorption. Journal of Molecular Liquids, 273: 425-434.
  • Liu Y, Liu X, Dong W, Zhang L, Kong Q, Wang W, 2017. Efficient Adsorption of Sulfamethazine onto Modified Activated Carbon: A Plausible Adsorption Mechanism. Scientific Reports, 7 (1): 12437.
  • Liu Y, Xu H, Yang S-F, Tay J-H, 2003. A General Model for Biosorption of Cd2+, Cu2+ and Zn2+ by Aerobic Granules. Journal of Biotechnology, 102 (3): 233-239.
  • McKeown NB, Budd PM, 2006. Polymers of Intrinsic Microporosity (PIMs): Organic Materials for Membrane Separations, Heterogeneous Catalysis and Hydrogen Storage. Chemical Society Reviews, 35 (8): 675-683.
  • McKeown NB, Budd PM, Msayib KJ, Ghanem BS, Kingston HJ, Tattershall CE, Makhseed S, Reynolds KJ, Fritsch D, 2005. Polymers of Intrinsic Microporosity (PIMs): Bridging the Void between Microporous and Polymeric Materials. Chemistry-a European Journal, 11 (9): 2610-2620.
  • McLintock IS, 1967. The Elovich Equation in Chemisorption Kinetics. Nature, 216 (5121): 1204-1205.
  • Midda MO, Srivastava VC, Kushwaha JP, 2018. Modelling Single and Binary Adsorptive Behaviour of Aniline and Nitrobenzene onto Granular Activated Carbon. Physics and Chemistry of Liquids, 58 (2): 150-163.
  • Rahdar A, Rahdar S, Labuto G, 2020. Environmentally Friendly Synthesis of Fe2o3@Sio2 Nanocomposite: Characterization and Application as an Adsorbent to Aniline Removal from Aqueous Solution. Environmental Science and Pollution Research, 27 (9): 9181-9191.
  • Satilmis B, 2020. Amidoxime Modified Polymers of Intrinsic Microporosity (PIM-1); a Versatile Adsorbent for Efficient Removal of Charged Dyes; Equilibrium, Kinetic and Thermodynamic Studies. Journal of Polymers and the Environment, 28 (3): 995-1009.
  • Satilmis B, Uyar T, 2018. Removal of Aniline from Air and Water by Polymers of Intrinsic Microporosity (PIM-1) Electrospun Ultrafine Fibers. Journal of Colloid and Interface Science, 516: 317-324.
  • Satilmis B, Uyar T, 2019. Development of Superhydrophobic Electrospun Fibrous Membrane of Polymers of Intrinsic Microporosity (PIM-2). European Polymer Journal, 112: 87-94.
  • Sato H, Nakajo S, Oishi Y, Shibasaki Y, 2018. Synthesis of Linear Polymer of Intrinsic Microporosity from 5,5',6,6'-Tetrahydroxy-3,3,3',3'-Tetramethylspirobisindane and Decafluorobiphenyl. Reactive & Functional Polymers, 125: 70-76.
  • Sriprom P, Assawasaengrat P, Neramittagapong A, Neramittagapong S, 2014. Catalytic Wet-Air Oxidation of Aniline Removal from Synthetic Wastewater. Advanced Materials Research, 931-932: 32-36.
  • Wang X, Mao X, Huang J, 2018. Hierarchical Porous Hyper-Cross-Linked Polymers Modified with Phenolic Hydroxyl Groups and Their Efficient Adsorption of Aniline from Aqueous Solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 558: 80-87.
  • Xiao G, Long L, 2012. Efficient Removal of Aniline by a Water-Compatible Microporous and Mesoporous Hyper-Cross-Linked Resin and Xad-4 Resin: A Comparative Study. Applied Surface Science, 258 (17): 6465-6471.
  • Yi Z, Huajie L, Mingchun L, Meihua X, 2020. Adsorption of Aniline on Aminated Chitosan/Graphene Oxide Composite Material. Journal of Molecular Structure, 1209: 127973.
  • Yu W, Xu C, Yin C, Yu S, Sun W, Xie C, Xian M, 2018. Mechanism of Aniline Adsorption on Post-Crosslinked Resins: Pore Structure and Oxygen Content. Water Science and Technology, 78 (10): 2096-2103.
  • Zeng X, Huang J, 2020. Anisole-Modified Hyper-Cross-Linked Resins for Efficient Adsorption of Aniline from Aqueous Solution. Journal of Colloid and Interface Science, 569: 177-183.
  • Zhao D, Zhao L, Zhu C-S, Shen X, Zhang X, Sha B, 2009. Comparative Study of Polymer Containing Β-Cyclodextrin and –Cooh for Adsorption toward Aniline, 1-Naphthylamine and Methylene Blue. Journal of Hazardous Materials, 171 (1): 241-246.
  • Zhou J-X, Luo X-S, Liu X, Qiao Y, Wang P, Mecerreyes D, Bogliotti N, Chen S-L, Huang M-H, 2018. Azo-Linked Porous Organic Polymers: Robust and Time-Efficient Synthesis Via Nabh4-Mediated Reductive Homocoupling on Polynitro Monomers and Adsorption Capacity Towards Aniline in Water. Journal of Materials Chemistry A, 6 (14): 5608-5612.

Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2)

Yıl 2020, Cilt: 10 Sayı: 3, 1886 - 1898, 01.09.2020
https://doi.org/10.21597/jist.725624

Öz

Polymers of Intrinsic Microporosity (PIMs) are documented as suitable materials for organic adsorption applications. Intrinsic porous structure along with a solution-processability behaviour make them attractive for the adsorption of organic contaminants from water. In this research, PIM-2 powder was synthesised and the exploitation of PIM-2 for aniline removal was studied using a batch adsorption process. The effect of several variables were explored including initial aniline concentration, adsorption time and temperature. Adsorption reached the equilibrium after five hours and experimental adsorption capacity (qe, exp) was found as 79.7 mg g-1 for aniline at pH 6 and 298K. Isotherm (Langmuir, Freundlich and Liu) and kinetic models (pseudo first order and pseudo second order) and elovich model were applied using non-linear regression analysis. In addition, various errors analysis approaches were used to determine the most appropriate isotherm and kinetic models. Pseudo second order model and Liu isotherm fitted well for aniline adsorption. Maximum adsorption capacity (qm) were computed as 82.4 mg g-1 for aniline at pH 6 and 298 K based on the Liu adsorption model. Thermodynamic studies revealed that the adsorption process was physical, spontaneous and exothermic.

