Preparation and Characterization of Polyvinyl Alcohol/Activated Carbon (PVA/AC) Composite and Its Use in the Adsorption of 4-Nitrophenol (4-NP)

Öz

    In this study, polyvinyl alcohol-activated carbon (PVA/AC) composite was synthesized and characterized by SEM, FTIR, DLS and TGA-DSC measurement. The zero point charge for the PVA/AC was determined as approximately 3 pH. The efficiency of PVA/AC as a cheap adsorbent for removal of 4-nitrophenol (4-NP) from aqueous solution was researched at 298, 318 and 328 K. For this purpose, Freundlich and Langmuir isotherm models were used. According to the results, adsorption of 4-NP onto composite best fitted to Freundlich model. The pseudo-first-order, pseudo-second-order and intraparticle diffusion models were utilized to study the adsorption kinetics. The experimental consequences fitted with the pseudo-first-order model. According to Arrhenius equation, Ea was calculated as 14.13 kJmol^-1. Thermodynamic parameters were also calculated, which revealed that the adsorption process is endothermic, not spontaneous.

Anahtar Kelimeler

• Adsorption,Activated carbon,Polyvinyl alcohol,4-nitrophenol (4-NP),Zero point charge

Kaynakça

1. [1] Aljeboree, A., Alshirifi, A., Alkaim, A., Kinetics and equilibrium study for the adsorption of textile dyes on coconut shell activated carbon, Arabian Journal of Chemistry, 10, 3381-3393, 2017.
2. [2] Wang, H., Preparation and properties of porous poly (vinyl alcohol)/powdered activated carbon composite, Material Science and Advanced Technologies in Manufacturing, 852, 117-120, 2014.
3. [3] Jia, Z., Li, Z., Li, S., Li, Y., Zhu, R., Adsorption performance and mechanism of methylene blue on chemically activated carbon spheres derived from hydrothermally-prepared poly (vinyl alcohol) microspheres, Journal of Molecular Liquids, 220, 56–62, 2016.
4. [4] Kaur, T., Thirugnanam, A., Effect of Porous Activated Charcoal Reinforcement on Mechanical and In-Vitro Biological Properties of Polyvinyl Alcohol Composite Scaffolds, Journal of Materials Science & Technology, 33(7), 734–743, 2017.
5. [5] Kumar, A., Kumar, S., Kumar, S.,Gupta, D., Adsorption of phenol and 4-nitrophenol on granular activated carbon in basal salt medium: equilibrium and kinetics, J. Hazard. Mater., 147, 155–166, 2007.
6. [6] Liu, S., Wang, J., Huang, W., Tan, X., Dong, H., Goodman, B., Du, H., Lei, F., Diao, K., Adsorption of phenolic compounds from water by a novel ethylenediamine rosin-based resin: Interaction models and adsorption mechanisms, Chemosphere, 214, 821-829, 2019.
7. [7] Ivanov, A., Kozynchenko, O., Mikhalovska, L., Tennison, S., Jungvid, H., Gunko, V., Mikhalovsky, S., Activated carbons and carbon-containing poly(vinyl alcohol) cryogels: characterization, protein adsorption and possibility of myoglobin clearance, Phys. Chem. Chem. Phys., 14, 16267–16278, 2012.
8. [8] Swamy, M., Nagabhushana, B., Krishna, R., Kottam, N., Raveendra, R., Prashanth, P., Fast adsorptive removal of methylene blue dye from aqueous solution onto a wild carrot flower activated carbon: isotherms and kinetics studies, Desalination and Water Treatment, 71, 399–405, 2017.

