Araştırma Makalesi
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Investigation of the Effect of Aluminum Trihydroxide on the Mechanical and Fire Properties of EPDM Rubber

Yıl 2024, Cilt: 1 Sayı: 2, 77 - 83

Öz

In this study, the effect of aluminum trihydroxide (Al(OH)_3) non-flammable fillers on the rheological, mechanical, UL-94 flammability test and limit oxygen index (LOI) properties of EPDM rubbers with different rates of Al(OH)_3 non-flammable additive was investigated Al(OH)_3 was added to EPDM rubber at rates of 10, 30, 50 percent. EPDM rubbers with non-flammable additives were prepared using laboratory type banbury, vulcanized in the press and test plates were obtained. Minimum torque (ML) and maximum torque (MH) increased with the increase in the amount of Al(OH)3. The hardness value of EPDM rubber, which was 66 Shore A, was obtained as 87 Shore A with the addition of Al(OH)3. While the tensile strength and elongation at break decreased, the amount of permanent deformation and abrasive wear increased. Al(OH)3 added to EPDM rubber at a rate of 25phr reduced the horizontal burning rate. The LOI value of EPDM rubber, which was 22.3%, increased with the addition of Al(OH)_3, and was obtained as 37.4%.

Kaynakça

  • Balachandran Nair, A., Kurian, P. and Joseph, R. (2012). Effect of aluminium hydroxide, chlorinated polyethylene, decabromo biphenyl oxide and expanded graphite on thermal, mechanical and sorption properties of oil-extended ethylene–propylene–diene terpolymer rubber. Materials & Design, 40, 80–89. doi: 10.1016/j.matdes.2012.03.032
  • Benjamin, Z., Dietmar, S. and Bernhard, S. (2019). Mechanical and fire properties of multicomponent flame retardant EPDM rubbers using aluminum trihydroxide, ammonium polyphosphate, and polyaniline. Materials, 12, 1932. doi:10.3390/ma12121932
  • Canaud, C., Visconte, L.L.Y. and Nunes, R.C.R. (2001). Mechanical and flammability properties of ATH-filled EPDM compositions. Macromolecular Materials and Engineering. 286, 377-381.
  • Di, Z., Zheng, W., Yue, Y., Jingjing, L., Chunqing, H., Ning, Q., Xiangyang, P., Zhen, H. and Pengfei, F. (2023). Effect of aluminum hydroxide (ATH) content on free volumes and water barrier property of silicone rubber. 4th Japan-China Joint Workshop on Positron Science (JWPS2019) JJAP Conf. Proc., 011203.
  • Ekwueme, C C. and Igwe, I.O. (2018). Cure characteristics and mechanical properties of pineapple leaf fibre filled natural rubber, Journal of Minerals and Materials Characterization and Engineering, 6, 601-617. doi: 10.4236/jmmce.2018.66043.
  • Fu, S.Y., Feng, X.Q., Lauke, B. and Mai, Y.W. (2008). Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites. Composites Part B, 39(6), 933–961. doi:10.1016/j.compositesb.2008.01.002
  • Hull, T.R., Witkowski, A. and Hollingbery, L. (2011). Fire retardant action of mineral fillers. Polymer Degradation and Stability, 96(8), 1462–1469. doi: 10.1016/j.polymdegradstab.2011.05.006
  • Hornsby, P.R. (2001). Fire retardant fillers for polymers. International Materials Reviews, 46(4), 199–210. doi: 10.1179/095066001771048763
  • Ibarra, L., Posadas, P. and Esteban-Martínez, M. (2005). A comparative study of the effect of some paraffinic oils on rheological and dynamic properties and behavior at low temperature in EPDM rubber compounds. Journal of Applied Polymer Science, 97(5), 1825–1834. doi:10.1002/app.21954
  • Khattab, M.A., Feteha A.H.F., Sadik, W.A. and Abdel-Bary, E.M. (2016). Effect of aluminium trihydrate as flame retardant on properties of a thermoplastic rubber nanocomposite. Fire and Materials, 41(6), 688-699. doi: 10.1002/fam.2411
  • Levchik, S.V. and Weil, E.D. (2008). Developments in phosphorus flame retardants. Advances in Fire Retardant Materials, 41–66. doi: 10.1533/9781845694701.1.41
  • Maiti, M., Basak, G.C., Srivastava, V.K. and Jasra, R.V. (2016). Mesoporous silica reinforced polybutadiene rubber hybrid composite, International Journal of Industrial Chemistry, 7, 131–141. doi: 10.1007/s40090-015-0062-8
  • Natinee, L., Alif, W., Azizon, K. and Tadamoto, S. (2019). Mechanical, thermal and fire retardant Characteristics of NR/PP/ATH thermoplastic vulcanizates. Walailak Journal of Science and Technology (WJST). 16(10), 723-737.
  • Tang, G., Hu, Y. and Song, L. (2013). Study on the Flammability and Thermal Degradation of a Novel Intumescent Flame Retardant EPDM Composite. Procedia Engineering, 62, 371–376. doi: 10.1016/j.proeng.2013.08.078
  • Surya, I. and Khosman, H. (2020). The compounds of montmorillonite-filled natural rubber: Cure rate index, swelling and hardness properties. AIP Conference Proceedings, 2237(1). doi:10.1063/5.0005218
  • Surya, I., Sukeksi, L. and Hayeemasae, N. (2018). Studies on cure index, swelling behaviour, tensile and thermooxidative properties of natural rubber compounds in the presence of alkanolamide. IOP Conference Series: Materials Science and Engineering, 309, 012060. doi:10.1088/1757-899X/309/1/012060
  • Wan, L., Deng, C., Zhao, Z.-Y., Chen, H. and Wang, Y.-Z. (2020). Flame Retardation of Natural Rubber: Strategy and Recent Progress. Polymers, 12(2), 429. doi: 10.3390/polym12020429
  • Weil, E.D. and Levchik, Sergei. (2009). Flame retardants for plastics and textiles: Practical applications. 1-297.
  • Zhang, X., Guo, F., Chen, J., Wang, G. and Liu, H. (2005). Investigation of interfacial modification for flame retardant ethylene vinyl acetate copolymer/alumina trihydrate nanocomposites. Polymer Degradation and Stability. 87, 411-418.
  • Zhao, W., Kumar Kundu, C., Li, Z., Li, X. and Zhang, Z. (2021). Flame retardant treatments for polypropylene: Strategies and recent advances. Composites Part A: Applied Science and Manufacturing, 145, 106382. doi: 10.1016/j.compositesa.2021.106382
  • Zirnstein, B., Tabaka, W., Frasca, D., Schulze, D. and Schartel, B. (2018). Graphene/hydrogenated acrylonitrile-butadiene rubber nanocomposites: Dispersion, curing, mechanical reinforcement, multifunctional filler. Polymer Testing, 66, 268–279. doi: 10.1016/j.polymertesting.2018.01.035