Kaynakça

  • Ahmadi M, Mohammadian M, Khosravi-Nikou MR, Baghban A, 2019. Experimental, Kinetic, and Thermodynamic Studies of Adsorptive Desulfurization and Denitrogenation of Model Fuels Using Novel Mesoporous Materials. Journal of Hazardous Materials, 374: 129-139.
  • An F, Feng X, Gao B, 2010. Adsorption Property and Mechanism of Composite Adsorbent PMMA/SiO2 for Aniline. Journal of Hazardous Materials, 178 (1): 499-504.
  • Budd PM, Ghanem BS, Makhseed S, McKeown NB, Msayib KJ, Tattershall CE, 2004. Polymers of Intrinsic Microporosity (PIMs): Robust, Solution-Processable, Organic Nanoporous Materials. Chemical Communications, (2): 230-231.
  • Budd PM, McKeown NB, Fritsch D, 2005. Free Volume and Intrinsic Microporosity in Polymers. Journal of Materials Chemistry, 15 (20): 1977-1986.
  • Budd PM, McKeown NB, Ghanem BS, Msayib KJ, Fritsch D, Starannikova L, Belov N, Sanfirova O, Yampolskii Y, Shantarovich V, 2008. Gas Permeation Parameters and Other Physicochemical Properties of a Polymer of Intrinsic Microporosity: Polybenzodioxane PIM-1. Journal of Membrane Science, 325 (2): 851-860.
  • Foo KY, Hameed BH, 2010. Insights into the Modeling of Adsorption Isotherm Systems. Chemical Engineering Journal, 156 (1): 2-10.
  • Freundlich H, 1906. Over the Adsorption in Solution. Journal of Physical Chemistry, 57: 385-471.
  • Fuoco A, Satilmis B, Uyar T, Monteleone M, Esposito E, Muzzi C, Tocci E, Longo M, De Santo MP, Lanč M, Friess K, Vopička O, Izák P, Jansen JC, 2020. Comparison of Pure and Mixed Gas Permeation of the Highly Fluorinated Polymer of Intrinsic Microporosity PIM-2 under Dry and Humid Conditions: Experiment and Modelling. Journal of Membrane Science, 594: 117460.
  • Gan Y, Chen G, Sang Y, Zhou F, Man R, Huang J, 2019. Oxygen-Rich Hyper-Cross-Linked Polymers with Hierarchical Porosity for Aniline Adsorption. Chemical Engineering Journal, 368: 29-36.
  • Gao D-W, Hu Q, Pan H, Jiang J, Wang P, 2015. High-Capacity Adsorption of Aniline Using Surface Modification of Lignocellulose-Biomass Jute Fibers. Bioresource Technology, 193: 507-512.
  • Gheewala SH, Annachhatre AP, 1997. Biodegradation of Aniline. Water Science and Technology, 36 (10): 53-63.
  • Ghosal PS, Gupta AK, 2017. Determination of Thermodynamic Parameters from Langmuir Isotherm Constant-Revisited. Journal of Molecular Liquids, 225: 137-146.
  • Günay A, Arslankaya E, Tosun İ, 2007. Lead Removal from Aqueous Solution by Natural and Pretreated Clinoptilolite: Adsorption Equilibrium and Kinetics. Journal of Hazardous Materials, 146 (1): 362-371.
  • Guo F, Wang Y, Chen X, Chen M, He W, Chen Z, 2019. Supermacroporous Polydivinylbenzene Cryogels with High Surface Area: Synthesis by Solvothermal Postcrosslinking and Their Adsorption Behaviors for Carbon Dioxide and Aniline. Journal of Applied Polymer Science, 136 (27): 47716.
  • Guo H, Yang F, Chai X, Jiao Z, Li C, 2012. Synthesis of Novel Calix[6]-1,4-Crown-Based Netty Polymer and Its Excellent Adsorption Capabilities for Aniline Derivatives. Iranian Polymer Journal, 21 (7): 451-456.
  • Harrache Z, Abbas M, Aksil T, Trari M, 2019. Thermodynamic and Kinetics Studies on Adsorption of Indigo Carmine from Aqueous Solution by Activated Carbon. Microchemical Journal, 144: 180-189.
  • Ho YS, McKay G, 1999. Pseudo-Second Order Model for Sorption Processes. Process Biochemistry, 34 (5): 451-465.
  • Hu Q, Gao D-W, Pan H, Hao L, Wang P, 2014. Equilibrium and Kinetics of Aniline Adsorption onto Crosslinked Sawdust-Cyclodextrin Polymers. Rsc Advances, 4 (75): 40071-40077.
  • Huang Y, Xu Y, He Q, Cao Y, Du B, 2014. Rapid Removal of Aniline from Contaminated Water by a Novel Polymeric Adsorbent. Water Environment Research, 86 (1): 20-27.
  • Igberase E, Ofomaja A, Osifo PO, 2019. Enhanced Heavy Metal Ions Adsorption by 4‑Aminobenzoic Acid Grafted on Chitosan/Epichlorohydrin Composite: Kinetics, Isotherms, Thermodynamics and Desorption Studies. International Journal of Biological Macromolecules, 123: 664-676.
  • Khan EA, Shahjahan, Khan TA, 2018. Adsorption of Methyl Red on Activated Carbon Derived from Custard Apple (Annona Squamosa) Fruit Shell: Equilibrium Isotherm and Kinetic Studies. Journal of Molecular Liquids, 249: 1195-1211.
  • Kuang W, Liu Y-N, Huang J, 2017. Phenol-Modified Hyper-Cross-Linked Resins with Almost All Micro/Mesopores and Their Adsorption to Aniline. Journal of Colloid and Interface Science, 487: 31-37.
  • Lagergren S, 1898. About the Theory of So Called Adsorption of Soluble Substances. Kungliga Svenska Vetenskapsakademiens Handlingar, 24 (4): 1-39.
  • Langmuir I, 1916. The Constitution and Fundamental Properties of Solids and Liquids. Part I. Solids. Journal of the American Chemical Society, 38 (11): 2221-2295.