9. [9] Silva, M., Santos, M., Júnior, M., Fonseca, M., Filho, E., Natural Palygorskite as an Industrial Dye Remover in Single and Binary Systems, Materials Research,19, 1232-1240, 2016.
10. [10] Trivedi, M., Sethi, K., Panda, P., and Jana, S., A comprehensive physicochemical, thermal, and spectroscopic characterization of zinc (II) chloride using X‑ray diffraction, particle size distribution, differential scanning calorimetry, thermogravimetric analysis/differential thermogravimetric analysis, ultraviolet‑visible, and Fourier transform‑infrared spectroscopy, International Journal of Pharmaceutical Investigation, 7, 33-40, 2017.
11. [11] Cuevas, L., Villacura, E., Toloza, C., Magellan Peat (Sphagnum Magallanicum) As Natural Adsorbent OfRecalcitran Synthetic Dyes, J. Soil Sc. Plant Nutr., 8,31-43, 2008.
12. [12] Haddad, M., Mamouni, R., Saffaj, N., Lazar, S., Removal of a cationic dye – Basic Red 12– from aqueous solution by adsorption onto animal bone meal, Journal of the Association of Arab Universities for Basic and Applied Sciences, 12, 48–54, 2012.
13. [13] Dhorabe, P., Lataye, D., Ingole, R., Removal of 4-nitrophenol from aqueous solution by adsorption onto activated carbon prepared from Acacia glauca sawdust, Water Science & Technology, 73, 2016, doi: 10.2166/wst.2015.575.
14. [14] Chartarrayawadee, W., Moulton, S., Too, C., Wallace, G., Fabrication of Graphene Electrodes by Electrophoretic Deposition and Their Synergistic Effects with PEDOT and Platinum, Chiang Mai J. Sci., 40, 750-762, 2013.
15. [15] El-Naggar, N., Hussein, M., El-Sawah, A., Phycobiliprotein-mediated synthesis of biogenic silver nanoparticles, characterization, in vitro and in vivo assessment of anticancer activities, Scientific Reports, 8, 2018, doi:10.1038/s41598-018-27276-61.
16. [16] Paralikar, P., Biogenic Synthesis of Silver Nanoparticles Using Leaves Extract of EpiphyllumOxypetalum and its Antibacterial Activity, Austin Journal of Biotechnology & Bioengineering, 1, 2014.
17. [17] Bulut, Y., Karaer, H., Adsorption of Methylene Blue from Aqueous Solution by Crosslinked Chitosan/Bentonite Composite, Journal of Dispersion Science and Technology, 36,61-67, 2015.
18. [18] Salehi, E., Farahani, A., Macroporous chitosan/polyvinyl alcohol composite adsorbents based on activated carbon substrate, J Porous Mater., 24,1197–1207, 2017.
19. [19] Feyzi, F., Jalilvand, H., Dehghani, M., Adsorption of dimethyl sulfide from model fuel on raw and modified activated carbon from walnut and pistachio shell origins:kinetic and thermodynamic study, doi.org/10.1016/j.colsurfa.2020.124620.
20. [20] Nam, H., Nam, H., Wang, S., Preparation of activated carbon from peanut shell with KOH activation and its application for H2S adsorption in confined space, Journal of Environmental Chemical Engineering, 8, 103683, 2020.
21. [21] Fajri, L., Nawi, M., Sabar, S., Nawawi, N., Preparation of immobilized activated carbon-polyvinyl alcohol composite for the adsorptive removal of 2,4-dichlorophenoxyacetic acid, Journal of Water Process Engineering, 25, 269–277, 2018.
22. [22] Almeida, V., Vargas, A., Nogami, E., NaOH-activated carbon of high surface area produced from coconut shell: Kinetics and equilibrium studies from the methylene blue adsorption, Chemical Engineering Journal 174, 117– 125, 2011.
23. [23] Tseng, T., Wu, F., Juang, R., Characteristics and applications of the Lagergren’s first-order equation for adsorption kinetics, Journal of the Taiwan Institute of Chemical Engineers 41, 661–669, 2010.
24. [24] Wang, L., Zhang, J., Wang, A., Fast removal of methylene blue from aqueous solution by adsorption onto chitosan-g-poly(acrylic acid)=attapulgite composite. Desalination, 266: 33–39, 2011.
25. [25] Gürses, A., Hassani, A., Kırans, M.¸ Açıslı, O., Karaca, S., Removal of methylene blue from aqueous solution using by untreated lignite as potential low-cost adsorbent: kinetic, thermodynamic and equilibrium approach, J. Water Process Eng., 2,10-21, 2014.
26. [26] Daga, K., Gehlot, P., Use of Polyvınylalcohol Coated Carbon Black for Removal of Lınear AlkylbenzeneSulphonate (Las) From Wastewater, Nature Environment and Pollution Technology © Technoscience Publications, 6,725-730, 2007.
27. [27] Karaer, H., Kaya, I., Synthesis, characterization of magnetic chitosan/active charcoal composite and using at the adsorption of methylene blue and reactive blue4, Microporous and Mesoporous Materials, 232,26-38, 2016.
28. [28] Iqbal, M., Ashiq, M., Adsorption of dyes from aqueous solutions on activated charcoa, Journal of Hazardous Materials B, 139,57–66, 2007.
29. [29] Karaer, H., Uzun, İ., Adsorption of basic dyestuffs from aqueous solution by modified chitosan, Desalination and Water Treatment, 51, 2294-2305, 2013.
30. [30] Negma, N., AbdElWahed, M., Hassan, A., Kana, M., Feasibility of metal adsorption using brown algae and fungi: Effect of biosorbents structure on adsorption isotherm and kinetics, Journal of Molecular Liquids, 264, 292–305, 2018.
31. [31] Kyzas, G., Deliyanni, E., Lazaridis, N., Magnetic modification of microporous carbon for dye adsorption, Journal of Colloid and Interface Science, 430,166–173, 2014.
32. [32] Kim, Y., Kim, J., Isotherm, kinetic and thermodynamic studies on the adsorption of paclitaxel onto Sylopute, J. Chem. Thermodynamics, 130,104–113, 2019.
33. [33] Mahida, V., Patel, M., Removal of some most hazardous cationic dyes using novel poly(NIPAAm/AA/N-allylisatin) nanohydrogel, Arabian J. Chem., 9, 430-442, 2016.