EPDM Kauçuğun Mekanik ve Yanma Özelliklerine Alüminyum Trihidroksitin Etkisinin İncelenmesi

Yıl 2024, Cilt: 1 Sayı: 2, 77 - 83

Öz

Bu çalışmada farklı oranlarda alüminyum trihidroksit (Al(OH)_3) yanmaz katkı ilaveli EPDM kauçukların reolojik, mekanik, UL94 yanmazlık ve limit oksijen indeksi (LOI) özelliklerine Al(OH)_3 katkısının etkisi incelenmiştir. EPDM kauçuğuna Al(OH)_3 ağırlıkça % 10, 30, 50 oranlarında ilave edilmiştir. Laboratuvar tipi banbury kullanılarak Al(OH)_3 katkılı EPDM kauçukları hazırlanmış, preste vulkanize edilmiş ve test plakaları elde edilmiştir. Al(OH)_3 miktarının artması ile minimum tork (ML) ve maksimum tork (MH) artmıştır. EPDM kauçuğun 66 Shore A olan sertlik değeri Al(OH)_3 ilavesi ile 87 Shore A elde edilmiştir. Çekme mukavemeti ve kopma uzaması azalırken kalıcı deformasyon ve abrasif aşınma miktarı artmıştır. EPDM kauçuğuna ilave edilen 25phr oranındaki Al(OH)_3 yatay yanma hızını azaltmıştır. EPDM kauçuğunun %22.3 olan LOI değeri Al(OH)3 ilavesi ile %37.4 elde edilmiştir.

