Degradation of Chrysoidine Y Dye with Sulphite Ion in Aqueous Acidic Phase using Kinetic Method of Analysis

Öz

Chrysoidine Y dye (CYD) is harmful to aquatic species and human beings, which has the tendency to induce cancer and mutation to living cells. Its degradation is key in creating a healthy environment and curbing pollution. Hence, a stoichiometric method is used to study its degradation with a pool of sulphite ions (SO32-), under a constant ionic strength, [H+], and 449 nm wavelength. The stoichiometry is observed to be 1:1 for CYD: SO32-, which results in the formation of aniline and sulphonic acid as the main products of the degradation. The reaction is first-order with respect to CYD, first-order with respect to SO32-, and a second-order-overall. Increase in the proton concentration impacts positively on the reaction rate of CYD degradation. Negative salt effect is observed as the dilapidation rate of the dye drops. Occurrence of counter ion catalysis is pronounced with large appreciable rate. The participation of a firm intermediate molecule is negative as revealed by the Spectroscopic Scanning Technique (SST) and Michaelis Menten’s Type Plot (MMTP), which cancels the inner-sphere mechanism expectancy. The degradation of the dye was successfully carried out and the reaction points to the outer-sphere mechanism.

Anahtar Kelimeler

• Degradation
• Chrysoidine Y
• Sulphite ion
• Acidic phase
• Kinetics

Destekleyen Kurum

NIGERIAN DEFENCE ACADEMY, KADUNA NIGERIA

Proje Numarası

None

Etik Beyan

None as no human/animal materials was used for the study

Teşekkür

I wish to express my gratitude to the Nigerian Defence Academy Kaduna, Nigeria for their support through out this research.

Kinetik Analiz Yöntemi Kullanılarak Sulu Asidik Fazda Sülfit İyonlu Krizoidin Y Boyasının Bozunması

Öz

Krizoidin Y boyası (CYD), kansere ve canlı hücrelerde mutasyona neden olma eğiliminde olan su canlıları ve insanlar için zararlıdır. Bozunumu sağlıklı bir çevre yaratmada ve kirliliği azaltmada anahtar rol oynar. Bu nedenle, sabit iyonik güç [H+] ve 449 nm dalga boyu altında bir sülfit iyonları havuzunda (SO32-) bozunmasını incelemek için stokiyometrik bir yöntem kullanılır. Stokiyometrik oranın CYD: SO32- için 1:1 olduğu gözlemlenir ve bu da bozunmanın ana ürünleri olarak anilin ve sülfonik asit oluşumuyla sonuçlanır. Tepkime CYD açısından birinci dereceden, SO32- açısından birinci dereceden ve genel olarak ikinci derecedendir. Proton konsantrasyonundaki artış, CYD bozunmasının reaksiyon hızını olumlu yönde etkiler. Boyanın bozulma hızı düştükçe negatif tuz etkisi gözlemlenir. Karşı iyon katalizinin oluşumu büyük ve belirgin bir hızla belirgindir. Spektroskopik Tarama Tekniği (SST) ve Michaelis Menten Tip Grafiği (MMTP) tarafından ortaya konulduğu gibi, sağlam bir ara molekülün katılımı negatiftir ve bu da iç küre mekanizması beklentisini iptal eder. Boyanın bozunması başarıyla gerçekleştirildi ve reaksiyon dış küre mekanizmasına işaret etmektedir.

Anahtar Kelimeler

• Bozunma
• Krizoidin Y
• Sülfit iyonu
• Asidik faz
• Kinetik

Proje Numarası

None

Kaynakça

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