  • Lima ÉC, Adebayo MA, Machado FM, 2015. Carbon Nanomaterials as Adsorbents for Environmental and Biological Applications.Carbon Nanostructures. Springer, pp. 33-71, Brazil.
  • Lima EC, Hosseini-Bandegharaei A, Moreno-Piraján JC, Anastopoulos I, 2019. A Critical Review of the Estimation of the Thermodynamic Parameters on Adsorption Equilibria. Wrong Use of Equilibrium Constant in the Van't Hoof Equation for Calculation of Thermodynamic Parameters of Adsorption. Journal of Molecular Liquids, 273: 425-434.
  • Liu Y, Liu X, Dong W, Zhang L, Kong Q, Wang W, 2017. Efficient Adsorption of Sulfamethazine onto Modified Activated Carbon: A Plausible Adsorption Mechanism. Scientific Reports, 7 (1): 12437.
  • Liu Y, Xu H, Yang S-F, Tay J-H, 2003. A General Model for Biosorption of Cd2+, Cu2+ and Zn2+ by Aerobic Granules. Journal of Biotechnology, 102 (3): 233-239.
  • McKeown NB, Budd PM, 2006. Polymers of Intrinsic Microporosity (PIMs): Organic Materials for Membrane Separations, Heterogeneous Catalysis and Hydrogen Storage. Chemical Society Reviews, 35 (8): 675-683.
  • McKeown NB, Budd PM, Msayib KJ, Ghanem BS, Kingston HJ, Tattershall CE, Makhseed S, Reynolds KJ, Fritsch D, 2005. Polymers of Intrinsic Microporosity (PIMs): Bridging the Void between Microporous and Polymeric Materials. Chemistry-a European Journal, 11 (9): 2610-2620.
  • McLintock IS, 1967. The Elovich Equation in Chemisorption Kinetics. Nature, 216 (5121): 1204-1205.
  • Midda MO, Srivastava VC, Kushwaha JP, 2018. Modelling Single and Binary Adsorptive Behaviour of Aniline and Nitrobenzene onto Granular Activated Carbon. Physics and Chemistry of Liquids, 58 (2): 150-163.
  • Rahdar A, Rahdar S, Labuto G, 2020. Environmentally Friendly Synthesis of Fe2o3@Sio2 Nanocomposite: Characterization and Application as an Adsorbent to Aniline Removal from Aqueous Solution. Environmental Science and Pollution Research, 27 (9): 9181-9191.
  • Satilmis B, 2020. Amidoxime Modified Polymers of Intrinsic Microporosity (PIM-1); a Versatile Adsorbent for Efficient Removal of Charged Dyes; Equilibrium, Kinetic and Thermodynamic Studies. Journal of Polymers and the Environment, 28 (3): 995-1009.
  • Satilmis B, Uyar T, 2018. Removal of Aniline from Air and Water by Polymers of Intrinsic Microporosity (PIM-1) Electrospun Ultrafine Fibers. Journal of Colloid and Interface Science, 516: 317-324.
  • Satilmis B, Uyar T, 2019. Development of Superhydrophobic Electrospun Fibrous Membrane of Polymers of Intrinsic Microporosity (PIM-2). European Polymer Journal, 112: 87-94.
  • Sato H, Nakajo S, Oishi Y, Shibasaki Y, 2018. Synthesis of Linear Polymer of Intrinsic Microporosity from 5,5',6,6'-Tetrahydroxy-3,3,3',3'-Tetramethylspirobisindane and Decafluorobiphenyl. Reactive & Functional Polymers, 125: 70-76.
  • Sriprom P, Assawasaengrat P, Neramittagapong A, Neramittagapong S, 2014. Catalytic Wet-Air Oxidation of Aniline Removal from Synthetic Wastewater. Advanced Materials Research, 931-932: 32-36.
  • Wang X, Mao X, Huang J, 2018. Hierarchical Porous Hyper-Cross-Linked Polymers Modified with Phenolic Hydroxyl Groups and Their Efficient Adsorption of Aniline from Aqueous Solution. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 558: 80-87.
  • Xiao G, Long L, 2012. Efficient Removal of Aniline by a Water-Compatible Microporous and Mesoporous Hyper-Cross-Linked Resin and Xad-4 Resin: A Comparative Study. Applied Surface Science, 258 (17): 6465-6471.
  • Yi Z, Huajie L, Mingchun L, Meihua X, 2020. Adsorption of Aniline on Aminated Chitosan/Graphene Oxide Composite Material. Journal of Molecular Structure, 1209: 127973.
  • Yu W, Xu C, Yin C, Yu S, Sun W, Xie C, Xian M, 2018. Mechanism of Aniline Adsorption on Post-Crosslinked Resins: Pore Structure and Oxygen Content. Water Science and Technology, 78 (10): 2096-2103.
  • Zeng X, Huang J, 2020. Anisole-Modified Hyper-Cross-Linked Resins for Efficient Adsorption of Aniline from Aqueous Solution. Journal of Colloid and Interface Science, 569: 177-183.
  • Zhao D, Zhao L, Zhu C-S, Shen X, Zhang X, Sha B, 2009. Comparative Study of Polymer Containing Β-Cyclodextrin and –Cooh for Adsorption toward Aniline, 1-Naphthylamine and Methylene Blue. Journal of Hazardous Materials, 171 (1): 241-246.
  • Zhou J-X, Luo X-S, Liu X, Qiao Y, Wang P, Mecerreyes D, Bogliotti N, Chen S-L, Huang M-H, 2018. Azo-Linked Porous Organic Polymers: Robust and Time-Efficient Synthesis Via Nabh4-Mediated Reductive Homocoupling on Polynitro Monomers and Adsorption Capacity Towards Aniline in Water. Journal of Materials Chemistry A, 6 (14): 5608-5612.
Toplam 45 adet kaynakça vardır.