Kaynakça

  • Balachandran Nair, A., Kurian, P. and Joseph, R. (2012). Effect of aluminium hydroxide, chlorinated polyethylene, decabromo biphenyl oxide and expanded graphite on thermal, mechanical and sorption properties of oil-extended ethylene–propylene–diene terpolymer rubber. Materials & Design, 40, 80–89. doi: 10.1016/j.matdes.2012.03.032
  • Benjamin, Z., Dietmar, S. and Bernhard, S. (2019). Mechanical and fire properties of multicomponent flame retardant EPDM rubbers using aluminum trihydroxide, ammonium polyphosphate, and polyaniline. Materials, 12, 1932. doi:10.3390/ma12121932
  • Canaud, C., Visconte, L.L.Y. and Nunes, R.C.R. (2001). Mechanical and flammability properties of ATH-filled EPDM compositions. Macromolecular Materials and Engineering. 286, 377-381.
  • Di, Z., Zheng, W., Yue, Y., Jingjing, L., Chunqing, H., Ning, Q., Xiangyang, P., Zhen, H. and Pengfei, F. (2023). Effect of aluminum hydroxide (ATH) content on free volumes and water barrier property of silicone rubber. 4th Japan-China Joint Workshop on Positron Science (JWPS2019) JJAP Conf. Proc., 011203.
  • Ekwueme, C C. and Igwe, I.O. (2018). Cure characteristics and mechanical properties of pineapple leaf fibre filled natural rubber, Journal of Minerals and Materials Characterization and Engineering, 6, 601-617. doi: 10.4236/jmmce.2018.66043.
  • Fu, S.Y., Feng, X.Q., Lauke, B. and Mai, Y.W. (2008). Effects of particle size, particle/matrix interface adhesion and particle loading on mechanical properties of particulate–polymer composites. Composites Part B, 39(6), 933–961. doi:10.1016/j.compositesb.2008.01.002
  • Hull, T.R., Witkowski, A. and Hollingbery, L. (2011). Fire retardant action of mineral fillers. Polymer Degradation and Stability, 96(8), 1462–1469. doi: 10.1016/j.polymdegradstab.2011.05.006
  • Hornsby, P.R. (2001). Fire retardant fillers for polymers. International Materials Reviews, 46(4), 199–210. doi: 10.1179/095066001771048763
  • Ibarra, L., Posadas, P. and Esteban-Martínez, M. (2005). A comparative study of the effect of some paraffinic oils on rheological and dynamic properties and behavior at low temperature in EPDM rubber compounds. Journal of Applied Polymer Science, 97(5), 1825–1834. doi:10.1002/app.21954
  • Khattab, M.A., Feteha A.H.F., Sadik, W.A. and Abdel-Bary, E.M. (2016). Effect of aluminium trihydrate as flame retardant on properties of a thermoplastic rubber nanocomposite. Fire and Materials, 41(6), 688-699. doi: 10.1002/fam.2411
  • Levchik, S.V. and Weil, E.D. (2008). Developments in phosphorus flame retardants. Advances in Fire Retardant Materials, 41–66. doi: 10.1533/9781845694701.1.41
  • Maiti, M., Basak, G.C., Srivastava, V.K. and Jasra, R.V. (2016). Mesoporous silica reinforced polybutadiene rubber hybrid composite, International Journal of Industrial Chemistry, 7, 131–141. doi: 10.1007/s40090-015-0062-8
  • Natinee, L., Alif, W., Azizon, K. and Tadamoto, S. (2019). Mechanical, thermal and fire retardant Characteristics of NR/PP/ATH thermoplastic vulcanizates. Walailak Journal of Science and Technology (WJST). 16(10), 723-737.
  • Tang, G., Hu, Y. and Song, L. (2013). Study on the Flammability and Thermal Degradation of a Novel Intumescent Flame Retardant EPDM Composite. Procedia Engineering, 62, 371–376. doi: 10.1016/j.proeng.2013.08.078
  • Surya, I. and Khosman, H. (2020). The compounds of montmorillonite-filled natural rubber: Cure rate index, swelling and hardness properties. AIP Conference Proceedings, 2237(1). doi:10.1063/5.0005218
  • Surya, I., Sukeksi, L. and Hayeemasae, N. (2018). Studies on cure index, swelling behaviour, tensile and thermooxidative properties of natural rubber compounds in the presence of alkanolamide. IOP Conference Series: Materials Science and Engineering, 309, 012060. doi:10.1088/1757-899X/309/1/012060
  • Wan, L., Deng, C., Zhao, Z.-Y., Chen, H. and Wang, Y.-Z. (2020). Flame Retardation of Natural Rubber: Strategy and Recent Progress. Polymers, 12(2), 429. doi: 10.3390/polym12020429
  • Weil, E.D. and Levchik, Sergei. (2009). Flame retardants for plastics and textiles: Practical applications. 1-297.
  • Zhang, X., Guo, F., Chen, J., Wang, G. and Liu, H. (2005). Investigation of interfacial modification for flame retardant ethylene vinyl acetate copolymer/alumina trihydrate nanocomposites. Polymer Degradation and Stability. 87, 411-418.
  • Zhao, W., Kumar Kundu, C., Li, Z., Li, X. and Zhang, Z. (2021). Flame retardant treatments for polypropylene: Strategies and recent advances. Composites Part A: Applied Science and Manufacturing, 145, 106382. doi: 10.1016/j.compositesa.2021.106382
  • Zirnstein, B., Tabaka, W., Frasca, D., Schulze, D. and Schartel, B. (2018). Graphene/hydrogenated acrylonitrile-butadiene rubber nanocomposites: Dispersion, curing, mechanical reinforcement, multifunctional filler. Polymer Testing, 66, 268–279. doi: 10.1016/j.polymertesting.2018.01.035
Toplam 21 adet kaynakça vardır.

Ayrıntılar

Birincil Dil Türkçe
Konular Makine Mühendisliği (Diğer)
Bölüm Araştırma Makaleleri
Yazarlar

Melisa Işin 0000-0001-6091-4494

İlker Köprü 0000-0002-0038-0635

Salih Hakan Yetgin 0000-0002-6068-9204

Erken Görünüm Tarihi 21 Aralık 2024
Yayımlanma Tarihi
Gönderilme Tarihi 31 Ekim 2024
Kabul Tarihi 28 Kasım 2024
Yayımlandığı Sayı Yıl 2024 Cilt: 1 Sayı: 2

Kaynak Göster

APA Işin, M., Köprü, İ., & Yetgin, S. H. (2024). EPDM Kauçuğun Mekanik ve Yanma Özelliklerine Alüminyum Trihidroksitin Etkisinin İncelenmesi. ADÜ Fen Ve Mühendislik Bilimleri Dergisi, 1(2), 77-83.