Atık sularda boya giderimi için fonsiyonellenmiş nanoselüloz esaslı adsorbanlar

Öz

Son yıllarda, dünya genelinde artan nüfus ile birlikte tarımsal ve endüstriyel faaliyetler giderek artmıştır. Bu faaliyetler sırasında ortaya çıkan organik maddeler, inorganik anyonlar, toksik ağır metaller, zehirli gazlar vb. birçok kirletici çevreye salınmakta ve özellikle sularda önemli derecede kirlilik sorunlarına yol açmaktadır. Bu nedenle çevre dostu ve uygun maliyetli arıtma teknolojilerine ihtiyaç duyulmaktadır. Atık sularda kullanılan adsorpsiyon işlemi çevre dostu arıtma teknolojilerinden biridir. Çeşitli doğal kaynaklardan elde edilebilen selülozik maddeler adsorbanlar olarak kullanılabilmektedir. Atık sularda bulunan organik kirleticiler ve ağır metal iyonlarının adsorpsiyon kapasiteleri kimyasal işlemlerden etkilenmekte olup, modifiye edilmiş selülozun modifiye edilmemiş selüloza göre daha yüksek adsorpsiyon kapasitesi sergilediği bilinmektedir. Bu derlemede, literatürde yer alan çeşitli nanoselüloz esaslı adsorbanların, özellikle atık sularda bulunan boyaların uzaklaştırılmasında sergiledikleri adsorpsiyon kapasiteleri ve bu adsorbanların modifikasyonları sonrasında yapılarının karakterizasyonunda kullanılan FTIR ve SEM analizleri incelenmiştir. Nanoselüloz esaslı adsorbanların atık sulardaki boyaların uzaklaştırılmasında iyi bir potansiyel sergilediği görülmektedir. Çevre kirliliğini minimuma indirmek için ucuz ve daha etkili selüloz esaslı adsorbanların modifikasyonlarla geliştirilebileceği düşünülmektedir.

Anahtar Kelimeler

• Adsorpsiyon
• Atık Su
• Boya Uzaklaştırma
• Modifikasyon
• Nanoselüloz

Functionalized nanocellulose based adsorbents for dye removal from wastewater

Öz

In recent years, agricultural and industrial activities have gradually increased with the increasing population worldwide. Many pollutants, such as organic substances, inorganic anions, toxic heavy metals, toxic gases etc., generated during these activities are released into the environment and cause significant pollution problems, especially in water. Therefore, environmentally friendly and cost-effective treatment technologies are needed. The adsorption process used in waste water is one of the environmentally friendly purification technologies. Cellulosic materials obtained from various natural sources can be used as adsorbents. The adsorption capacity of organic pollutants and heavy metal ions in wastewater is affected by chemical processes, and it is known that modified cellulose exhibits higher adsorption capacity than unmodified cellulose. In this review, the adsorption capacities of various nanocellulose-based adsorbents, especially in the removal of dyes in wastewater, and the FTIR and SEM analyzes used in the characterization of the structures of these adsorbents after modifications were examined. Nanocellulose-based adsorbents appear to exhibit good potential in removing dyes in the waste water. It is thought that cheap and more effective cellulose-based adsorbents can be developed with modifications to minimize environmental pollution.

Anahtar Kelimeler

• Adsorption
• Waste water
• Dye removal
• Modification
• Nanocellulose

Kaynakça

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