Ayrıntılar

Birincil Dil İngilizce
Konular Kimya Mühendisliği
Bölüm Kimya / Chemistry
Yazarlar

Bekir Satılmış 0000-0002-3704-8628

Yayımlanma Tarihi 1 Eylül 2020
Gönderilme Tarihi 22 Nisan 2020
Kabul Tarihi 18 Haziran 2020
Yayımlandığı Sayı Yıl 2020 Cilt: 10 Sayı: 3

Kaynak Göster

APA Satılmış, B. (2020). Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2). Journal of the Institute of Science and Technology, 10(3), 1886-1898. https://doi.org/10.21597/jist.725624
AMA Satılmış B. Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2). Iğdır Üniv. Fen Bil Enst. Der. Eylül 2020;10(3):1886-1898. doi:10.21597/jist.725624
Chicago Satılmış, Bekir. “Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2)”. Journal of the Institute of Science and Technology 10, sy. 3 (Eylül 2020): 1886-98. https://doi.org/10.21597/jist.725624.
EndNote Satılmış B (01 Eylül 2020) Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2). Journal of the Institute of Science and Technology 10 3 1886–1898.
IEEE B. Satılmış, “Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2)”, Iğdır Üniv. Fen Bil Enst. Der., c. 10, sy. 3, ss. 1886–1898, 2020, doi: 10.21597/jist.725624.
ISNAD Satılmış, Bekir. “Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2)”. Journal of the Institute of Science and Technology 10/3 (Eylül 2020), 1886-1898. https://doi.org/10.21597/jist.725624.
JAMA Satılmış B. Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2). Iğdır Üniv. Fen Bil Enst. Der. 2020;10:1886–1898.
MLA Satılmış, Bekir. “Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2)”. Journal of the Institute of Science and Technology, c. 10, sy. 3, 2020, ss. 1886-98, doi:10.21597/jist.725624.
Vancouver Satılmış B. Adsorption of Aniline from Aqueous System by Highly Fluorinated Polymers of Intrinsic Microporosity (PIM-2). Iğdır Üniv. Fen Bil Enst. Der. 2020;10(3):1886-98.